• Title/Summary/Keyword: heavy alloy

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Hard TiN Coating by Magnetron-ICP P $I^3$D

  • Nikiforov, S.A.;Kim, G.H.;Rim, G.H.;Urm, K.W.;Lee, S.H.
    • Journal of the Korean institute of surface engineering
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    • v.34 no.5
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    • pp.414-420
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    • 2001
  • A 30-kV plasma immersion ion implantation setup (P $I^3$) has been equipped with a self-developed 6'-magnetron to perform hard coatings with enhanced adhesion by P $I^3$D(P $I^3$ assisted deposition) process. Using ICP source with immersed Ti antenna and reactive magnetron sputtering of Ti target in $N_2$/Ar ambient gas mixture, the TiN films were prepared on Si substrates at different pulse bias and ion-to-atom arrival ratio ( $J_{i}$ $J_{Me}$ ). Prior to TiN film formation the nitrogen implantation was performed followed by deposition of Ti buffer layer under A $r^{+}$ irradiation. Films grown at $J_{i}$ $J_{Me}$ =0.003 and $V_{pulse}$=-20kV showed columnar grain morphology and (200) preferred orientation while those prepared at $J_{i}$ $J_{Me}$ =0.08 and $V_{pulse}$=-5 kV had dense and eqiaxed structure with (111) and (220) main peaks. X-ray diffraction patterns revealed some amount of $Ti_{x}$ $N_{y}$ in the films. The maximum microhardness of $H_{v}$ =35 GN/ $M^2$ was at the pulse bias of -5 kV. The P $I^3$D technique was applied to enhance wear properties of commercial tools of HSS (SKH51) and WC-Co alloy (P30). The specimens were 25-kV PII nitrogen implanted to the dose 4.10$^{17}$ c $m^{-2}$ and then coated with 4-$\mu\textrm{m}$ TiN film on $Ti_{x}$ $N_{y}$ buffer layer. Wear resistance was compared by measuring weight loss under sliding test (6-mm $Al_2$ $O_3$ counter ball, 500-gf applied load). After 30000 cycles at 500 rpm the untreated P30 specimen lost 3.10$^{-4}$ g, and HSS specimens lost 9.10$^{-4}$ g after 40000 cycles while quite zero losses were demonstrated by TiN coated specimens.s.

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Interfacial Properties and Stress-Cure Sensing of Single-Shape Memory Alloy (SMA) Fiber/Epoxy Composites using Electro-Micromechanical Techniques (미세역학적 시험법을 이용한 단-섬유 형태 형상기억합금/에폭시 복합재료의 계면특성 및 응력-경화 감지능)

  • Jang, Jung-Hoon;Kim, Pyung-Gee;Wang, Zuo-Jia;Lee, Sang-Il;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.9 no.3
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    • pp.20-26
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    • 2008
  • It is well know that the structure of shape memory alloy (SMA) can change from martensite austenite by either temperature or stress. Due to their inherent shape recovery properties, SMA fiber can be used such as for stress or cure-monitoring sensor or actuator, during applied stress or temperature. Incomplete superelasticity was observed as the stress hysteresis at stress-strain curve under cyclic loading test and temperature change. Superelasticity behavior was observed for the single-SMA fiber/epoxy composites under cyclic mechanical loading at stress-strain curve. SMA fiber or epoxy embedded SMA fiber composite exhibited the decreased interfacial properties due to the cyclic loading and thus reduced shape memory performance. Rigid epoxy and the changed interfacial adhesion between SMA fiber and epoxy by the surface treatment on SMA fiber exhibited similar incomplete superelastic trend. Epoxy embedded single SMA fiber exhibited the incomplete recovery during cure process by remaining residual heat and thus occurring residual stress in single SMA fiber/epoxy composite.

