• Title/Summary/Keyword: heating rates

Search Result 460, Processing Time 0.027 seconds

Strength Properties of High-Strength Concrete Exposed at High Temperature (고온을 받은 고강도 콘크리트의 강도특성)

  • 윤현도;김규용;한병찬
    • Journal of the Korea Concrete Institute
    • /
    • v.14 no.5
    • /
    • pp.698-707
    • /
    • 2002
  • A review is presented of experimental studies on the strength performance of concrete exposed at short-term and rapid heating as in a fire and after cooling. Emphasis is placed on concretes with high original compressive strengths, that is, high-strength concrete(HSC). The compressive strength-temperature relationships from the reviewed test programs are distinguished by the test methods used in obtaining the data(unstressed, unstressed residual strength, and stressed tests) and by the aggregate types(normal or lightweight), The compressive strength properties of HSC vary differently with temperature than those of NSC. HSC have higher rates of strength loss than lower strength concrete in the temperature range of between 20$^{\circ}C$ to about 400$^{\circ}C$. These difference become less significant at temperatures above 400$^{\circ}C$ compressive strengths of HSC at 800$^{\circ}C$ decrease to about 30 % of the original room temperature strength. A comparison of lest results with current code provisions on the effects of elevated temperatures on concrete compressive strength and elastic modulus shows that the CEN Eurocodes and the CEB provisions are unconservative.

Growth of Li2B4O7 Single Crystal and Its Thermoluminescent Properties (Li2B4O7 단결정 성장과 열형광 특성)

  • Park, Kang-Soo;Ahn, Jung-Keun;Kim, Dong-Jin;Hwang, Yoon-Hwae;Kim, Hyung-Kook;Park, Myeong-Hwan;Kang, Hee-Dong;Kim, Do-Sung
    • Journal of Sensor Science and Technology
    • /
    • v.12 no.1
    • /
    • pp.16-23
    • /
    • 2003
  • Thermoluminescent properties of $Li_2B_4O_7$ single crystal grown by Czochralski method have been investigated. The high quality $Li_2B_4O_7$ single crystal without core was obtained at rotation speed of 10 rpm for seed crystal and pulling speed below $0.18\;mm{\cdot}h^{-1}$. The structure of $Li_2B_4O_7$ single crystal was classified as tetragonal by XRD analysis. The TL glow curve was composed with three overlapped peaks which can be easily deconvoluted and the TL response of $Li_2B_4O_7$ single crystal TLD to X-ray radiation is linear within the range of $50\;mGy{\sim}1.5\;Gy$. Activation energies of three TL glow peaks analyzed by the various heating rates method and PL spectrum were 0.93, 1.78 and 2.25 eV, respectively.

Variation of the Overall Heat Transfer Coefficient of Plastic Greenhouse Covering Material (플라스틱온실 피복재의 관류열전달계수 변화)

  • Lee, Hyun-Woo;Diop, Souleymane;Kim, Young-Shik
    • Journal of Bio-Environment Control
    • /
    • v.20 no.2
    • /
    • pp.72-77
    • /
    • 2011
  • The objective of the present study is to provide the basic data necessary for estimating the overall heat transfer coefficient of commercial plastic greenhouse. The heat flow through covering of greenhouses was measured and the variation of overall heat transfer coefficient was analyzed. Because the inside-outside temperature difference of greenhouse to indicate the stabilized overall heat transfer coefficient was different depending on the number of covering layers, the actual overall heat transfer coefficient should be decided in range of inside-outside temperature difference to make the coefficient constant for each covering method. The variation trend of the overall heat transfer coefficient according to the inside-outside temperature difference corresponded with the existing research results, but the specific values of temperature difference to present the stabilized overall heat transfer coefficient were different each other. The increase rates of overall heat transfer coefficient with wind speed were quite dissimilar among several research results and the quantity of heat loss through covering according to the wind speed in the double layers covered or curtained greenhouse was less than that in the single layer covered greenhouse. Because there was large variations among the values of overall heat transfer coefficient for the polyethylene film greenhouses, it was required to establish the standardized environmental condition for experiment measuring heat flow through covering in commercial greenhouse.

