• 한국구조물진단유지관리공학회 논문집
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• 제9권3호
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• pp.120-128
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• 2005

콘크리트용 혼화재료로 고로슬래그미분말은 경제적, 환경적 이점뿐만 아니라, 고강도, 내해수성, 내화학성과 같은 성능개선의 효과도 있다. 고로슬래그미분말이 콘크리트용 재료로서 아주 유용한 자원임에도 불구하고, 초기 강도의 저하로 인한 거푸집의 해체 및 순환의 문제로 공사기간이 지연되어 공사비의 증가 등의 단점이 있다. 따라서 본 연구에서는 고로슬래그미분말 혼합 모르타르의 초기 강도의 증진을 위하여, 다양한 알칼리 자극제를 혼합 사용하여, 모르타르의 유동성 및 압축강도 특성을 평가하였다. 또한 알칼리 자극제의 혼합에 따른 수화 반응 성상을 알아보기 위하여, XRD 분석, 미소수화열 및 $Ca(OH)_2$를 정량하였다. 실험결과 유동성과 응결시간에 대한 단점을 고로슬래그미분말로 보완하고, 적당한 알칼리 자극제의 선택과 첨가량을 조절하여 사용한다면, 고로슬래그미분말을 콘크리트에 사용하여도 초기 강도 저하 없이 사용가능할 것으로 판단된다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.517-520
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• 2008

중력식 콘크리트 댐은 댐의 자중에 의해 수압 등의 외력에 저항하여 역학적인 안정을 유지하는 댐으로 크게 내부콘크리트와 외부콘크리트로 분류되어 시공된다. 성덕 다목적댐은 경북내륙지역의 안정적 용수공급 및 보현천, 길안천유역의 홍수피해 경감을 위해 경상북도 청송군에 건설 중인 댐으로, 댐길이 274m 댐높이 58.5m 총 저수용량 27.9${\times}$10$^6$ m$^3$ 규모의 중력식 다목적 댐이다. 본 댐의 분할 타설고 설정 및 수화열에 의한 온도 균열 유무 조사 등의 목적으로 상류 가물막이댐에 대한 시험시공을 실시하였다.본 연구에서는 성덕 다목적댐의 내부 및 외부콘크리트의 배합, 강도 특성 및 단열온도 등의 역학적 특성과 발열 특성을 실내실험을 통하여 확인하고, 상류 가물막이댐의 시험시공시 온도 및 응력 계측을통한 현장에서의 수화열과 온도응력 특성을 검토하였다.

• 콘크리트학회논문집
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• 제27권3호
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• pp.265-272
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• 2015

본 연구에서는 매스콘크리트의 높은 수화열을 제어하기 위하여 결정핵 (C-S-H)와 지연제(포도당)를 동시 사용하여 최대 수화온도를 낮추면서, 응결지연효과를 상쇄시키는 방법이 제시되었다. 이를 위하여 시멘트 페이스트의 수화온도를 측정하고, C-S-H와 포도당의 동시 사용이 시멘트 모르타르의 응결시간 및 압축강도에 미치는 영향을 조사하였다. 실험결과에 따르면. 칼슘실리케이트 수화물과 포도당을 동시 사용할 경우 최대 수화온도를 저감하면서도 최대수화온도에 도달하는 시간을 줄일 수 있음을 확인하였다. 또한 C-S-H와 포도당의 동시 사용은 시멘트 모르타르의 28일 압축강도에는 큰 영향을 미치지 않는 것으로 나타나, 이러한 방법이 매스콘크리트의 수화열 조절에 효과적인 대안이 될 수 있음을 알 수 있었다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문 발표회
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• pp.77-82
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• 2003

The purpose of this study is development of technique to use cementitious powder as recycle cement produced from deteriorated Concrete waste which has a large quantity of calcium carbonate. Therefore, after having theoretical consideration based on the properties of high-heated concrete and concerning about neutralization of Concrete, we analysis chemical properties of ingredients of cementitious powder. After making origin cement paste, then processing the accelarated carbonation, we consider the properties of hydration and chemical properties of cementitious powder under various temperature conditions. As a result of the thermal analysis, the CaCo3 content of cementitious powder would affect decision of heat temperature to recover its hydrated ability because CaCo3 content is increased when neutralization is progressed. And as a result of XRD analysis, in case of origin powder of non-neutralized paste, CaO peak is found at 700℃. but, heat temperature to generate CaO would increase when the content of neutralized ingredients is increased. Finally, recycle cement heated at 700℃ shows the best compressive strength when the content of neutralized ingredients in recycle cement is less then 50%. However, it would be quite difficult to manage quality of recycle cement according to recycling points of various concrete waste.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문발표회
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• pp.77-82
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• 2003