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Effects of Cu and Mg on Wear Properties of SiC Particulate Reinforced Al-Si Metal Matrix Composites (SiC 입자강화 Al-Si 복합재료의 내마멸성에 미치는 Cu , Mg의 영향)

  • Shim, Shang-Han;Chung, Yong-Keun;Park, In-Min
    • Journal of Korea Foundry Society
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    • v.10 no.1
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    • pp.43-49
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    • 1990
  • The influences of Cu and Mg addition on wear properties of SiC particulate reinforced Al-Si metal(alloy) matrix composites were investigated. Metal matrix composites were prepared by combination of compocasting and hot pressing techniques. The main results obtained are as follows : 1) The composite with Mg addition exhibits letter wear resistance than that with Cu addition. It is considered that Mg addition improved wettability of matal matrix composite by the strong segregation to the SiC / Al matrix interface. 2) After homogenization treatment, it was found that the interfacial segregation of Mg was predominant, while that of Cu was not detected. 3) The SiC / Al-11Si eutectic composite exhibits better wear resistance than the SiC / Al-6Si hypoeutectic composite does. 4) It seems that the increase in the amount of Mg addition affects on the uniform dispersion of SiC particulates, on the refinement of microstructure and on age hardening and these effects cause wear resistance improvement of composites.

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The relation between physical/mechanical properties md ballistic properties in several engineering ceramics (세라믹스의 물리/기계적 물성과 방탄물성과의 상관관계 연구)

  • Kim Cheol-soo;Lee Hyung-Bock
    • Composites Research
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    • v.18 no.6
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    • pp.34-39
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    • 2005
  • In this study, we analyzed the relation between physical/mechanical properties and ballistic properties for several engineering ceramics that were expected to use as armor material. After physical/mechanical measurement, we measured ballistic properties about KE(Kinetic Energy, L/D=10.7, tungsten heavy alloy) and HEAT(High Explosive Anti-Tank, K215) projectiles. Increasing Young's modulus/density, hardness/density and flexural strength/density ratios, ballistic properties were generally increased. Especially it appeared that the ballistic property about KE projectile was lineally increased, as HEL/density ratio increased.

Synthesis of Alumina-Silica ceramic armor materials(I) (알루미나-실리카계 세라믹복합체 방탄재료 연구(I))

  • Kim Cheol-soo;Lee Hyung-Bock
    • Composites Research
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    • v.18 no.6
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    • pp.40-47
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    • 2005
  • In this study, we tried to invent ceramic armor material with brilliant ballistic properties by the silica of the high compression-expansion ratio and based on alumina that has the most economical and higher ballistic efficiency. After we choose three compositions, proper sintering temperature for each composition was decided. After physical/mechanical measurement, we measured ballistic properties about KE(Kinetic Energy, L/D=10.7, tungsten heavy alloy) and HEAT(High Explosive Anti-Tank, K215) projectiles. As a result, $46\%\;Al_2O_3\;-\;51\%\;SiO_2$ of three compositions had the highest ballistic efficiency md better properties than alumina.

Study on the Dislocation Behavior during Creep in 12% Chromium Steel (12% Cr 강의 크리이프중 전위거동에 관한 연구)

  • Oh, Sea-Wook;Jang, Yun-Seok
    • Journal of Ocean Engineering and Technology
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    • v.4 no.2
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    • pp.262-262
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    • 1990
  • In order to check the effect of dislocation behavior on creep rate in 12% Chromium steel, 14 samples of different compositions were examined by creep rupture test, and subgrain sizes, distribution of dislocations and precipitates were checked. And, authors reviewed the behaviors of dislocations, the formation and growth of subgrains and precipitates during creep. The results are as the following: 1) Creep rates calculated by .epsilon. over dot = .rho.bv show 10-15% higher values than actual data measured. However, authors conclude that the density and velocity of dislocations together with subgrain size are important factors governing deformation during creep in 12% chromium steel. 2) The values of the strength of obstacles in the mobility of dislocations are more clearly depended on the effective stress in the range of $10{\pm}5kgf/mm^{2}$ and increase with the increase of temperature. 3) Creep rates decrease with the smaller sizes of subgrains formed and can result in the longer creep rupture lives(hours). The smaller subgrains can be made by forming shorter free gliding distances of dislocations with very fine precipitates formed in the matrix during creep by applying proper alloy design. 4) Dislocation mobility gets hindered by precipitates occurring, which are coarsened by the softening process governed by diffusion during long time creep.