Slow Cook-Off Test and Evaluation for HTPE Insensitive Propellants (HTPE 둔감추진제 완속가열 시험평가)

  • Yoo, Ji-Chang;Kim, Chang-Kee;Kim, Jun-Hyung;Lee, Do-Hyung;Min, Byung-Sun
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.14 no.6
    • /
    • pp.31-37
    • /
    • 2010
  • This study was carried out to investigate the thermal decomposition and execute EIDS slow cook-off test for the propellant ingredients and 2 kinds of HTPE propellants. The thermal analysis of the propellant ingredients used in this study showed that the thermal stability of these materials decreases in the following order : AP > HTPE > AN > BuNENA. In addition, propellant HTPE 002 containing AN showed that an endothermic process at around $125^{\circ}C$ corresponding to the solid phase change(II$\rightarrow$I) of AN was followed by the exothermic process of BuNENA/AN mixture up to $200^{\circ}C$. In EIDS slow cook-off tests, HTPE 001 and HTPE 002 reacted at around $250^{\circ}C$ and $152^{\circ}C$ respectively, and both of them showed sudden temperature increase curves at $115^{\circ}C$. The critical temperatures, $T_c$, of thermal explosion for the propellants HTPE 001 and HTPE 002, were obtained from both the non-isothermal curves at various heating rates and Semenov's thermal explosion theory. Kissinger's method that was used to calculate $T_c$ was also employed to obtain the activation energies for thermal decompositions.

A Study on Effects of Vulcanization Systems on Cross-linking and Degradation Reactions of NR/CR Blends Using Dynamic DSC and TGA (Dynamic DSC와 TGA를 이용한 NR/CR 고무블렌드의 가황시스템이 가교 및 열화반응에 미치는 영향 연구)

  • Min, Byung-kwon;Park, DongRyul;Ahn, WonSool
    • Korean Chemical Engineering Research
    • /
    • v.47 no.2
    • /
    • pp.169-173
    • /
    • 2009
  • Effects of variations sulfur/accelerator ratio on cross-linking and thermal degradation behavior of NR/CR rubber compounds were studied using both dynamic DSC and non-isothermal TGA. DSC thermograms of the given samples were obtained with several different heating rates, and after cross-liked in DSC, TGA thermograms with the same samples also obtained. Kissinger analysis was applied to assess the activation energies for the cross-linking and thermal decomposition processes. Results showed that the formation and thermal decomposition reaction of the samples occurred in the overall temperature range of $120{\sim}180^{\circ}C$ and $350{\sim}450^{\circ}C$, respectively, exhibiting that data could be well-fittable by Kissinger method. Furthermore, formation activation energy by DSC was estimated as $83.0{\pm}5.0kJ/mol$, which was much smaller than that of degradation by TGA, $147.0{\pm}2.0kJ/mol$. From these results, it was considered that, although variations of sulfur/accelerator ratio in the present experiments affected little on the formation mechanism and/or thermal degradation, they could play roles as the catalysts which lower the activation energy of formation. Because of stabilization after formation reaction, however, they have no more effects on the lowering the activation energy, showing higher values when decomposition, caused by main-chain scissions.

Dehydration of Foamed Fish(Sardine)-Starch Paste by Microwave Heating 2. Quality Stability and Shelf-life of the Product (어육(정어러) 발포건조제품가공에 관한 연구 2. 제품저장중의 품질변화와 저장기간)

