• 한국환경과학회지
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• 제22권1호
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• pp.59-72
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• 2013

The purpose of this study is to assess the effects of heavy metal concentrations in the blood and urine of the general population. This research had been conducted from April to December 2008, studying 545 residents of Daejeon and Chungcheong Province. Through the concentrations of heavy metals(Pb, Cd, Hg, As, Mn) in the biota samples and questionnaires, the residents heavy metal exposure level and the influential factors according to personal characteristics or lifestyle were evaluated. As to the heavy metal concentration in the blood and urine of the comparing region, were As and Mn statistically significant(p<0.01, p<0.05). Blood lead and urinary mercury concentrations were higher in males than females. The heavy metal concentration for each age group increased blood mercury. The concentration of all heavy metals were higher in the drinkers than in the non-drinkers. Blood lead and mercury concentrations were higher in the smokers than in the non-smokers, but the urinary cadmium, arsenic and blood manganese was higher in the non-smokers than in the smokers. As to the blood lead and urinary cadmium concentration according to the food preference fish showed high concentration. To clarify the factors affecting the heavy metal concentration in biota among subjects multiple regression analysis was conducted. As a results, it turned out that as to lead content in blood, sex, age and smoking have influence on the subjects with explanatory adequacy of 14.0 %. These results demonstrated that the factors affected the concentrations of heavy metals in blood and urine. The results of this study could be used as the foundational data for setting the health risk assessment.

• 한국환경농학회지
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• 제16권2호
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• pp.115-118
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• 1997

When the light metals such as $Ca^{++}$ and $Mg^{++}$ were added to heavy metal solution, the adsorption of heavy metals was increased by 20 to 30% more, but there were no differences between species. $Pb^{++}$ was the most adsorbed metal(99.5%), and the adsorption ratio of $Cd^{++}$ was significantly improved. In addition, when the light metal concentration was increased to 100ppm, the adsoption ratios of all four heavy metals were reached to 92 to 99%, while coniferous barks showed only 85 to 92%. On the mixture of four heavy metals, the adsorbed amount of each metal was significantly reduced, compared with that of one heavy metal, while $Zn^{++}$ showed the adsorption improvement to 95%. On the column experiment, $Pb^{++}$ was almost completely adsorbed in the upper part of column, and the adsorbed amount of $Cu^{++}$ was gradually decreased depending on column depth. However, $Cd^{++}$ and $Zn^{++}$ were not influenced by column height, and constantly adsorbed on various column height. Based on the above results, each heavy metal had different adsorption mechanism.

• 생명과학회지
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• 제19권11호
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• pp.1562-1567
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• 2009

안동호와 임하호의 수환경내 중금속의 오염정도와 서식 어종간의 중금속 축적 정도를 알아보기 위해 양호수의 수질, 저니 및 서식어종인 붕어를 이용하여 중금속 함량을 비교 분석하였다. 안동호와 임하호 수질과 저니내 중금속 함량은 안동호에서 높은 함량을 보이며, As는 함량의 차이가 큰 것으로 나타났다. 안동호와 임하호에 서식하는 붕어의 중금속 함량의 경우 안동호에 서식하는 붕어에서 높은 함량을 보이며, Cr, Cu, Cd 및 As는 함량의 차이가 큰 것으로 나타났다. 또한 비늘, 근육, 뼈 조직은 안동호와 임하호의 함량차이가 크며, 안동호에서 높은 함량을 나타냈다. 본 연구의 결과 안동호와 임하호의 수질과 저니 및 서식어종인 붕어의 중금속 함량은 안동호에서 임하호보다 중금속 함량이 높게 나타났으며, 안동호와 임하호의 함량차이도 큰 것으로 나타났다. 이는 안동호의 경우 안동호 상류 지점의 폐광산과 농경지로부터 하상퇴적물이 유입되어 하상퇴적물 속에 포함된 유기물을 붕어가 먹이로 섭취함으로써 중금속 함량에 영향을 미친 것으로 생각된다.