Development of Shrink-Fit Tool Holder using Shape Memory Alloys (형상기억합금을 이용한 열박음 공구홀더 개발)

  • Shin, Woo-Cheol;Ro, Seung-Kook;Kim, Byung-Sub;Park, Jong-Kweon
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.19 no.6
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    • pp.889-894
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    • 2010
  • Conventional shrink-fit tool holders have positive features, such as high accuracy, high strength, high stiffness and low sensitivity to centrifugal forces, but they require heavy investments for heating and cooling equipment. Generally the heating equipment has to heat the tool holder up to $200{\sim}300^{\circ}C$ for tool changes. This paper introduces a novel shrink-fit tool holder that is able to unclamp a tool at $40{\sim}50^{\circ}C$. This feature makes it possible to switch between the clamped and unclamped states by using a simple device, which has lower power, smaller size and lower cost than the heating equipment of the conventional shrink-fit tool holders. The proposed shrink-fit tool holder is able to expand its tool hole by using the shape memory alloys which are integrated in the tool holder body. Performances of the SMA shrink-fit tool holder were evaluated experimentally. The experimental results confirm that the proposed tool holder is feasible in aspects of clamping/unclamping operations, clamping force and repeatability of tool setup.

A Study of Localization with Material Properties Using Numerical Method (재료의 특징에 따른 국부화에 대한 수치해석적 연구)

  • 황두순;이병섭;이용성;윤수진;홍성인
    • Transactions of Materials Processing
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    • v.9 no.4
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    • pp.395-403
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    • 2000
  • Formation of Shear Band under the adiabatic condition is widely observed In the engineering materials during rapidly forming process lot a thermally rate-dependent material. The shear band stems from evolution of a narrow region in which an intensive plastic flow occurs. The shear band often plays a role of a precursor of the ductile fracture during a forming process. The objective of this study is to investigate the localization behavior using numerical method. In this work, the implicit finite difference scheme is employed due to the ease of convergence and the numerical stability It is noted that physical and mechanical properties of materials determine how the shear band is formed and then localized. Material properties can be characterized with inertia number dissipation number and diffusion number. It is observed that the dimensionless numbers effect on localization. Using a parametric study, comparison was made between CRS-1018 steel with WHA (tungsten heavy alloy). The deformation behavior of material in this study include an isotropic hardening as well as thermal softening. Moreover, this study suggests that a kinematic hardening constitutive relation be required to predict a more accurate strain level at a shear band.

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Development of Temperature and Strain-Rate Dependent Unified Constitutive Equation for Ships and Offshore Structures (선박 및 해양구조물용 극저온 재료의 온도 및 변형률 속도 의존 통합 구성방정식 개발)

  • Park, Woong-Sup;Kim, Jeong-Hyeon;Chun, Min-Sung;Lee, Jae-Myung
    • Journal of the Society of Naval Architects of Korea
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    • v.48 no.3
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    • pp.200-206
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    • 2011
  • The mechanical properties of the most widely used cryogenic materials, i.e. austenitic stainless steel (ASS), aluminum alloy and invar steel, strongly depend on temperatures and strain rates. These phenomena show very complicated non-linear behaviors and cannot be expressed by general constitutive equation. In this study, an unified constitutive equation was proposed to represent the effect of temperature and strain rate on the materials. The proposed constitutive equation has been based on Tomita/Iwamoto and Bodner/Partom model for the expression of 2nd hardening due to martensite phase transformation of ASS. To simulate ductile fracture, modified Bodner/Chan damage model was additionally applied to the model and the model validity was verified by comparison of experimental and simulation results.

Thermal Property of Mo-5~20 wt%. Cu Alloys Synthesized by Planetary Ball Milling and Spark Plasma Sintering Method (유성볼밀링 및 스파크 플라즈마 소결법으로 제조한 Mo-5~20 wt%. Cu 합금의 열적 특성)

  • Lee, Han-Chan;Moon, Kyoung-Il;Shin, Paik-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.8
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    • pp.516-521
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    • 2016
  • Mo-Cu alloys have been widely used for heat sink materials, vacuum technology, automobile, and many other applications due to their excellent physical and electric properties. Especially, Mo-Cu composites with 5 ~ 20 wt.% copper are widely used for the heavy duty service contacts due to their excellent properties like low coefficient of thermal expansion, wear resistance, high temperature strength, and prominent electrical and thermal conductivity. In most of the applications, highly-dense Mo-Cu materials with homogeneous microstructure are required for better performance. In this study, Mo-Cu alloys were prepared by PBM (planetary ball milling) and SPS (spark plasma sintering). The effect of Cu with contents of 5~20 wt.% on the microstructure and thermal properties of Mo-Cu alloys was investigated.