• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집A
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• pp.105-110
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• 2001

It has recently been raised main issue how solve the problem of insufficient energy. One of the solution is to increase the thermal efficiency of power generation system. For the purpose of high efficiency, it is necessary to increase the steam temperature and pressure. So, the use of modified $9{\sim}12%Cr$ steel having superior creep rupture strength and oxidation resistance is required to endure such severe environment. The evaluation of creep properties of those heat resistance material is very important to secure the reliability of high temperature and pressure structural components. Since creep properties are determined by microstructural change such as carbide precipitation and coarsening, It is certain that there are some relationship between creep properties and hardness affected by microstructure. In this study, SP-Creep ruptured test for newly developed 9Cr steel being used as boiler valve material was performed, and creep properties of the material were evaluated. Also, hardness test were performed and hardness results were related to the creep properties such as LMP and creep strength to verify the availability of SP-Creep test as creep test method.

• 대한기계학회논문집A
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• 제35권4호
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• pp.447-452
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• 2011

일반적으로 화력발전 터빈 로터나 케이싱과 같이 고온 고압에서 운전되는 설비의 경우 크리프 및 피로 손상이 주된 손상기구로 알려져 있다. 터빈 설비의 수명을 정확하게 예측하기 위해서 크리프 및 피로 손상 기구를 복합적으로 고려해야 하지만 500MW 급 대용량 터빈 설비의 경우 기저 부하를 담당하기 때문에 기동횟수가 많지 않고 고온에서 장시간 동안 안정적인 운전을 하므로 잔여수명을 결정할 때 크리프 수명을 주로 사용한다. 국내에서 20 년 넘게 운전되고 있는 대용량 터빈의 경우 대부분 니켈, 크롬, 몰리브덴, 바나듐 성분이 포함한 재료로 되어 있다. 본 논문에서는 대용량 터빈의 크리프 수명을 예측하기 위하여 1Cr1Mo1/4V 터빈 로터강에 대한 크리프 손상 모델을 제안하고자 한다.

• 한국재료학회지
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• 제13권1호
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• pp.36-42
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• 2003

The oxidation behaviors of Y-Cr bilayer deposited on ferritic steel by magnetron-sputtering for application of the Fe-Cr alloys as interconnectors of planar-type solid oxide fuel cells (SOFCs) were studied. After oxidation at $800^{\circ}C$ for 40 hours, the major phase of $Y_2$$O_3$and the minor phase of $YCrO_3$, $Mn_{1.5}$ $Cr_{1.5}$ $O_4$and Cr$_2$SiO$_4$were formed in the Y/Cr bilayered samples, while the major phase of Cr$_2$O$_3$and the minor phase of $Y_2$$O_3$were formed as the major phase in the Cr/Y bilayered samples. The Log(ASR/T) that expresses electric resistance of the Y/Cr coated specimen with nonconducting $_Y2$$O_3$oxide showed high value of -2.80 Ω$\textrm{cm}^2$$K^{-1}$ / and that of the Cr/Y coated specimen with conducting $Cr_2$$O_3$oxide appeared to be -4.11 Ω$\textrm{cm}^2$$^{K}$ . The electric resistance of the Y/Cr coated specimen was largely increased due to the formation of high resistance oxide scales. However, the Cr/Y coated specimen did not show any increase in the electric resistance and had the long-term stability of oxidation because there was no formation of the secondary phases with low conductivity.

• 연구논문집
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• 통권31호
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• pp.157-163
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• 2001

Evolution of microstructure due to service exposure to high temperature has a strong effect performance of heat resistant steels. In case of modified 9Cr-1Mo steels, precipitation of $Fe_2Mo$-type laves phases and coarcening of $M_23C_6$-type carbides is the primary cause of degradation of mechanical properties such as creep resistance, tensile strength and toughness. Creep tests have been carried out on pre-aging mod. 9Cr-1Mo steels to examine the effect of pre-aging and stress on the creep strength. Based on the results, a nondestructive procedure, where electrochemical technique that quantitatively detect laves phases and $M_23C_6$-type carbides in a material is used, has been proposed to evaluate a residual creep life of mod. 9Cr-1Mo steels.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2004년도 제5회 압연심포지엄 신 시장 개척을 위한 압연기술
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• pp.285-293
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• 2004

