• 한국응용과학기술학회지
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• 제22권4호
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• pp.379-384
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• 2005

In general, water treatment sludge (WTS) had high concentration of heavy metal, thus it made the reuse or recycling of WTS difficult. The optimal solidification conditions for maximum suppression of heavy metal elution from WTS were decided in this study. Under the optimal solidification conditions (i.e., temperature, $320^{\circ}C;$ ratio of WTS and MgO, 9:1; solidification time, 1hr), all of heavy metal including aluminum were not detected. Therefore there are no problems for reuse or recycling of WTS which was solidified under the optimal solidification conditions found in the study.

• 한국환경과학회지
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• 제18권2호
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• pp.239-244
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• 2009

In this study, to stabilize the heavy metal in the contaminated soils, the column leaching test based on rainfall and pH value was performed by using coal mine drainage sludge(CMDS): which was generated during electrical purification of abandoned coal mine wastewater. Four types of testing column were used in this study. That were the CMDS and the heavy metal contaminated soils well mixed in 0 wt%, 1 wt%, 3 wt% and 3 wt% layered column. According to the investigation, when the influent pH was $5.5{\sim}6.2$, there were no heavy metal elution at all conditions, and when the influent pH was $3{\sim}3.3$, the order of Cu, Zn, Pb, Cr elution concentration was 3 wt% M(mixed)<3 wt% S(separation)<1 wt% M<0 wt% and the average elution concentration was quite low, the value was 0.005 mg/L. Therefore, CMDS can used as new stabilizer of the heavy metal in the contaminated soils.

• 상하수도학회지
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• 제22권4호
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• pp.413-420
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• 2008

In order to utilize cinder melting slag as a filter media to control the quality of early rainwater, its environmental stability was verified by heavy metal elution experiment and improved by pre-treatment. Possibilities of improving its function as an absorbent was considered. Absorption characteristics of melting slag before and after the pre-treatment were analyzed by heavy metal equilibrium and stationary-phase column experiments, which in turn were analyzed by comparison experiment with activated carbon. As a result of heavy metal elution experiment, every metal item existed in a much lower amount than the criteria or was not detected, implying that there is no problem recycling it. Absorption equilibrium experiment showed that the time for pre-treatment melting slag to reach the equilibrium was reduced, while the absorbed amount was greatly increased. Stationary-phase column experiment assures us that the elimination rate was not changed much by influx rate, pH and the change in packing volume rate, indicating that this melting slag can be used not only as a filter media to control the quality of early rainwater but also in many areas of water-processing.

• 한국토양비료학회지
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• 제39권1호
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• pp.21-28
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• 2006

본 실험은 포화수분상태에서 두개의 서로 다른 토양의 흡착가능장소에 대한 흡착능과 경쟁에 따른 Cd, Pb, 그리고 Cr 이온의 이동성을 조사하였다. 이 조사를 위하여 수용성상태로 단일, 이중, 삼중의 중금속 조합을 이용하였다. 두개의 토양시료는 밭토양의 지표면으로부터 20 cm 이내에서 채취한 토양을 사용하였다. 그리고 공극수량에 따른 출현과 용출곡선을 중금속용액과 치환용 K 이온용액을 가하여 각각의 곡선이 최대와 최소치에 이은 시점까지 조사하였다. 조사 결과 출현과 용출곡선은 대칭을 이루지 않았으며 용액상태로 존재하는 중금속이온의 종류가 증가됨에 따라 용출곡선의 미행이 증가되었을 뿐만 아니라 공극수량도 증가하는 경향을 보였다. 그리고 출현과 용출곡선을 기준하여 곡선의 위와 아래의 면적을 비교하여 본 결과 출현 후 K에 의한 용출면적은 상대적으로 작아 K에 의한 중금속 탈착은 작은 것으로 조사되었는데 이는 중금속이온이 가지는 전기음성도 차이에 기인한 것으로 추정되었다. 결론적으로 토양내에서 중금속이온의 이동은 토양내에서 존재하는 중금속이온의 종류가 2개 이상 존재하는 한 토양의 물리적 비평형과 용액상태의 화학적평형이 중금속이온 이동에 영향을 미치는 것으로 추정하였다.

• 한국지반환경공학회 논문집
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• 제9권4호
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• pp.47-52
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• 2008

본 연구는 안동지역에 소재하는 안동 임하호 저니토가 호소수에 미치는 영향을 조사하기 위하여 안동호와 임하호 6개 지역에서 채취한 저니토의 토양성분과 중금속 용출 특성을 분석하였다. 대부분의 저니토는 illite(I), kaolinite(Ka), quartz(Q) 및 feldspar(F)로 구성되어 있다. 저니토에 포함된 중금속 중 아연(Zn), 비소(As), 크롬(Cr), 구리(Cu), 납(Pb)의 농도는 임하호에 비하여 안동호에서 상대적으로 높게 나타났다. 특히 안동호의 저니토에서는 다른 중금속들에 비해 비소(As)와 아연(Zn)의 용출이 크게 나타났다. 저니토를 이용한 흡착실험에서는 아연(Zn), 카드늄(Cd) 및 구리(Cu)의 흡착은 적게 일어난 반면 납(Pb)과 크롬(Cr)은 높은 흡착력을 보여주었다.