  • LEE Kang-Ho;LEE Byeong-Ho;SONG Dong-Suck;You Byeong-Jin;LEE Byeong-Ho;SUH Jae-Soo;JEA YOi-Guan;RYU Hong-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.15 no.4
    • /
    • pp.291-297
    • /
    • 1982
  • In this part of the studies on dielectric dehydration of foamed fish-starch paste, qualify stability and shelf-life of the product of which the preparation formula and processing conditions were described in previous report (Lee et al, 1982) were determined by means of accelerated reaction test. The product was stored for 50 days under the conditions of temperatures at 35, 45, and $55^{\circ}C$ in steady state and various water activities of 0.44, 0.52, 0.65, and 0.75, respectively. The loss of available lysine, extent of TBA value, and development of browning during the storage were measured and reaction kinetically analysed to assess quality stability and shelf-life of the product for the storage at room temperature of $25^{\circ}C$. Extent of browning was accelerated with the increase of water activity and temperature marking the time to reach a limit of color and flavor deterioration, or to reach brown color density of 0.17 O.D./g at 420 nm, 106 days at aw=0.44, $35^{\circ}C$, and 41 days at aw=0,65, $55^{\circ}C$, These reaction rates resulted in a prediction of shelf-life, 130 to 110 days in the storage at aw=0.44 to 0.75, $25^{\circ}C$. The quality limit assessed by TBA values and sensory evaluation of rancidity was 87 days at aw=0.44, $35^{\circ}C$, and 30 days at aw=0.75, $55^{\circ}C$ which gave a predicted shelf-life, 128 to 113 days . at aw=0.44 to 0.75, $25^{\circ}C$ storage.

  • PDF

The properties of algal degradation and gas emission by thermophilic oxic process (고온호기발효장치를 이용한 조류 분해 및 가스 발생특성)

  • Kang, Changmin
    • Journal of the Korea Organic Resources Recycling Association
    • /
    • v.7 no.2
    • /
    • pp.57-64
    • /
    • 1999
  • The purpose of this study is to establish effective conditions for controlling $CH_4$, $N_2O$ emission from organic Waste / wastewater treatment processes. Continuous and batch experiments were conducted to treat the micro algae from polluted and eutrophicated lakes through the thermophilic oxic process. The microalgae used were mainly Microcystis sp.(collected from eutrophic lake) and Chlorella sp. (cultured in laboratory) Wasted cooking oil was added by aid-heating source. Physico-chemical components of sludges and microalgae were analyzed. In batch experiments, air supply was changed from 50ml/min to 150ml/min. The temperature. water content and drained water were affected by the air flow rate at initial stage. However, there was almost no influence of air flow rate on them in middle and last stages. At air flow rate of 100ml/min, the degradation rate of organic material was higher than that at other air flow rates. $CO_2$ concentration in exhaust was proportional to the strength of aeration, especially at initial stage when degradation was active. $CH_4$ with low concentration was detected only at starting stage when air diffusion was not enough. $N_2O$ production was not affected by variation of air supply. In continuous experiments no matter what the dewatering methods (with PAC and without PAC) and media (wood chip and reed chip) were changed, $N_2O$ was almost not affected by variation of injected air. Result showed that the reed chips using for lake purification could be used as media for thermophilic oxic process in lake and marshes area. $CO_2$ concentration was not so much affected by the change of dewatering methods and media types. $CH_4$ was not detected in the experimental period. So it can be shown that the thermophilic oxic process had been well operated in wide handling conditions regardless of media and dewatering methods.

  • PDF

Study of the Curing Reaction Rate of a Glass Fiber Reinforced Bisphenol-A (BPA) Epoxy Prepreg by Differential Scanning Calorimetry (DSC) (Differential Scanning Calorimetry (DSC)를 이용한 유리섬유 Bisphenol-A(BPA)계 에폭시 프리프레그의 경화 반응 속도 연구)

  • Kwon, Hyeon-Jin;Park, Hee-Jung;Lee, Eun-Ju;Ku, Sang-Min;Kim, Seon-Hong;Lee, Kee-Yoon
    • Composites Research
    • /
    • v.31 no.1
    • /
    • pp.30-36
    • /
    • 2018
  • The curing behavior of glass fiber reinforced epoxy prepregs based on Bisphenol-A (BPA) was studied by differential scanning calorimetry (DSC). The total heat of reaction(${\Delta}H_{total}=280.3J/g$) was determined based on the results of the dynamic heating scanning experiments. Isothermal experiments were carried out at $110{\sim}130^{\circ}C$, and it was observed that the maximum conversion and the maximum reaction rate were increased as temperature increased. Also Kamal equation was applied to analyze autocatalytic reaction of epoxy prepregs. The higher temperatures, the greater reaction rate constants ($k_1$, $k_2$). Theoretical values were calculated by these reaction rate constants and compared with experimental values. And it was confirmed that they were in reasonable agreement. At the beginning of the reaction, the experimental data and theoretical prediction were shown the same tendency, but at the end of reaction, the experimental data were smaller than theoretical predicted values due to reaction rates controlled by diffusion.

