• Title/Summary/Keyword: heating temperature and time

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Thermal Stability of Polypropylene-Based Wood Plastic Composites by The Addition of Ammonium Polyphosphate (폴리인산염 첨가에 의한 폴리프로필렌 기반의 Wood Plastic Composites 열안정성)

  • Chun, Sang-Jin;Lee, Sun-Young
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.6
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    • pp.682-690
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    • 2014
  • In order to improve the thermal stability of wood plastic composites (WPC), thermal degradation behavior of WPC in this study was investigated by the addition of wood flour and fire retardant after hybridization of wood flour and ammonium polyphosphate (APP) into polypropylene (PP) matrix. Thermal degradation behavior of all formulations was analyzed with thermogravimetric analyzer under nitrogen environment at heating rate of $10^{\circ}C/min$. As the thermal degradation temperature of wood flour is lower than that of PP, char layer formed by the wood flour decreases the speed of heat transfer to PP. In addition, the char layer increases the 2nd thermal degradation temperature and decreases the 2nd thermal degradation speed. The WPC treated with APP increases the 1st and 2nd degradation temperatures. In the case of WPC with high loading level of wood flour, the 1st thermal degradation temperature and 2nd thermal degradation rate were increased by the addition of APP, and then the amount of remnants at high temperature was increased by the increase of the APP loading level. In the case of WPC treated with APP, the amount of the remnants at high temperature was increased with the increase of wood flour content from 10 wt% to 50 wt%, indicating that char formation of the APP and wood flour occurred at the same time, resulting in high thermal stability effect by the increase of wood flour content.

A Study on the Analysis and the Improvement of Land and Sea Breeze Model Experiment suggested to 2009 Revised Elementary Science Curriculum (2009 개정 교육과정 초등과학에서 제시된 해륙풍 모형실험 분석 및 개선 방안)

  • Kang, Houn Tae;Lee, Gyuho;Noh, Suk Goo
    • Journal of Korean Elementary Science Education
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    • v.36 no.1
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    • pp.1-15
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    • 2017
  • The purpose of this study is to analyze the problems of land and sea breeze model experiment that has presented in $5^{th}$ grade curriculum in chapter "Weather and our lives" and makes better model simulation so that learners can have better and more effective way to study it. To survey the opinions from dedicated teachers about land and sea breeze model experiment, we produced the survey through interview with science exclusive teacher from M elementary school. An elementary science education expert, 3 men of science EdD modified and complemented survey and started Delphi survey to 12 science teachers who have career teaching more than 3 years. The problems found in this survey were 'one heat bulb, short heating time, small temperature difference of water and sand, lack of class time, empty space between sand and water, back of transparent boxes, little amount of scent and the location of the it' etc. But the most of all, it is hard to see the successful result of the experiment. Based on these kinds of investigations, and lots of trial and error, redesigned the new model experiment that has the most similarity to the real one and high probability of success. According to this, it was able to see the smoke forms horizontal movement along the sand and the smoke goes in one circulation cycle. through this experiment, we made a conclusion that although those scientific experiments in textbook were developed through lots of considerations of expert, to consider the aspect of consumer, it needs to reach the educational agreement about simulation experiment so that It can lead to successful experiment and high quality education.

Ammonia Emission Characteristics of the Naturally Ventilated Growing-finishing Pig Building in Winter (자연환기식 육성${\cdot}$비육돈사와 동절기 암모니아 발생특성)

  • Lee, S. H.;Cho, H. K.;Kim, K. W.;Lee, I. B.;Choi, K. J.;Oh, K. Y.;Yu, B. K.
    • Journal of Animal Environmental Science
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    • v.11 no.2
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    • pp.103-110
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    • 2005
  • The study was carried out to develop the real time measuring technique of ammonia and carbon dioxide concentration emitted from growing-finishing pig house in winter and estimate ammonia emission rate emitted from the pig house. As the study was carried out, environmental management technique for the pig house and odor abatement skill could be properly developed to reduce the residence's annoyance. The room temperature of the growing-finishing pig house was $10^{\circ}C$ higher than outdoor air temperature in spite of additional heating, because of heat emitted from body temperature of the pigs. The daily variation pattern of room temperature in the pig house shows the similar tendency with outdoor air temperature. The daily mean ventilation rate per head was $16\;m^3/h$ and ranged from $12\;m^3/h$ to $22.4\;m^3/h$. The difference of day and night for ventilation rate was about 2 times. The ammonia emission rate was $208{\pm}28\;mg/h{\cdot}pig$ per daily basics calculated with ventilation rate and ammonia concentration.