• 한국토양비료학회지
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• 제49권6호
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• pp.768-775
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• 2016

Heavy metal pollution in arable field is an critical problem due to crop safety. For this reason, national survey of heavy metal pollution in the arable field near at the industrial area has been conducted from 1999 in Korea. The main purpose of this research was to monitor heavy metal pollution in Chungnam/chungbuk province and to evaluate pollution index (PI) in soil. Total of 15 sampling locations were examined and average concentration of each heavy metals were following: As - $2.99{\pm}2.63$, Cd - $0.23{\pm}0.07$, Cu - $9.35{\pm}6.48$, Ni - $9.26{\pm}8.03$, Pb - $10.18{\pm}3.32$, Zn - $52.9{\pm}17.18$. No sampling site was exceeded threshold level of each heavy metals. Calculated PI in soil was ranged between 0.03 - 0.27 indicating that also no heavy metal pollution is occurred in examined sampling locations. Although, no heavy metal pollution was observed in the examined sites but monitoring of heavy metal pollution should be continued for possible accidental pollution in arable field near at the industrial area.

• 환경위생공학
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• 제13권1호
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• pp.174-184
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• 1998

Biosorption characteristics were investigated to discuss the use of agar entrapped Spirulina to remove of heavy metal ions from polluted waters. Agar immobilized algae were used as bioadsorbent in continuous reactor for heavy metal ions removal. The process solution contains Pb, Cu, and Cd as single ion and binary ions. In the adsorption of single heavy metal ions by agar immobilized Spirulina, the adsorption reached within 1hr and observed diffusion limitation differed from the free algal cell adsorption. The optimum pH for the adsorption of heavy metals was 4.5 but the influence of pH decreased less than that of free algal cell. Also, the adsorption characteristics of single heavy metal ions with agar immobilized Spirulina fitted the BET isotherm. Both of experiments of free algal cell and agar immobilized algae showed higher removal efficiency in the single ion solutions than binary ions solutions. The experimental results in the packed column with agar immobilized algae were over 90% of removal efficiency for the Pb, Cu, and Cd in single ion solutions.

• 자원환경지질
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• 제30권2호
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• pp.123-135
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• 1997

In order to investigate the dispersion patterns and contamination level of heavy metals in the soil-ecosystem and to evaluate the efficiency of soil remediation by reversed soil method, soils and plants were collected from the Dongjin Au-Ag-Cu mine area and analysed for heavy metals. The dispersion patterns of heavy metals in soils and plants show that heavy metal pollutions caused by waste rump around Dongjin mine are mainly found in the vicinity of the waste rump and in the southward slanting of mine. Toxic metallic pollutants from the mine influence heavy metal contents in paddy soils in downstream area, and may be a potential sources of heavy metal pollution on crop plants. Soil samples collected from the remediated rice farming field by reversed method show similar levels of heavy metal content to those from the polluted rice farming field, but topsoil enrichment of heavy metals are not found. Heavy metal contents of the rice plants collected from remediated rice farming field are significantly lower than those from polluted rice farming field, and it suggests that the reversed soil method is effective for the reduction of bioavailability of heavy metals.

• 한국환경과학회지
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• 제5권2호
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• pp.195-201
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• 1996

This study was conducted for the efficient utilization of a scoria, which is abundantly found in Cheju island, as adsorbent and the scoria was examined for its performance in clarification of adsorption of heavy metal ions. The order in heavy metal ions adsorbed on scoria was; Pb+>Cd^{2+}$>Cu^{2+}$>Ag^+$>Co^{2+}$>Zn^{2+}$>Cr^{3+}$>Cr^{6+}$. This tendency was relatively consistent with the decreasing order of radius of hydrated metal ion. Also, the smaller scoria size and the larger amounts of scoria showed higher removal efficiency for heavy metal ions. The same scoria size showed more effective removal efficiency for heavy metal ions at lower initial concentration than at higher initial concentration. The adsorption abilities of original scoria and chemically treated scoria were compared. Adsorption isotherm of scoria was generally obeyed to Freundlich formula than langmuir formula and Freundlich constant, than was obtained in the range of 0.2~0.4.

