• 폴리머
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• 제30권4호
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• pp.326-331
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• 2006

대표적인 고내열 POF(plastic optical fiber)의 재료로 사용되는 MMA(methyl methacrylate)/IPMI(N-isopropyl maleimide) 공중합체는 단량체 간의 반응성이 매우 차이가 나므로 $(r_1/r_2=1.72:0.17)$, 중합체의 조성분포가 불균일하게 되어 물성을 저하시키는 원인으로 작용한다. 본 논문에서는 MMA/IPMI 공중합에 스티렌을 도입하여, IPMI의 반응성을 증가시켜 중합체의 조성 분포를 좀 더 균일하게 개선하였으며, 전환율도 약 $1.5{\sim}2$배 정도로 증가시키는 결과를 얻을 수 있었다. 합성된 MMA/IPMI/St 삼원공중합체의 경우 굴절률은 MMA/IPMI 공중합체보다 증가하였으며 이는 주로 스티렌의 함량과 관련되는 것으로 나타났다.

• 한국화재소방학회논문지
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• 제10권3호
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• pp.3-9
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• 1996

PMDA와 4,4'-DDE 단량체를 이용하여 진공증착중합법으로 기판온도를 변화시키면서 제조한 폴리이미드 박막을 TGA(Thermogravimetry Analyzer)로 내열특성을 조사하였다. 박막 제조시 기판온도의 증가에 따라 증착율이 감소함을 알 수 있었으며, 기판온도가 7$0^{\circ}C$ 이상 일때는 중합이 이루어지지 않아 폴리이미드라고 할 수 없었다. TG곡선으로부터 구한 5%중량 감소온도($T_{TG}$)는 기판온도가 $20^{\circ}$, $40^{\circ}$, $70^{\circ}$일때는 $565^{\circ}$, $397^{\circ}$, $210^{\circ}$이었다. 따라서 $20^{\circ}$와 $40^{\circ}$에서 제조한 박막이 20,000시간 동안 견딜 수 있는 온도는 각각 $230^{\circ}$와 $200^{\circ}$임을 예측할 수 있었다.

• 한국재료학회지
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• 제30권1호
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• pp.38-43
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• 2020

Sand casting 3D printing uses a binder jetting method to produce a mold having complicated shape by spraying a binder on sand coated with activator. Appropriate heat treatment process in sand mold fabrication can increase the degree of polymerization to improve flexural strength. However, long heat treatment of over 24 hours decreases flexural strength and reliability due to chemical bond decomposition through thermal degradation. The main role of the activator is to control the reaction rate between the polymer chains. As a result, when the activator composition is increased from 0.15 wt% to 0.25 wt%, the flexural strength is increased by 218 N/㎠. However, excess activator (0.40 wt%) has been shown to decrease reliability without increasing flexural strength. The main role of the binder is to control the flexural strength of the specimen. As the binder composition is increased from 2.00 wt% to 4.00 wt%, the flexural strength increases to about 255 N/㎠, indicating the maximum flexural strength increase. Finally, the reliability of the flexural strength of the fabricated specimens is evaluated by a Weibull plot. Weibull modulus calculations are used to evaluate the flexural strength reliability of the specimens, and maximum reliability value of 11.7 is obtained at 0.20 wt% activator composition. Therefore, it is confirmed that this composition has maximum flexural strength reliability.

• 대한치과기공학회지
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• 제39권1호
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• pp.25-33
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• 2017

Purpose: The aim of this study was to evaluate accuracy of glass fiber mesh complete denture of before and after curing. Methods: Edentulous model was selected as the master model. Ten study models were made by Type IV stone. Wax complete dentures were produced by the denture base and artificial teeth. CD and GD groups were measured six measurement distance before curing. The wax complete denture was investment after measurement is completed. Using a heat polymerization resin was injected resin. After injecting the resin it was curing. A complete denture was re-measured after curing. The measured data was verified by paired t-test. Results: Overall CD group was larger the value of the measured length. In the CD group, A-D point was larger. The smallest point was the B-D point. However, there was no statistically significant difference only C-D point(p>0.05). In the GD group, A-B point was larger. but B-D point was the smallest. A-D and B-C statistically points showed significant differences(p<0.05). Conclusion: Glass fiber mesh resin complete denture can be clinically applied to the edentulous patient.