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Phase Evolution in LiMO2(M=Co,Ni) Cathode Materials for Secondary Lithium Ion Batteries : Effect of Temperature and Oxygen Partial Pressure (리튬 2차 전지용 양극활물질 LiMO2(M=Co,Ni)의 온도와 산소 분압에 따른 상전이 거동)

  • Huang, Cheng-Zhu;Kim, Ho-Jin;Jeong, Yeon-Uk;Lee, Joon-Hyung;Kim, Jeong-Joo
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.292-297
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    • 2005
  • $LiMO_{2}(M=Co,Ni)$ samples were synthesized with $Li_{2}CO_{3},\;Co_{3}O_{4}$, and NiO by the solid-state reaction method. In the case of $LiCoO_{2}$, at low temperature$(T=400^{\circ}C)$ spinel structure was synthesized and the obtained spinel phase was transformed to layered phase at high temperature$(T\ge600^{\circ}C)$. The phase transition behaviors of $LiCoO_{2}$ were investigated with various heating temperature and time. The rate of transition was directly proportional to the concentrations of reactant, and activation energy of reaction was around 6.76 kcal/mol. When CoO(rock salt structure) was used as a starting material instead of $Co_{3}O_{4}$(spinel structure), layered structure of $LiCoO_{2}$ was obtained at low temperature. In the case of $LiNiO_{2}$ the transition from layered structure to rock salt structure occurred easily by disordering/ordering reaction, but did not occur in $LiCoO_{2}$. The difference in metal ion radii in $LiCoO_{2}$ and $LiNiO_{2}$ results in different behaviors of phase transitions.

Manufacturing and Properties of Bi-Sn Impregnated Wood Composites of Juglans nigra (북미산 흑호두나무 Bi-Sn 용융합금 복합체의 제조와 특성)

  • Kang, Seog-Goo;Park, Kye-Shin;Lee, Ho;Seo, In-Soo;Lee, Jong-Shin;Lee, Hwa-Hyoung
    • Journal of the Korea Furniture Society
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    • v.22 no.1
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    • pp.54-62
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    • 2011
  • The metalized wood composites with natural grain of imported Juglans nigra, which was impregnated with low melting alloy were manufactured and evaluated in this study. And the proper manufacturing conditions was also investigated in this study. The low melting alloy with bismuth (Bi) and tin (Sn) which are harmless to humans, was applied to this new composites. The composites showed not only no defects of discoloration, delamination, swelling, and cracking, because of high dimensional stability and low thickness swelling, but also much improved performance such as high bending strength, high hardness, abrasion resistance, high thermal conductivity as floor materials. This study also suggested the proper impregnating condition, such as 10 minutes of the preliminary vacuum time, $186^{\circ}C$ of the heating temperature and 10 minutes of the maintaining pressure time at the pressure of $30kgf/cm^2$. This metalized wood composites showed 7 times higher density than control, great increase in bending strength from $131.8N/mm^2$ to $192.3N/mm^2$, and great increase in hardness from $18.2N/mm^2$ to $90.4N/mm^2$. The composites demonstrated not only high emissivity of 91%, high shilding effectiveness of 92.59∼99.99%, high fire resistance but also great decrease in abrasion depth, water absorption and thickness swelling.

