• Asian Journal of Turfgrass Science
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• v.10 no.3
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• pp.263-270
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• 1996

This experiment was conducted to investigate the loss of various herbicides by means of vola-tility from the turfgrass field and the hare ground with the different soil moisture contents and temperatures. Different herbicides were applied at the rates of 375 g a.i. /l0a of pendimethalin,250 g a.i. /l0a of napropamide, and 96.4 g a.i. /l0a of dicamba with 200 \ulcorner/10a of spray volume in the turfgrass(Zoysia japonica cut off 5cm) grown in pots(265.8 $cm^2$) and bared soil. The pots were placed in the growth chamber with 10,000 lux of light intensity(12h per day) at 25 and 35˚C for 7days. Amberlite XAD polymeric resin(20/50 mesh) was used as sampling media for herbicide airborne residues. Air flow was maintained at 10 \ulcorner /min by vacuum pump regulated with a factory calibrated flow meter. Herbicide airborne residues were extracted from the XAD resin with 300 ml of 1:1 acetone and hexane. The extracts were concentrated by rotary evaporation at 35˚C and dissolved in 1 ml MeCN for HPLC analysis. The airborne losses of the herbicide applied in the turfgrass and bare soil increased as the temperature and soil moisture contents were increased, regardless of the kinds of herbicide. Higher airborne residues was observed in the turfgrass pots than the bare soil pots. Pendimethalin and dicamba with higher vapor pressure gave rise to the increased loss of airborne herbicides, showing that 6.26 and 6.4% of average airborne loss in pendimethalin and dicamba, respectively, compared to 0.56% in napropamide. The amount of airborne losses in turfgrass was highest at one day after application and then a declined trend was observed as the time was prolonged. Key words. Herbicides, Turfgrass field, Bare ground, Volatility.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.6
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• pp.392-395
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• 2006

The toxic effects of 9 commercially available herbicides on the earthworm, Eisenia fetida (Savigny) were evaluated with recommended dose, 2-fold and 4-fold dose using soil surface spray, immersion and contact filter tests in order to find out whether herbicides actually influence the life of earthworm in the soil or not. In the surface sprayed soil test, the earthworm mortality to nine herbicides were not significantly different from the comparison with the control regardless of level of dose. In the immersion test, the mortality of 4-fold dose was 34% in the napropamide and 64% in the alachlor. In contact filter test, the mortality appeared 80% in alachlor, 37% in napropamide, and 10% in triclopyr at 2-fold dose level and those of 4-fold dose were as follows: napropamide 96%, alachlor 80%, glyphosate 47%, triclopyr 37%, paraquatdichloride 37%; glufosinate ammonium 33%, pyributicarb 10%. As a result of these tests by three methods, the mortality of earthworm in terms of the recommended dose level was no observation about eight herbicides while the napropamide appeared 33% in contact filter test.

• Korean Journal of Weed Science
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• v.12 no.3
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• pp.261-270
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• 1992

