• Title/Summary/Keyword: heavy metal Pb

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The Quality Characteristic of Pearls Produced at Pearl oyster, Pinctada fucata cultured in Tongyeong (통영해역의 진주조개, Pinctada fucata에서 생산된 진주의 품질특성)

  • Seo, Jin-Hyung;Lee, Sang-Jun;Jeong, Woo-Geon;Cho, Sang-Man
    • The Korean Journal of Malacology
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    • v.28 no.3
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    • pp.245-254
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    • 2012
  • This project analyzes distinct qualities of pearl cultured in Tongyeong by physical, chemical and optical test. The result is to provide scientific data for the value of pearl from Korean seawater. It divides one year pearl, which is used as a sample in the project, into white, natural blue and yellow gold colors, and then it has been divided into A, B and C based on the quality of the last results. A chemical experiment demonstrates that the higher quality has lower protein content of less than 10%. In another test called heavy metal content test, there is no big difference among classes. In the characterization of spectroscopy, it shows 280 nm peak indicated the conchiolin. It is clear that 407 nm, 430 nm and 460 nm peak are White group that are not in processed condition.

Pollution of Heavy Metals and Sedimentation Rates in Sediment Cores from the Chinhae Bay, Korea (진해만 퇴적물의 퇴적속도와 중금속 오염)

  • Yang, Han-Soeb;kim, Seong-Soo;Kim, Gue-Buem
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.103-103
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    • 1995
  • In the Chinhae Bay, Korea, sedimentation rates and sedimentary record of anthropogenic metal loads were determined by $^{210}Pb$ dating and heavy metal analysis of four sediment cores . The sedimentation rates varied from 0.16g/$cm^2$/yr(3.1mm/yr) at Sta. Ct, located within narrow waterway to 0.24g/$cm^2$/yr(4.8mm/yr) at Sta. Cl, located in Haengam Bay. Maximum contents of Mn, Zn, Cu and Cr were observed at Sta. C2 located near the mouth of Masan Bay, while minimum contents were observed at Sta. CB. Mn/Fe ratios at Sta. C2 and Sta. C4 showed gradually increasing and decreasing downward, respectively, in the upper layer of sediment cores. This suggests that Mn may be diagenetically redistributed in highly reduced environment. At Sta. C2, the concentrations of Zn and Cu began to increase from 1920s by anthropogenic input and have been remarkablely increasing since mid 1960s. At Sta. C3, located near Sungpo, anthropogenic input of these two elements has also slightly increased after 1970s. However, pollution of these two elements was not significant in Haengam Bay(Sta. Cl) and Chiljun watenway(Sta. C4). The pollution of Co, Ni and Cr was not remarkable in all core samples except surface sediment of Sta. C2. The total input of anthropogenic Zn and Cu since 1920s was estimated to be 28∼792 ㎍/cm2 and 0∼168㎍/cm2, respectively. Sta. C2 showed remarkablely higher values relative to other stations: anthropogenic loads of Zn and Cu constituted 27% and 29% of the total sedimentary inventories at the present day, respectively. Fe, Ni, Cr and Co contents showed good correlation(r>0.8) with each other. Anthropogenic Zn and Cu also showed a very good positive correlation(>0.9). However, correlation between these two group of element was quite scattered, indicating different sources and geochemical behaviors.

Pollution of Heavy Metals and Sedimentation Rates in Sediment Cores from the Chinhae Bay, Korea (진해만 퇴적물의 퇴적속도와 중금속 오염)