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Microbial Transglutaminase Modifies Gel Properties of Porcine Collagen

  • Erwanto, Y.;Kawahara, S.;Katayama, K.;Takenoyama, S.;Fujino, H.;Yamauchi, K.;Morishita, T.;Kai, Y.;Watanabe, S.;Muguruma, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.2
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    • pp.269-276
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    • 2003
  • We studied the gel properties of porcine collagen with microbial transglutaminase (MTGase) as a catalyst. A creep meter was used to measure the mechanical properties of gel. The results showed samples with high concentration of MTGase gelled faster than those with a low concentration of MTGase. The gel strength increased with incubation time and the peaks of breaking strength for 0.1, 0.2 and 0.5% MTGase were obtained at 40, 20 and 10 min incubation time, respectively. According to SDS-PAGE, the MTGase was successfully created a collagen polymer with an increase in molecular weight, whereas no change in formation was shown without MTGase. The sample with 0.5% MTGase began to polymerize after 10 or 20 min incubation at $50^{\circ}C$, and complete polymerization occurred after 40-60 min incubation. Scanning electron microscopic analysis revealed that the gel of porcine collagen in the presence of MTGase produced an extremely well cross-linked network. The differential scanning calorimetric analysis showed the peak thermal transition of porcine collagen gel was at $36^{\circ}C$, and that with MTGase no peak was detected during heating from 20 to $120^{\circ}C$. The melting point of porcine collagen gel could be controlled by MTGase concentration, incubation temperature and protein concentration. Knowledge of the structural and physicochemical properties of porcine collagen gel catalyzed with MTGase could facilitate their use in food products.

Physicochemical Characteristics of Gelatin from Abdominal Skin of Yellowfin Tuna (Thunnus albacares) (황다랑어 복부 껍질로부터 추출한 gelatin의 물리화학적 특성)

  • Yoo, Sung-Jae;Cho, Seung-Mock;Woo, Jin-Wook;Kim, Sang-Ho;Byun, Sang-Hun;Kim, Tae-Wan;Kim, Seon-Bong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.41 no.6
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    • pp.419-426
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    • 2008
  • Physicochemical characteristics of gelatin extracted from abdominal skin of yellowfin tuna (Thunnus albacares), were investigated by comparing its proximate composition, pH, amino acid composition, viscoelastic properties, gel strength and SDS-PAGE patterns, with those of bovine and porcine gelatins. The effects of gelatin concentration, maturation time, heat and freeze treatments on the gel strength of yellowfin tuna abdominal skin gelatin were studied. Amounts of $\alpha$-chains, $\beta$- and $\gamma$-components of yellowfin tuna abdominal skin gelatin were higher than those of the two mammailan gelatins. Yellowfin tuna abdominal skin gelatin had the lowest imino acids (proline and hydroxyproline) content, which was consistent with that of other fishes. However, yellowfin tuna abdominal skin gelatin was highest in glycine, alanine, and lysine. The gel strengths of all gelatins were proportional to the concentration of gelatin, but yellowfin tuna abdominal skin gelatin exhibited the greatest gel strength at each concentration. Yellowfin tuna abdominal skin gelatin required a longer maturation time than the two mammalian gelatins to form a firm gel. Higher heating temperature decreased the gel strength of yellow fin tuna abdominal skin gelatin more than in the two mammalian gelatins. Freezing decreased the gel strength of bovine gelatin only slightly, but longer freezing times resulted in greater reductions in gel strength in the yellowfin tuna abdominal skin and porcine gelatins.

Dynamic Simulation of a Hybrid Cooling System utilizing Heat Pump, Desiccant and Evaporative Cooler (열펌프, 데시칸트 및 증발식 냉각기를 조합한 하이브리드 냉방 시스템의 동특성 해석 연구)

  • Seo, Jung-Nam;Kim, Young-Il;Chung, Kwang-Seop
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.7 no.1
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    • pp.45-50
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    • 2011
  • Hybrid desiccant cooling system(HDCS) consists of desiccant rotor, regenerative evaporative cooler, heat pump and district heating hot water coil. In this study, TRNSYS and EES, dynamic and steady simulation programs were used for studying hybrid desiccant cooling system which is applied to an apartment house from June to August. The results show that power consumption of the hybrid desiccant cooling system is 70 kWh in June, 199 kWh in July and 241 kWh in August. Sensible and latent heats removed by the hybrid desiccant cooling system are 300 kWh, 301 kWh in June, 610 kWh, 858 kWh in July and 719 kWh, 1010 kWh in August. COP of the hybrid desiccant cooling system is 8.6 in June, 7.4 in July and 7.2 in August. COP of the hybrid desiccant cooling system decreases when latent heat load increases. Operation time of the system is 70 hours in June, 190 hours in July and 229 hours in August. Since the cooling load is largest in August, the operation time of August is longest for maintaining the indoor temperature at $26^{\circ}C$. Due to the characteristics of hybrid desiccant cooling system for efficiently handling both sensible and latent loads, this system can handle sensible and latent heat loads efficiently in summer.