Oxidation behavior of 304 and 430 stainless steel were studied using thin film X-ray analysis and glow discharge spectrum analysis (here-after GDS). The oxidation layer of 304 stainless steel was composed of $Cr_2O_3\;and\;FeCrO_4$ and its thickness was about $1.5{\mu}m$ after $1\~5$ minutes of annealing at $1120^{\circ}C$ open air. However, the oxidation layer of 430 stainless steels was mainly composed of $Cr_2O_3$ and its typical thickness was 0.5um after $1\~5$ minutes of annealing at $1000^{\circ}C$ open air. Electro-chemical analysis revealed that the descaling of oxidation layer could be activated by Fe, Cr dissolution from the matrix behind the oxidation layer at the current density of $5\~10ASD$ and by Fe, Cr-oxide dissolution from the oxidation layer at the current density over than 10ASD. Electrolytic stripping of 430 and 304 revealed the intial incubation period of descaling by oxygen evolving at low current density range such as $5\~10ASD$. However the dissolution of oxide layer was occurred when applying the anodic current of $10\~20ASD$ on 430 and 304 stainless steels. It was suggested that the electrolytic pickling of high Cr bearing stainless steel such as 430 and 304 seemed to be the more effective in the high current density range such as $10\~20ASD$ than the low current density range such as $5\~10ASD$.

• Journal of Welding and Joining
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• 제18권2호
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• pp.49-56
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• 2000

Recently developed Austenite stainless steel, 309L was used to overlay on 3Cr-1Mo-V-Ti-B steels, using Electroslag welding process, which wide electrodes were adopted. Transition region in welding interlayer relating to disbonding crack was investigated. Also, the effect of welding condition on the width of transition region and coarsening grains of the austenite were studied. 1) With increasing welding speed the width of martensite at transient region was increased, but the amount of delta ferrite in weld metal was reduced, being fine grained. 2) The form of martensite at the transition region was occurred by reversible transformation during cooling since the interdiffusion of Cr and Ni from weld metal and Fe and C from base metals at the transition region, causes to lowering the concentration of Cr and Ni at the transition region, leading to increasing Ms point. 3) With increasing welding speed, the grain of austenite formed at the welding interface was finer. With increasing welding current under the same welding speed, the grain size of the austenite was finer. At high current, original grain size of the austenite is coarse, but the austenite has fine grains because the austenite was transformed to martensite during cooling. 4) In the case of high welding speed, the width of martensite at the welding interface was increased, but the grain size of austenite at the welding interface was finer. This indicates that the inhibition of disbonding crack may be achieved through dispersening fine carbides in the gain boundary.

• 열처리공학회지
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• 제30권3호
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• pp.117-126
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• 2017

The variation in microstructure and mechanical properties during heat treatment was examined in a series of 0.27% C-1.5% Mn-1.0% Cr steels with silicon contents in the range of 0 to 1.0 wt%. It was found that addition of 0.5%~1.0% silicon increased both tensile strength and impact toughness through solid solution strengthening and microstructural refinement. 0.27% C-1.0% Si-1.5% Mn-1.0% Cr steel showed tensile strength of 1,700 MPa in the as-quenched condition and the steel revealed a full martensitic structure even after air cooling from $900^{\circ}C$ to room temperature, showing air hardening characteristics. Tempering at $150^{\circ}C$ which corresponds to the typical paint-baking temperature after painting of body in white, slightly decreased the tensile strength and increased elongation, but substantially increased the impact toughness compared to the as-quenched steel.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 1999년도 추계학술발표회 초록집
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• pp.103-104
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• 1999

• 한국재료학회:학술대회논문집
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• 한국재료학회 1997년도 한국재료학회 추계학술발표회
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• pp.42-42
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• 1997

• 한국재료학회:학술대회논문집
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• 한국재료학회 2002년도 추계학술발표강연 및 논문개요집
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• pp.33-33
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• 2002