An Epidemiological Observation of Fire Accident in Korea (화재사고(火災事故)(WHO-E 916)에 관(關)한 역학적관찰(疫學的觀察))

  • Lee, Chong-Dae;Han, Seong-Un;Bin, Soon-Duk;Chu, In-Ho
    • Journal of Preventive Medicine and Public Health
    • /
    • v.1 no.1
    • /
    • pp.43-49
    • /
    • 1968
  • Epidemiological and statistical observations were made of fire hazards that occurred during the past 18 years, 1948 to 1965. Injury and mortality rates for all ages were computed chronologically. For the years of 1955, 1961 and 1965, all fire accidents were epidemiologically analysed to draw characteristic patterns in relation to the seasonal and 24 hour distribution, causes and sites of accidents etc.. Fire hazards observed herein are the categorys E 916 of the International Classification of Causes of Death, 1955, and includes all accidents caused by fire and explosion of combustible materials. The following conclusion was made: 1. The average number of annual deaths due to fire was 183 and the number of the in jured due to the same cause was 335. The mortality rate per 100,000 population was 0.8 and the ratio of injuries per death was 1.83. 2. The casually rate including both the dead and injured was 5.0 per 100,000 in Seoul, the highest among the provinces and followed by 3.4 in Cheju -Do, 2.1 in Kangwon-Do, 1.7 in Kyunggi-Do accordingly. The other provinces had a range of 0.6 to 1.2. 3. The monthly distribution of fro accidents showed that the winter months, December through February, had more frequent accidents, while the summer season, June through August had less. The 24 hour distribution of accidents showed more cases from 12:00 to 18:00 and less from 4:00 to 10:00 hours. 4. The per cent distribution of causes of accidents showed; 90.0% for careless, 10.0% for arson. The cause of carelessness was further breakdown into; 15.0% for kitchen fire places, 13.8% for fire playing, 9,4% for electrical heating and wires, 8.3% for fuels, 6.3% for matches, 5.2% for ash dumps and the remaining for others. 5. The accidents as classified by place revealed that 56.8% of the total occurred at the common dwelling houses, 11.3 at various industrial workshops, 9.3% at the street shops and the remaining at the miscellaneous places.

  • PDF

Pretreatment sterilization of garlic and ginger using antimicrobial agents and blanching (데치기 및 초고압 처리를 이용한 항균처리 마늘 및 생강의 살균 효과 연구)

  • Choi, Jun-Bong;Cheon, Hee Soon;Chung, Myong-Soo;Cho, Won-Il
    • Korean Journal of Food Science and Technology
    • /
    • v.50 no.2
    • /
    • pp.172-178
    • /
    • 2018
  • The sterilization rates were investigated to develop effective pretreatment methods of garlic and ginger using antimicrobial agents and blanching. Antibacterial components in chopped garlic and ginger, such as allicin, ginger, and shogaol, exhibited an antibacterial effect that reduced bacteria by a factor of $10^1(CFU/g)$. The total number of bacteria in garlic and ginger was decreased by $10^1(CFU/g)$ after individually soaking in 1% (w/w) citric acid, calcium oxide and 200 ppm sodium hypochlorite solution for 1 h, respectively. When chopped garlic and ginger were immersed in 1% (w/w) calcium oxide solution for 1 h, the bactericidal effect was increased by $10^4-fold$. Total cells with thermoduric bacteria exhibited a $10^3-10^4-fold$ reduction after heating for 30-40 s at $90-95^{\circ}C$. The combination of soaking in 200 ppm sodium hypochlorite solution and blanching at $95^{\circ}C$, 40 s showed $10^1-fold$ decrease in total number of cells compared to blanching in whole ginger.