  • Yang, Han-Soeb;kim, Seong-Soo;Kim, Gue-Buem
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.489-500
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    • 1995
  • In the Chinhae Bay, Korea, sedimentation rates and sedimentary record of anthropogenic metal loads were determined by $^{210}Pb$ dating and heavy metal analysis of four sediment cores . The sedimentation rates varied from 0.16g/$cm^2$/yr(3.1mm/yr) at Sta. Ct, located within narrow waterway to 0.24g/$cm^2$/yr(4.8mm/yr) at Sta. Cl, located in Haengam Bay. Maximum contents of Mn, Zn, Cu and Cr were observed at Sta. C2 located near the mouth of Masan Bay, while minimum contents were observed at Sta. CB. Mn/Fe ratios at Sta. C2 and Sta. C4 showed gradually increasing and decreasing downward, respectively, in the upper layer of sediment cores. This suggests that Mn may be diagenetically redistributed in highly reduced environment. At Sta. C2, the concentrations of Zn and Cu began to increase from 1920s by anthropogenic input and have been remarkablely increasing since mid 1960s. At Sta. C3, located near Sungpo, anthropogenic input of these two elements has also slightly increased after 1970s. However, pollution of these two elements was not significant in Haengam Bay(Sta. Cl) and Chiljun watenway(Sta. C4). The pollution of Co, Ni and Cr was not remarkable in all core samples except surface sediment of Sta. C2. The total input of anthropogenic Zn and Cu since 1920s was estimated to be 28~792 $\mu\textrm{g}$/cm2 and 0~168$\mu\textrm{g}$/cm2, respectively. Sta. C2 showed remarkablely higher values relative to other stations: anthropogenic loads of Zn and Cu constituted 27% and 29% of the total sedimentary inventories at the present day, respectively. Fe, Ni, Cr and Co contents showed good correlation(r>0.8) with each other. Anthropogenic Zn and Cu also showed a very good positive correlation(>0.9). However, correlation between these two group of element was quite scattered, indicating different sources and geochemical behaviors.

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Vertical Variation of Sediment Structure and Geochemical Characteristics of Core Sediment in Nakdong River Midstream (낙동강 중류의 주상퇴적물에서 나타나는 퇴적 구조와 지화학적 특성의 수직적 변화)

  • Kim, Shin;Lee, Kyu Yeol;Kim, Ju Eon;Lee, Kwon Chul;Ahn, Jung Min;Lee, Injung;Jung, Kang Young;Im, Tae Hyo
    • Journal of Korean Society on Water Environment
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    • v.31 no.3
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    • pp.304-312
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    • 2015
  • In this study, we tried to determine the vertical variation of sediment structure and geochemical characteristics, core sediment was collected in the Nakdong River midstream on August, 2014. Core sediment mainly composed of sand (51.48%) and silt (46.21%) and coarsing upward changed from sM to mS facies. IL and TOC were decreased from lower to upper layer. C/N ratio was lower than 10 so the organic matters were originated from underwater creatures and C/S ratio was decreased from lower to upper layer. Heavy metal (Al, Fe, Zn, Cr, Pb, Ni, Cu, Cd) content were decreased from lower to upper layer and seriously polluted condition is not. These results are thought to be due to the effect of natural and anthropogenic in the fluctuation of flow.

Seasonal Variation in Heavy Metal Removal Efficiency and Application of Risk Assessment for Constructed Wetlands (인공습지에서 중금속 제거율의 계절적 변동 및 위해성평가)

  • Shin, Yu-Ri;Yoon, Chun-Gyeong;Son, Yeong-Kwon;Kim, Hyung-Joong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.52 no.6
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    • pp.57-62
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    • 2010
  • 본 연구는 자유수면형 인공습지에서의 시기적인 중금속 제거율의 변동을 평가하기 위하여 수행되었다. 대상 인공습지의 유입수는 하수처리수가 포함된 하천수이다. 인공습지에는 갈대 (Phragmites australis)와 부들 (Typha latifolia)이 주로 분포하며, 이들 두 종은 습지의 95 % 이상을 차지하는 우점종이다. 2009년 5월부터 9월까지 습지의 유입과 유출부분에서 유입수와 유출수를 시료 채취하였다. 채취된 시료는 ICP-AES 방법을 이용하여 6가지 중금속을 분석하였으며, 위해성 평가를 이용하여 카드뮴 (Cd), 크롬 ($Cr^{+6}$), 비소 (As), 납 (Pb), 니켈 (Ni), 구리 (Cu)의 분석 결과를 평가하였다. 위해성평가는 농부와 레크리에이션에 대한 두가지 시나리오를 바탕으로 이루어졌다. 연평균 중금속 제거율은 계절적인 변화 측면에서 큰 변화를 나타내지 않았다. 위해성 평가 결과 시료가 채취된 부분 및 계절적인 변화 대부분에서 US EPA의 기준인 $10^{-4}$를 초과하지 않는 수준으로 허용가능한 수준이었다. 하지만, 봄철 농부에 대한 위해성평가 결과 위해도가 $10^{-4}$ 수준이며, $10^{-6}-10^{-8}$ 수준은 질병의 이동이 우려되는 수준 (US EPA)임을 감안하여, 인공습지에 중금속 농도 저감 시설의 설치를 고려해야 한다. 본 연구에서는 위해성 평가를 가상의 시나리오에 적용하여 평가를 시도함으로서, 수치적인 자료로 제시할 수 있을 뿐만 아니라 중금속의 정량적인 평가를 수행할 수 있었다. 따라서 위해성 평가는 인공습지의 안전성에 대하여 대중과 소통할 수 있는 도구로서 이용할 수 있으며, 인공습지의 효율적인 운영 및 현장 적용에 있어서 스크리닝 도구로서의 역할이 가능할 것으로 판단된다.