• 한국환경과학회지
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• 제8권2호
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• pp.197-204
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• 1999

The extent of heavy metal pollution in agricultural in soils near the abandoned mine land site was investigated using their concentrations from the 47 sampling sites in B mine. Samples were prepared using 0.1N HCI - Korean Standard Methods - and then analysed for Cd, Cu, Pb, As and Cr by Inductively Coupled Plasma Spectrometer. In addition, soil and mine tailing samples were sequentially extracted to investigate the chemical speciation of heavy metals in them. The soils in the vicinity of mining area are highly contaminated by heavy metals ranging up to 5.96mg Cd/kg, 253.3mg Cu/kg, 76.7mg Pb/kg, and 15.45 mg As/kg, according to the analysis of Korean Standard Methods. The heavy metal levels by the sequential extraction are much higher than its level by Korean Standard Methods, and little correlated with each other. Based on the results, it is suggested that the As pollution in agricultural soils near the AMLS should be dealt as of prior significance in establishing reclamation strategies for the area.

• 한국환경복원기술학회지
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• 제8권5호
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• pp.39-46
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• 2005

This study was conducted to investigate the heavy metal accumulation in wild plants. The samples from 5 plant species on 14 sites were taken on the roadside where urban and industrial regions in northern Gyeonggi do. Artemisia princeps var. orientalis, Chenopodium album L. var. centrobrum, Erigeron canadensis L., Rumex crispus L. and Taraxacum platycapum H. Dahlst were taken from different parts of the plants gathered in surveyed sites for analysing. This study classified which species were suitable to accumulators, excluders, or indicators which were provided as Phytoremediation for heavy metals(Cd, Cr, Ni, Pb and Zn) and considered the applicability of that work. 1. The mean accumulation of 6 heavy metals in plants was as follows; Zn> Cu> Cr> Pb> Ni> Cd in rows except for Ni and Pb in Erigeron. 2. The highest heavy metal accumulators were Taraxacum and Artemisia. 3. The comparison of heavy metal accumulations between the tops and roots in the plants was as follows; Zn> Cd> Pb> Ni> Cu> Cr. 4. Comparison of heavy metal accumulations between tops and roots, root parts were higher than the top parts in most of the plants. Especially, in Taraxacum, a ratio was over 1.0 in Cr, Ni, and Zn. Therefore, Taraxacum was an accumulator for 3 heavy metals. And Erigeron, Chenopodium, Rumex, Artemisia were good for excluders which had lower than 1.0.

• Environmental Analysis Health and Toxicology
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• 제14권4호
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• pp.155-163
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• 1999

Heavy metal accumulation in living organisms through food-wed can give serious damage on physiological responses for vital activities. The initiation of heavy metal supposed to begin from the bio-accumulation of plants. To establish basic data fur heavy metal contents in plants at the area without artificial contamination, both woody and herb plants at Mt. Kwang-Duk were studied. The content of heavy metals in various organs of plants were analyzed by ICP. The range of heavy metals in plants for Al, As, Cd, Co, Cr, Cu, Fe. Mn, Pb, Se and Zn were 1.019∼257.200ppm, O∼2.929ppm, 0∼0.079ppm, 0∼0.054ppm, 0.023∼3.007ppm, 0∼1.997ppm, 2.031∼148.500ppm, 1.069∼51.320ppm, O∼126.900ppm, 0.708∼4.927ppm and 0.846∼4.949ppm, respectively. The amount of heavy metals in plants are much less than that of soil except some species. In woody plants, it was detected that the metal contents of leaves were higher than that of stems especially in case of Al and Fe with statistical significance. There were significant differences between shoots and roots of herb plants in metal content of Al, Co and Fe. Those metals have more accumulated in roots comparing with shoots. Some species of plants had shown the difference tendency of heavy metal accumulation. Generally, most species had not exceeded over twice of mean value each other, and had various difference according to the kinds of heavy metals.