• Elastomers and Composites
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• 제6권1호
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• pp.71-81
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• 1971

The intention of this study is to investigate the properties of polymer blend, NBR/PVC vulcanizates and blending procedures such as roll-mixing temperatures and sequences for polymer blending of NBR and PVC(resin type). The results obtained are as follows: 1. The roll temperature applied for polymer blending is around $150^{\circ}C$. At this temperature region, the degradation of rubber stock, which may be caused by heat, can be minimized and mill processing in practical application in industries can also be facilitated. 2. It is obviously necessary that a small amount of plasticizers should be added to the stock for improving processibility of roll mixing and physical properties. 3. On roll-mixing sequence, it is more effective that PVC compounded with plasticizer is added to NBR milled on hot roll. 4. The vulcanizates of the blends with different degree of polymerization of PVC ale similar to one another in properties. 5. NBR/PVC(70/30) blends shows the better physical characters than eve,-made foreign latex blend except abrasion-resistance. 6. As PVC addition ratio is increased, the physical properties such as resistance to ozone, tear, heat and oil and tensile strength, modulus, hardness have also improved, on the other hand, tension set and rebound character decreased. 7. The curve of ultimate elongation have point of inflection at the ratio of $30\sim40$ part of PVC. 8. While CR is blended, the physical properties such as brittle point, rebound and resistance to oil in high temperature have improved. 9. Polymer blend of NBR and domestic PVC is applied for the industrial utility such as rubber sole and heel, electric wire cover and oil-resistant packing, coating and gasket, printing roll, film for food packing etc.

• 한국재료학회지
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• 제34권3호
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• pp.175-183
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• 2024

Geopolymer, also known as alkali aluminum silicate, is used as a substitute for Portland cement, and it is also used as a binder because of its good adhesive properties and heat resistance. Since Davidovits developed Geopolymer matrix composites (GMCs) based on the binder properties of geopolymer, they have been utilized as flame exhaust ducts and aircraft fire protection materials. Geopolymer structures are formed through hydrolysis and dehydration reactions, and their physical properties can be influenced by reaction conditions such as concentration, reaction time, and temperature. The aim of this study is to examine the effects of silica size and aging time on the mechanical properties of composites. Commercial water glass and kaolin were used to synthesize geopolymers, and two types of silica powder were added to increase the silicon content. Using carbon fiber mats, a fiber-reinforced composite material was fabricated using the hand lay-up method. Spectroscopy was used to confirm polymerization, aging effects, and heat treatment, and composite materials were used to measure flexural strength. As a result, it was confirmed that the longer time aging and use of nano-sized silica particles were helpful in improving the mechanical properties of the geopolymer matrix composite.

• Journal of the Korean Wood Science and Technology
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• 제13권2호
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• pp.14-34
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• 1985

본(本) 연구(硏究)에서는 국내산(國內産) 미이용(未利用) 활엽수재(闊葉樹材)인 현사시나무의 재질개량(材質改良)을 위한 방안(方案)으로 비닐계 단량체(單量體)인 methylmethacrylate (MMA) 용액(溶液)을 목재내(木材內)로 주입(注入)한 후(後) 가압(加壓) 가열(加熱) 촉매중합법(觸媒重合法)에 의하여 제조(製造)한 목재(木材)-고분자(高分子) 복합체(複合體)(WPC ; wood-polymer composites)와 열압축목재(熱壓縮木材) (Staypak ; heat-stabilized compressed wood)의 물리적(物理的), 기계적(機械的) 성질(性質)과 치수 안정성(安定性)을 조사(調査)하였다. WPC 제조시(製造時) 단량체(單量體)의 주입량(注入量)을 비교(比較)하기 위하여 침지법(浸漬法)과 진공감압법(眞空減壓法)을 실시(實施)하였다. 본(本) 연구(硏究)에서 얻어진 결과(結果)는 다음과 같다. 1. 목재내(木材內) 단량체(單量體)의 주입량(注入量)은 진공감압법(眞空減壓法)이 침지법(浸漬法)에 비(比)해 약(約) 2배(培)의 효과(效果)가 있었다. 2. 목재내(木材內)로 주입(注入)된 단량체(單量體)는 WPC 제조시(製造時) 약(約) 절반가량 중합(重合)되었다. 3. 제조(製造)된 WPC의 치수 안정효과(安定效果)의 측정결과(測定結果), 반경방향(半徑方向)에서의 항수축율(抗收縮率) 12.5~13.6%, 접선방향(接線方向)에서의 항수축율(抗收縮率)은 12.5~13.6%, 접선방향(接線方向)이 17.18~40.14%였다. 흡수감소율(吸收減少率)은 8.19~15.5%로 진공감압법(眞空減壓法)이 침지법(浸漬法)에 의(依)한 WPC보다 효과(效果)가 좋았다. 4. 휨강도(强度) 시험시(試險時) 하중(荷重)을 가(加)하는 방향(方向)을 달리하였을 때 반경방향(半徑方向)으로 하중(荷重)을 가(加)한 경우(境遇)가 접선방향(接線方向)에 비(比)해 높은 강도치(强度値)를 나타내었다. 5. Staypak 및 WPC는 소재(素材)에 비(比)해 횡압축강도(橫壓縮强度)가 70~90% 향상(向上)되었으며, 종압축강도(從壓縮强度)는 10~30% 증가(增加)되었다. 6. Staypak의 비중(比重)은 0.66, 침지법(浸漬法)에 의(依)한 WPC는 0.61, 진공감압법(眞空減壓法)에 의(依)한 WPC의 비중(比重)은 0.62, 소재(素材)는 0.44였다.