Many herbicides that are applied at the soil before weed emergence inhibit plant growth soon after weed germination occurs. Plant growth has been known as an irreversible increase in size as a result of the processes of cell divison and cell enlargement. Herbicides can influence primary growth in which most new plant tissues emerges from meristmatic region by affecting either or both of these processes. Herbicides which have sites of action during interphase($G_1$, S, $G_2$) of cell cycle and cause a subsequent reduction in the observed frequency of mitotic figures can be classified as an inhibitor of mitotic entry. Those herbicides that affect the mitotic sequence(mitosis) by influencing the development of the spindle apparatus or by influencing new cell plate formation should be classified as causing disruption of the mitotic sequence. Sulfonylureas, imidazolinones, chloroacetamides and some others inhibit plant growth by inhibiting the entry of cell into mitosis. The carbamate herbicides asulam, carbetamide, chlorpropham and propham etc. reported to disrupt the mitotic sequence, especially affecting on spindle function, and the dinitroaniline herbicides trifluralin, nitralin, pendimethalin, dinitramine and oryzalin etc. reported to disrupt the mitotic sequence, particularly causing disappearence of microtubles from treated cells due to inhibition of polymerization process. An inhibition of cell enlargement can be made by membrane demage, metabolic changes within cells, or changes in processes necessary for cell yielding. Several herbicides such as diallate, triallate, alachlor, metolachlor and EPTC etc. reported to inhibit cell enlargement, while 2, 4-D has been known to disrupt cell enlargement. One potential danger inherent in the use of soil acting herbicides is that build-up of residues could occur from year to year. In practice, the sort of build-up that would be disastrous is unikely to occur for substances applied at the correct soil concentration. Crop injury caused by soil applied herbicides can be minimized by (1) following the guidance of safe use of herbicides, particularly correct dose at correct time in right crop, (2) by use of safeners which protect crops against injury without protecting any weed ; interactions between herbicides and safeners(antagonists) at target sites do occur probably from the following mechanisms (1) competition for binding site, (2) circumvention of the target site, and (3) compensation of target site, and another mechanism of safener action can be explained by enhancement of glutathione and glutathione related enzyme activity as shown in the protection of rice from pretilachlor injury by safener fenclorim, (3) development of herbicide resistant crops ; development of herbicide-resistant weed biotypes can be explained by either gene pool theory or selection theory which are two most accepted explanations, and on this basis it is likely to develop herbicide-resistant crops of commercial use. Carry-over problems do occur following repeated use of the same herbicide in an extended period of monocropping, and by errors in initial application which lead to accidental and irregular overdosing, and by climatic influence on rates of loss. These problems are usually related to the marked sensitivity of the particular crops to the specific herbicide residues, e.g. wheat/pronamide, barley/napropamid, sugarbeet/ chlorsulfuron, quinclorac/tomato. Relatively-short-residual product, succeeding culture of insensitive crop to specific herbicide, and greater reliance on postemergence herbicide treatments should be alternatives for farmer practices to prevent these problems.

• Asian Journal of Turfgrass Science
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• v.21 no.1
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• pp.69-79
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• 2007

Incorporating herbicides application into a fertilization program has several benefits including saving time and reducing traffics on the lawn. Premixed products of fertilizers and herbicides are commonly known as Weed & Feed in the lawn-care industry. To compare Weed & Feed with separate applications of fertilizers and herbicides on a Kentucky bluegrass (Poa pratensis L.) lawn, a Weed & Feed 28-3-3, containing 0.64% 2,4-D, 0.31% MCPP, and 0.03% dicamba of active ingredients, was used in this study. The first application was in May, with the second in June or Sept. Herbicides in forms of 2,4-D (LV-4, 4EC), MCPP (4EC), and dicamba (Clarity, 4EC) were applied at rates equal to the amounts in Weed & Feed or at half of the rates. The dominant weed in both locations was common dandelion (Taraxacum officinale Weber.) in 2005 and 2004. A secondary weed was Canada thistle (Cirsium arvense (L.) Scop.) in 2004 and broadleaf plantain (Plantago major L.) in 2005. When applied in May and June, fertilizer plus full rate of herbicides treatment achieved 112.3 and 83.7 days of acceptable turf quality in 2004 and 2005, respectively. During the same period, Weed & Feed resulted in 58.7 and 24.3 days of acceptable turf quality, respectively. Our study showed that Weed & Feed was generally as effective in weed control as the same amount of fertilizer plus half rates of herbicides sprayed although results may vary due to the timing of application. Fertilizer plus full rates of herbicides provided the same or better results of weed control than Weed & Feed.