• The Korean Journal of Ecology
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• 제21권3호
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• pp.225-231
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• 1998

The studies on the potentiality of biomonitoring heavy metal pollution in coastal region of industrial complex were performed to investigate the heavy metal accumulation and induction of metal-binding protein (MBP) as detoxification process using Rumex maritimus. Bioconcentration in organs and MBP in root of R. maritimus was investigated for the research of the tolerance of heavy metals. The bioconcentration of cadmium and zinc in organs showed 3.6-8.0 times in root higher than in shoot, so it was found that heavy metal accumulated selectively in root. MBP increased absorbance in 254 nm and decreased in 280 nm, because it was composed of high cystein content and low aromatic acids, so absorbance had large difference between 254 nm and 280 nm. The existence of MBP in the 10-20 fraction was ascertained with anion exchange chromatography and it was identified that concentration of heavy metal increased according as an exposure concentration of medium increased in QAE Sephadex A-25 elution profile. These results suggested that MBP could play a role in biomarker determining the bioconcentration of plant. This study demonstrated a possibility that removal ability of heavy metal of R. maritimus resulted from detoxification process and MBP could be utilized as a biomarker of heavy metal pollution.

• The Korean Journal of Ecology
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• 제22권2호
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• pp.95-100
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• 1999

The heavy metal concentrations in seawater and winkles (Littorina brevicula) collected from the Onsan bay area in southeast of Korea were analyzed. The heavy metal concentrations in the seawater obtained from the most polluted site showed approximately 189. 205. and 110 fold higher cadmium, copper. and zinc concentrations, respectively. than the uncontaminated control site. The contamination levels of these metals in winkles were 11.08 - 2.35, 334.5 - 212.5, and 426.0 - 499.2$\mu\textrm{g}$ per gram dry body weight. respectively. The concentrations of all three metals in both the seawater and winkles decreased gradually with increasing distance from Daejeong stream, suggesting the stream being the major source of heavy metal input into the bay. Among the four body parts of digestive gland and gonad. gill. kidney, and remaining tissue in contaminated winkles, kidney showed the highest accumulation level of cadmium: copper and zinc, however. were more or less distributed among the four body parts. Upon gel filtration chromatography of the cytosol from the kidney of cadmium induced winkles, one cadmium peak corresponded to the elution peak of horse kidney metallothionein.

• Environmental Engineering Research
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• 제10권5호
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• pp.205-212
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• 2005

The study was conducted to investigate the removal of heavy metals by using Hydroxyapatite(HAp) made from waste oyster shells and wastewater with high concentration of phosphorus. The maximum calcium concentration for the production of HAp in this study was released up to 361 mg/L at pH of 3 by elution experiments. When the pH was at adjusted 6, the maximum calcium released concentration was 41 mg/L. During the elution experiment, most of the calcium was released within 60 minutes. This reaction occurred at both pH levels of 3 and 6. The result of the XRD analysis for the HAp product used in this study shows the main constituent was HAp, as well as OCP. The pH was 8.6. As the temperature increased, the main constituent did not vary, however its structure was crystallized. When the pH was maintained at 3, the removal efficiency decreased as the heavy metal concentration increased. The order of removal efficiency was as follows: $Fe^{2+}$(92%), $Pb^{2+}$(92%) > $Cu^{2+}$(20%) > $Cd^{2+}$(0%). Most of these products were dissolved and did not produce sludge in the course of heavy metals removal. As the heavy metal concentration increased at pH of 6, the removal efficiency increased. The removal efficiencies in all heavy metals were over 80%. From the analysis of the sludge after reaction with heavy metals, the HAp was detected and the OCP peak was not observed. Moreover, lead ion was observed at the peaks of lead-Apatite and lead oxidant. In the case of cadmium, copper and iron ions, hydroxide forms of each ion were also detected.

• 한국환경과학회지
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• 제5권6호
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• pp.771-778
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• 1996

The sediment in the highly contaminated Gamjeon brook was collected, mixed with the raw material of the tile, and then the commercial tile was produced using the mixture. The concentrations of the heavy metals in the mixture-before and after the tile was produced-were analyzed and the effects of the acid solution on the produced tile were examined. The production of the tiles was successful and the result of heavy metal analysis showed that the concentration of Fe was the highest and that of Cd was the lowest The amount of heavy metal in the sediment - the raw material of the tile mixture was more than that of the produced tile. The elution concentration of the heavy metal by the acid solution(pH : 4 - 7) was low and the quality of the produced tile was better than the commercial tile. The result of this study suggested that the contaminated sediment was removed to produce good tiles, therefore the water pollution and soil pollution were reduced.

• 유기물자원화
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• 제8권3호
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• pp.97-103
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• 2000

본 연구는 용융고화 슬래그에 대한 중금속 용출실험 및 두께별 흡음율 특성에 따른 흡음재료로서의 활용가능성을 제시하기 위하여 수행되었다. 용융고화 슬래그를 대상으로 한 중금속 용출실험 결과, 중금속이 슬래그내로 안정화되어 용출되지 않았다. 용융고화 슬래그의 저주파 영역에서의 흡음특성은 공통적으로 600 Hz~l kHz 부근에서 최대 흡음을 나타냈고, 고주파 영역에서는 3 kHz 부근에서 최대 흡음을 나타냈다. 고주파 영역에서는 7 kHz 주파수 영역을 넘는 범위에서는 흡음율이 다시 증대하는 특징을 나타냈다. 용융고화 슬래그를 방음벽의 재료로 사용할 경우 저주파 및 고주파 영역내의 흡음율이 80% 이상의 흡음효과를 얻을 수 있는 것으로 나타났는데, 이는 흡음율 시험에 사용되는 시편의 두께에 의한 흡음특성을 고려한다면 다소 차이가 있을 수 있으나, 흡음재료로의 재활용에 가능한 물성값을 보유한 것으로 본 연구결과 흡음자재로 활용가능성이 높은 것으로 나타났다.