Effect of cold plasma treatment on the quantitative compositions of silkworm powder

  • Jo, You-Young;Seo, YoungWook;Lee, Young Bo;Kim, Seong-Ryul;Kweon, HaeYong
    • International Journal of Industrial Entomology and Biomaterials
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    • v.38 no.2
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    • pp.25-30
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    • 2019
  • Atmospheric-pressure plasma technique is a technology for sterilizing agricultural product. In this study, dielectric barrier discharge plasma was applied to silkworm powder for 1 to 5 h with less than 2 ppm of $O_3$ and $NO_2$. Quantitative compositions including proximate contents, mineral and heavy metal contents, fatty acids, vitamins, and DNJ contents were measured. Proximate contents of silkworm powder were protein (57.2%), fat (9.9%), fiber (4.6%), ash (10.1%), and moisture (5.7%). These compositions were not affected by the treatment of plasma. Silkworm powder has 5 abundant minerals potassium (K), phosphorus (P), sulfur (S), calcium (Ca), and magnesium (Mg). Among these minerals, plasma treatment decreased the contents of P and S sharply from 732.3 to 176.8, and 492.7 to 185.2 mg/100g, respectively. Heavy metal contents including lead (Pb), cadmium (Cd), arsenic (As), and mercury (Hg) were not detected in the silkworm powder. Five vitamins such as ascorbic acid (13.6 mg/100g), riboflavin (5.4 mg/100g), ${\beta}$-carotene (1.8 mg/100g), niacin (0.6 mg/100g), and thiamine (0.4 mg/100g) were not significantly changed by plasma treatment. Silkworm powder is composed of 30 parts saturated fatty acids and 70 parts unsaturated ones. The fatty acid composition was not significantly changed by plasma treatment. The DNJ content of silkworm powder (3.72 mg/g) was also nearly constant within the experimental condition of plasma treatment.

A Study on Environmental Impact Assessment and Improvement Measures Around Construction Waste Intermediate Processing Sites in Rural Areas (농촌지역의 건설폐기물 중간처리 사업장 주변 환경 영향 평가 및 개선방안 연구)

  • Jang, Kyong-Pil;Kim, Byung-Yun
    • Journal of the Korean Institute of Rural Architecture
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    • v.26 no.2
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    • pp.65-72
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    • 2024
  • In order to analyze the impact of fine dust generated from a construction waste intermediate processing site on the surrounding areas, diverse types of samples were collected from inside the site and surrounding areas. The impact analysis results of samples are as follows. (1) Compared to the air quality management standards by the Ministry of Environment, the concentration of fine dust within the site was 30 to 46% for PM10 and 14 to 42% for PM2.5, which was not much different from the general air quality level. (2) It was found that PM10 within the site may have a partial effect on the air quality, but when the blocking facilities in the site, wheel washing facilities at vehicle entry and exit route, and sprinkler during working were maintained, the impact on the nearby area was not high. (3) In the case of PM2.5, its concentration was influenced more by the exhaust fumes from work vehicles than fine dust generated during construction waste processing. Since the PM2.5 concentrations in the site and surrounding area were not much different from the general air quality, there was little correlation with the work impact of construction waste intermediate processing sites. (4) Pb, an indicator of heavy metal components, was within 50ng/m3 in all three sites, which was 10% of the domestic management standard and equivalent to the general air quality level. The complaints from residents in nearby areas were filed using indicators based on visual and experiential information in their daily lives, so even if the survey results of environmental impact by the construction intermediate waste processing site are lower than the standard, nearby residents can feel it better than such numerical information. Therefore, specific activities to reduce find dusts should be continuously continued.