• Weed & Turfgrass Science
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• v.2 no.4
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• pp.395-401
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• 2013

This study was conducted to evaluate the selective control of creeping bentgrass invaded in Kentucky bluegrass by applying several herbicides and recovery of Kentucky bluegrass by sand injection seeding method. Selective herbicides such as mecoprop, triclopyr-TEA, imazaquin, bentazone and penosulam pyrazosulfuro-ethyl and non-selective herbicides such as glyphosate, paraquat dichloride and glyphsate ammonium oxyflorfen were used. Selective suppression of creeping bentgrass in Kentucky bluegrass was evaluated by turf color, chlorophyll and visual control indexes. Control of creeping bentgrass was most effective with the double dose application of triclopyr-TEA (2 Tri-T) in the selective herbicides and the 1 / 5 dose application of glyphosate ammonium oxyflorfen (1 / 5 GAO) in the non-selective herbicides. Visual control indexes by 2 Tri-T in selective herbicides and 1 / 5 GAOin non-selective herbicides were investigated 6.0 and 7.4, respectively. Treated sites were covered completely in 50 days after seeding Kentucky bluegrass by sand injection method.

• Korean Journal of Agricultural Science
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• v.41 no.2
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• pp.85-99
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• 2014

Sulfonylurea (SU)-resistant weeds of eight annual weeds, Monochoria vaginalis, Scirpus juncoides and Cyperus difformis, etc., and four perennial weeds, Scirpus planiculmis, Sagittaria pigmaea, Eleocharis acicularis and Sagittaria trifolia as of 2013 since identification Monochoria korsakowii in the reclaimed rice field in 1998. And the resistant Echinochloa oryzoides to ACCase and ALS inhibitors has been confirmed in rice fields of the southern province, Korea in 2009. In the beginning, the M. vaginalis, S. juncoides and C. difformis of these SU-resistant weeds were rapidly and individually spreaded in different fields, however, these resistant weeds have been occurring simultaneously in the same filed recently. The resistant biotype by weed species demonstrated about 10-to 1,000-fold resistance, based on $GR_{50}$ values of the SU herbicides tested. And the resistant biotype of E. oryzoides to cyhalofop-butyl, pyriminobac-methyl, and penoxsulam was about 14, 8, and 11 times more resistant than the susceptible biotype base on $GR_{50}$ values. The products and applied area of SU-included herbicides have been increased rapidly, and have accounted for about 69% and 96% in Korea, respectively. In Korea, the main cause of SU-resistant weed is extensive use of these herbicides. The top ten herbicides by applied area were composed of all SU-included herbicides by 2003. The concentrated and successive treatment of ACCase and ALS inhibitors for control of barnyardgrass in rice led up to the resistance of E. oryzoides. Also, SU-herbicides like pyrazosulfuron-ethyl and imazosulfuron which effective to barnyardgrass can be bound up with the resistance of E. oryzoides. The ALS activity isolated from the resistant biotype of M. korsakowii to SU-herbicides tested was less sensitive than that of susceptible biotype. The concentration of herbicide required for 50% inhibition of ALS activity ($I_{50}$) of the SU-resistant M. korsakowii was 14-to 76-fold higher as compared to the susceptible biotype. No differences were observed in the rates of [$^{14}C$]bensulfuron uptake and translocation. Acetolactate synthase (ALS) genes from M. vaginalis resistant and susceptible biotypes against SU-herbicides revealed a single amino acid substitution of proline (CCT), at 197th position based on the M. korsakowii ALS sequence numbering, to serin (TCT) in conserved domain A of the gene. Carfentrazone-ethyl and pyrazolate were used mainly to control SU-resistant M. vaginalis by 2006 in Korea. However, the alternative herbicides such as benzobicyclone, to be possible to control simultaneously the several resistant weeds, have been developing and using broadly, because the several resistant weeds have been occurring simultaneously in the same fieled. The top ten herbicides by applied area in Korea have been occupied by products of 3-way mixture type including herbicides with alternative mode of action for the herbicide resistant weeds. Mefenacet, fentrazamide and cafenstrole had excellent controlling effects on the ACCase and ALS inhibitors resistant when they were applied within 2nd leaf stage.