• 한국의류학회지
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• 제23권4호
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• pp.584-592
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• 1999

Highly conductive polyaniline(PAn)-nylon 6 composite fabric was prepared by immersing the nylon 6 fabric in 0.5M aniline+0.35M HCl aqueous solution at 4$0^{\circ}C$ for 2hours, Polymerization was then followed by mixing the prepared oxidant and dopant solution(0.5M(NH4)2S2O+0.35M HCl) to the diffusion bath at 5$^{\circ}C$ for 30 minutes. The conductivity of prepared PAn-nylon 6 composite fabrics reached as high as 0.5$\times$10-1S/cm. Their conductivity were significantly affected by the aniline and oxidant concentration. As compared to those of nylon 6 fabric heat of fusion melting point the degree of crystallinity and tensile strength of PAn-nylon 6 did not significantly changed by inclusion of PAn. In the aspect of serviceability wheras the fabric conductivity was significantly decreased after multiple washion no significant changes in the fabric conductivity were observed after abrading the composite fabric over 50 cycles. However we found that the fabric conductivity could be recovered by acid re-doping with HCl.

• Elastomers and Composites
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• 제52권3호
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• pp.194-200
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• 2017

After the grafting of methacrylic acid (MA) to ethylene propylene diene monomer (EPDM), a new peak at $1704cm^{-1}$ corresponding to the carboxylic acid group was observed in the infrared (IR) spectrum. This characteristic MA molecule peak grew larger as the MA contents were increased. After casting films were prepared from pure EPDM and MA-grafted EPDM, differential scanning calorimeter (DSC) measurements were made the pure EPDM exhibited a melting point of approximately $45^{\circ}C$ while that of the MA-grafted EPDM was $135{\sim}140^{\circ}C$. As the graft ratio of MA increased, the absorbed heat capacity increased at temperatures near $135{\sim}140^{\circ}C$, indicating that an increased amount of MA reacted. Furthermore, owing to the addition of crystalline MA, it is expected that strength of the elastomer will improve as the graft ratio increases, as a result of the increased number of hard segments.

• 한국염색가공학회지
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• 제20권6호
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• pp.82-86
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• 2008

Cooling function is definitely one of the most desirable attribute of clothing. In spite of the recent progress on phase changing material(PCM) research, the final products with sufficient amount of cooling capability have not yet to be developed in market. A new concept of cooling fabrics has been proposed by applying "Peltier effect" to textile materials. It occurs whenever electrical current flows through two dissimilar conductors; depending on the direction of current flow, the junction of the two conductors is absorbed or released heat. This effect has been tested on P-type and N-type conducting polymers. A P-type conductive polypyrrole coated fabric was synthesized by in-situ polymerization on plain weave PET to make conductive fabrics. And an N-type electrically conductive material was synthesized by treatment of MWNT and polyethyleneimine(PEI). A noticeable amount of temperature difference has been found on the fabrics.