Electromagnetic Simulation of Ring-shaped Electrodeless fluorescent Lamps and its Electrical and Optical Characteristics (환형 무전극 형광램프의 전자계 시뮬레이션, 전기적 및 광학적 특성)

  • 최용성;조주웅;이영환;김광수;박대희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.5
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    • pp.552-559
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    • 2004
  • In recent, there have been several developments in lamp technology that promise savings in electrical power consumption and improved quality of the lighting space. Above all, the advantage of ring-shaped electrodeless fluorescent lamp is the removal of internal electrodes and heating filaments that are a light-limiting factor of conventional fluorescent lamps. The ring-shaped electrodeless lamp is intended as a high efficiency replacement for the incandescent reflector lamp in many applications. Therefore, the life time of ring-shaped electrodeless fluorescent lamps is substantially higher than that of conventional fluorescent lamps and last up to 60,000 hours. In this paper, maxwell 3D finite element analysis program(Ansoft) was used to obtain electromagnetic properties associated with the coil and nearby structures. The electromagnetic emitting properties were presented by 3D simulation software operated at 250 KHz and some specific conditions. The optical characteristics were measured luminance and a temperature and an optical spectrum distribution for 10 min in a one minute interval at the same time. With a goal of finding alternative materials, we show measurement results of electrical characteristics of a ring-shaped electrodeless fluorescent lamp as a function of frequency and the number of coil turns using a highly permeable($\mu$$_{r}$(equation omitted) 2,000) Mn-Zn ferrite. These results are compared with those of conventional ring-shaped electrodeless fluorescent lamp. It is found that the resistance, inductance and impedance are increased while the quality factor decreases as frequency increases.s.

New Hypothesis "Exhaustion of Diffusion-Contributable Vacancies in Core/Rim Structure"

  • Hayshi, Koji;Yanaba, Yutaka
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2002.11a
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    • pp.8-8
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    • 2002
  • TiC core/(Ti,Mo)C rim structure in TiC-$Mo_2C$-Ni base cermet which is generally prepared by sintering below 145$0^{\circ}C$ had been believed to be generated by the solid diffusion of Mo atoms 1 into TiC grains (D. Moskowitz and M.Humenik, 1r.:1966). Afterward, it was clarified that the c core/rim structure is generated by solution/re-precipitation mechanism : (1) $Mo_2C$ grains and s small TiC grains dissolve into the Ni liquid, (2) the dissolved Mo, Ti and C atoms migrate to the s surface of TiC coarse grains, (3) the Mo, Ti and C precipitate on the surface of TiC coarse g grains and form (Ti,Mo)C solid solution rim, and (4) the Ostwald ripening (grain growth by s solution/re-precipitation mechanism) of TiC-core/(Ti,Mo)-rim grains continues, and thus the w width of (Ti,Mo)C rim (at the same time, the grain size) increases with sintering time, etc. ( (H.Suzuki, K.Hayashi and O.Terada: 1973). The TiC-core was found not to disappear even by s sintering at 190$0^{\circ}C$ (ibid.: 1974) Recently, FeSi core/$Fe_2Si_5$-rim structure in Fe-66.7at%Si thermoelectric aIloy was found to also h hardly shrink and disappear by long heating at an appropriate temperature (1999: M.Tajima and K K.hayashD. Then, the authors considered its cause, and clarified experimentaIly that the disappearance of FeSi-core/$Fe_2Ski_5$-rim structure could be attributed to the exhaustion of diffusion-contributable vacancies in core/rim structure (N.Taniguchi and K.Hayashi:2001). At p present, the authors and my coworker are investigating whether the non-disappearance of TiC c core can be explained also from the new hypothesis "Exhaustion of diffusion-contributable v vacancies in corelrim structure".ure".uot;.

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