• Korean Journal of Weed Science
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• v.32 no.3
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• pp.240-255
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• 2012

The objectives of this study were to investigate the levels of phytotoxicity of rice varieties to HPPD (4-hydroxy phenylpyruvate dioxygenase)-inhibiting herbicides known for their efficiency to control the sulfonylureas-resistant weed species：mestrione, benzobicyclone, and tefuryltrione. The twenty-six rice varieties (8-Japonica ${\times}$ Indica-type varieties and 18-Japonica-type varieties) were grown for 25 days on seedling trays and then transplanted to paddy rice fields followed by herbicide treatment i.e. standard and double doses of there respective herbicides at 5, 10, and 15 days after transplanting. Although mestrione, benzobicyclone and tefuryltrione are all HPPD-inhibiting herbicides, the phytotoxicity symptoms of the different rice varieties based on the timing of application and doses of the herbicides were significantly different. The Japonica ${\times}$ Indica-type varieties showed much more phytotoxicity symptoms than Japonica-type varieties in all applied herbicides. Increasing herbicidal doses of mesotrione, and an earlier application of and increasing herbicidal doses of benzobicyclon caused severe phytotoxicity symptoms. On the other hand, phytotoxicity due to tefuryltrione did not exhibit significant differences between rice varieties in either the timing of application or dose of the herbicide. Regardless of timing of application and dose of the herbicides, Hangangchalbyeo-1, Hyangmibyeo-1 and high-yield rice varieties such as Namcheonbyeo, Dasanbyeo, Areumbyeo, and Hanareumbyeo, which belong to the Japonica ${\times}$ Indica-type varieties, showed 5 to 8 levels of phytotoxicity symptoms including albinism, browning, detached leaf, and necrosis to mesotrione and benzobicyclon whereas only 1 to 3 levels of phytotoxicity symptoms (chlorosis, albinism, and browning) were seen with to tefuryltrione application. The Japonica-type varieties exhibited only slight phytotoxicity symptoms (1~2 levels) in conformity with the timing of application and doses of the herbicides. However, there were significant differences among the Japonica-type rice varieties, depending on the type of herbicide. Thirteen-Japonica type rice varieties were sensitive to benzobicyclone while 4-Japonica-type and 7-Japonica-type varieties showed phytotoxicity symptoms such as chlorosis and albinism with mestrione and tefuryltrione application, respectively. Therefore, we suggest that the combined-type herbicides including mestrione, benzobicyclone and tefuryltrione should be rejected in paddy fields where rice is grown for either human consumption (functional or processed rice) or livestock feed because of severe phytotoxicity symptoms on the various rice varieties seen regardless of the timing of application and doses of the herbicides.

• The Korean Journal of Pesticide Science
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• v.3 no.3
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• pp.45-53
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• 1999

Red sorrel (Rumex acetosella L.) is a troublesome perennial weed in the alpine grasslands of Kangwon Province of Korea. A number of soil- and foliar-applied herbicides were evaluated for their efficacy of red sorrel control. In greenhouse experiments, no soil-applied herbicides, such as pendimethalin, simazine, alachlor, metolachlor, ethalfluralin controlled red sorrel, however, foliar-applied herbicides, such as glufosinate, paraquat, glyphosate, glyphosate + 2,4-D, dicamba, mecoprop, 2,4-D, bentazone controlled more than 60% of red sorrel 2 weeks after treatments. When dicamba and 2,4-D were applied to red sorrel in different growth stages, the auxin-type of herbicides cold control red sorrel regardless of growth stage. This result implies that the auxin-type herbicides can be applied between early May (early growth stage) and mid lune (before fruit maturation) at Kangwon alpine grasslands. In a field experiment, glufosinate at 1.0 kg a.i, $ha^{-1}$, glyphosate at 3.28 kg a.i. $ha^{-1}$, dicamba at 0.96 kg a.i. $ha^{-1}$, and mecoprop at 150 kg a.i. $ha^{-1}$ controlled more than 80% of red sorrel 4 weeks for treatment, suggesting such herbicides could be applied for red sorrel control at Kangwon alpine grasslands.