Characteristics of Heavy Metal Distribution in Surface Sediments from the south Sea of Korea (남해 대륙붕 표층퇴적물 중 중금속 원소의 분포 특성)

  • 조영길;이창복
    • 한국해양학회지
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    • v.29 no.4
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    • pp.338-356
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    • 1994
  • Sediment samples from the continental shelf of the South Sea of Korea are analysed to determine the concentration of Al, Fe, Mn, cu, Ni, Zn, Co, Cr and Pb. among these samples, fine-grained sediments were also analysed by a sequential extraction technique to know geochemical forms of the metals in this environments. The total concentration of Al, Fe, Cr, Ni, Cu and Zn in bulk sediments decreased gradually with the increase of distance from the coastal zone. This distribution patterns are well coincide with grain size distribution. However, the patterns of Mn, co and Pb do not follow such and overall distribution. The concentration of Pb, particularly, did not show any features in areal distribution, which may be result from different pathways to the sediments, compared to the other metals. the speculation data show that a considerable amount of Cd, Mn and Co are bounded in the carbonate fraction, accounting for 42.8%, 40.3% and 30.6%, respectively. Cu, Zn, Mn and Fe are largely associated to oxide fraction with proportions of 34.4%, 23.1%, 15.5% and 13.7%, respectively. However, the metals in residual fraction account for more than 50% of the total metal concentration, except for Mn. These observations emphasize that residual fraction in the dominant component controlling the elemental concentration.quartz and glauconite grains.Accordingly,these sediments are interpreted as an extension part of transgressive sand deposit that are widely distributed on the continental shalf floor of southern Yellow Sea.

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A Study on the Changes in Heavy Metal Emissions when Using Mixed Fuel in a Thermal Power Plant (화력발전소의 혼합연료 사용에 따른 중금속 배출량 변화 연구)

  • Song, Youngho;Kim, Ok;Park, Sanghyun;Lee, Jinheon
    • Journal of Environmental Health Sciences
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    • v.44 no.1
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    • pp.63-75
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    • 2018
  • Objectives: The aim of this research is to explore the total heavy metals from a coal-fired power plant burning bituminous coal with wood pellets due to the implementation of the Renewable Portfolio Standard policy (RPS, 10% of electricity from renewable energy resources by 2023). Methods: The research was carried out by collecting archival data and using the USEPA's AP-42 & EMEP/EEA compilation of emission factors for use in calculating emissions. The Monte Carlo method was also applied for carrying out the calculations of measurement uncertainty. Results: In this paper, the results are listed as follows. Sb was measured at 110 kg (2015) and calculated as 165 kg (2019) and 201 kg (2023). Cr was measured at 1,597 kg (2015) and calculated as 1,687 kg (2019) and 1,728 kg (2023). Cu was measured at 2,888 kg (2015) and calculated as 3,133 kg (2019) and 3,264 kg (2023). Pb was measured at 2,580 kg (2015) and calculated as 2,831 kg (2019) and 2,969 kg (2023). Mn was measured at 3,011 kg (2015) and calculated as 15,034 kg (2019) and 23,014 kg (2023). Hg was measured at 510 kg (2015) and calculated as 513 kg (2019) and 537 kg (2023). Ni was measured at 1,720 kg (2015) and calculated as 1,895 kg (2019) and 1,991 kg (2023). Zn was measured at 7,054 kg (2015) and calculated as 9,938 kg (2019) and 11,778 kg (2023). Se was measured at 7,988 kg (2015) and calculated as 7,663 kg (2019) and 7,351 kg (2023). Conclusion: This shows that most heavy metals would increase steadily from 2015 to 2023. However, Se would decrease by 7.9%. This analysis was conducted with EMEP/EEA's emission factors due to the limited emission factors in South Korea. Co-firewood pellets in coal-fired power plants cause the emission of heavy metals. For this reason, emission factors at air pollution control facilities would be presented and the replacement of wood pellets would be needed.

Determination of Mineral and Heavy Metal Contents of Various Salts (소금의 종류별 무기질 및 중금속 함량)

  • Park, Jeong-Wook;Kim, Seon-Jae;Kim, Sul-Hee;Kim, Bo-Hee;Kang, Seong-Gook;Nam, Sang-Ho;Jung, Soon-Teck
    • Korean Journal of Food Science and Technology
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    • v.32 no.6
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    • pp.1442-1445
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    • 2000
  • This study was carried out to investigate the contents of minerals and heavy metals in the sea salts of Korean products and imported products. NaCl was major component, which ranged from $80.31{\sim}89.84%$ for Korean products and from $91.59{\sim}97.66%$ for imported products. Minerals and heavy metals of Korean products and imported products were analyzed with ICP-AES and AAS, respectively. Mineral contents of K and Mg in Korean products were relatively higher than those in imported ones, but no significant differences were found for heavy metals between them.

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