• Korean Journal of Soil Science and Fertilizer
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• v.6 no.1
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• pp.9-16
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• 1973

In order to observe the effect of a continuous application of herbicides on the chemical properties of upland soil, samples were collected and analysed from a field experiment continuously applied with herbicides and from two pot experiments, one with a heavy dose and the other with a normal dose of herbicides, applied continuously. The soil samples were collected after three harvests of radish. The results of these analysis were summarized as follows; 1. Of herbicides, M.O., Lorox, 2, 4-D, Lasso, and P.C.P., the Lorox decreased soil pH and organic carbon content in soil and increased exchange and hydrolytic acids, and exchangeable potassium. The herbicide also showed an indication to decrease the exchangeable calcium, magnessium and sodium in soil. It seemed that such changes are mainly due to the indirect effect of Lorox or its metabolites, such as stimulating soil microorganisms, rather than direct chemical nature of them. 2. The other herbicides investigated in this study seemed to increase the organic carbon content in soil. 3. In addition, the continuous application of herbicides may result in an alteration of weed species in the field. All such facts might affect the properties of soil, which may call for a further detailed investigation having a set up of a long term experiment.

• Korean journal of applied entomology
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• v.10 no.1
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• pp.31-38
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• 1971

Tolerance test in plastic vat, pot and fold tests were carried out to investigate the selective herbicides for soybean culture in sandy loam. The soybean plants showed great tolerance against herbicides such as Tri-allate (Avadex-BW), Alachlor (Lasso), Butachlor (Machete), Propachlor (Ramrod), Nitrofen (TOK), MO, HE-314, Nitrofen/Dinoseb(TOK/DNBP), and Chlo.oxu.on (Tenoran), and the growth was normal even when each was treated with the herbicides up to 2ft3 times of the recommended concentrations. Soybean plants showed a slight tolerance against Prometryne (Gesagard), Propazine (Gegamil), Diuron (Karmex), Metabromuron (Patoran), Linuron (Lorox) and Swep when each was treated with herbicides up to 1-2 times of the recommended concentrations. Great injury or withering was noticed due to the high sensitivity of soybean to Simazine (CAT) and to Floumetron (Cotoran). In pot and field experiments with herbicides such as Butachlor (Machete), Alachlor (Lasso), Nitrofen (TOK), Kerb, Nitrofen/Dinoseb (TOK/DNBP), Swep, Linuron (Lorox), Simazine (CAT) and PCP, the following results were obtained: Great injuries were noticed with Simazine (CAT). Also, Linuron (Lorox) and Kerb showed a slight injury at early growth stage of soybean, Nitrofen (TOK) , Nitrofen/Dinoseb (TOK/DNEP), Alachlo. (Lasso), Butachlo. (Machete) and Swep had high selectivities for soybean and no injury was noticed. With respect to herbicidal effects there was a greatly significant difference between treated plots and non-treated plots with the exception of Simaaine (CAT) plot in field test. E. crusgalli and C. sanguinalis were tolerant against Simazine(CAT) and Linuron(Lorox). Cyperus and E. annuus were tolerant against Kerb. Great herbicidal effects on grasses were observed in Alachlor (Lasso) and Butachlor (Machete) plots. Among broad-leaf weeds, P. hydropiper and C. album were tolerant against Butachlor (Machete) and Alachlor (Lasso). When soybean was treated with the herbicides such as Alachlor (Lasso) (ai. 150g/10a), Butachlor (Machete) (ai. 300g/10a), Nitrofen (TOK) (ai. 250g/10a), Linuron (Lorox) (ai. 75g/10a) once after seeding, no additional wording was required till harvest.