The purpose of this study is development of technique to use cementitious powder as recycle cement produced from deteriorated Concrete waste which has a large quantity of calcium carbonate. Therefore, after having theoretical consideration based on the properties of hish-heated concrete and concerning about neutralization of Concrete, we analysis chemical properties of ingredients of cementitious powder After making origin cement paste, then processing the accelerated carbonation, we consider the properties of hydration and chemical properties of cementitious powder under various temperature conditions As a result of the thermal analysis, the CacO3 content of cementitious powder would affect decision of heat temperature to recover its hydrated ability because CacO3 content is increased when neutraliTation is preBlessed. And as a result of XRD analysis. in case of origin powder of non-neutralized paste, CaO peak is found at $700^{\circ}C$. but, heat temperature to generate CaO would increase when the content of neutralized ingredients is increased. Finally, recycle cement heated at $700^{\circ}C$ shows the best compressive strength when the content of neutralized ingredients in recycle cement is less then 50%. However, it would be quite difficult to manage quality of recycle cement according to recycling points of various concrete waste.

• 한국건축시공학회지
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• 제4권3호
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• pp.143-151
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• 2004

The purpose of this study is development of technique to use cementitious powder as recycle cement produced from deteriorated Concrete waste which has a large quantity of calcium carbonate. Therefore, after having theoretical consideration based on the properties of high-heated concrete and concerning about neutralization of Concrete, we analysis chemical properties of ingredients of cementitious powder. After making origin cement paste, then processing the accelarated carbonation, we consider the properties of hydration and chemical properties of cementitious powder under various temperature conditions. As a result of the thermal analysis, the $CaCO_3$ content of cementitious powder would affect decision of heat temperature to recover its hydrated ability because $CaCO_3$ content is increased when neutralization is progressed. And as a result of XRD analysis, in case of origin powder of non-neutralized paste, CaO peak is found at $700^{\circ}C$. but, heat temperature to generate CaO would increase when the content of neutralized ingredients is increased. Finally, recycle cement heated at $700^{\circ}C$ 120min. shows the best compressive strength when the content of neutralized ingredients in recycle cement is less then 50%.

• 국제학술발표논문집
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• The 3th International Conference on Construction Engineering and Project Management
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• pp.794-799
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• 2009

The temperature control of in-place concrete is the most important factor for an early age of curing concrete. Heat stress of mass concrete caused by the heat of hydration can induce the crack of concrete, and a frost damage from cold weather casting concrete results defect on compressive strength and degradation of durability. Therefore, success and failure of concrete work is dependant on the measurement and control of concrete temperature. In addition, the compressive strength assessment of in-place concrete obtained from the maturity calculated from the history of temperature make a reduction of construction cycle time, possible. For that purpose, wireless temperature measuring system was developed to control temperature and assess strength of concrete. And, it was possible to monitor the temperature of concrete over 1km apart from site office and to take a proper measure; mesh-type network was developed for wireless sensor. Furthermore, curing control system that contains the program capable to calculate the maturity of concrete from the history of temperature and to assess the compressive strength of concrete was established. In this study, organization and practical method of developed curing control system are presented; base on in-place application case.

• 콘크리트학회논문집
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• 제27권2호
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• pp.115-125
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• 2015

본 연구는 물-결합재비 20%를 가지는 고강도 고함량 고로슬래그 혼합 시멘트 페이스트의 유동성, 수화열, 응결시간 그리고 강도 발현 특성, 수화 및 포졸란 반응 특성 등을 실험을 통해 관찰하고, 이를 통해 고로슬래그 미분말의 치환률과 분말도가 수화 및 포졸란 반응에 미치는 영향을 분석하였다. 연구 결과에 따르면 물-결합재비가 낮은 고강도 배합에서는 고로슬래그 미분말로 시멘트를 대체함으로써 시멘트와 결합하는 자유수가 상대적으로 증가하는 dilution effect에 의해 시멘트의 초기 수화가 촉진되어 재령 3일부터 28일까지의 초기 강도는 보통 포틀랜드 시멘트만을 사용한 배합보다 더 높게 나타났다. 반면, 재령이 증가하면서 수화반응속도가 급격히 낮아지고, 고로슬래그 미분말로 시멘트를 대량 치환함에 따라 수산화칼슘이 충분히 공급되지 못하므로 포졸란 반응도가 낮아져 장기강도의 발현이 억제되는 것으로 나타났다. 또한 고로슬래그의 분말도가 높으면 자유수를 더 많이 흡착함으로써 유동성이 저하되고 수화도가 낮아져 강도가 오히려 저하되는 것으로 나타났다. 이와 같은 결과는 보통 강도 콘크리트와는 다른 경향을 나타내는 것으로 향후 콘크리트 배합에 대해 추가 검증이 필요하며, 고로슬래그 미분말을 대량 혼합한 고강도 콘크리트의 개발을 위해서는 장기 강도의 발현율을 더 높일 수 있는 방안에 대한 연구가 필요하다.

• 한국광물학회지
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• 제9권1호
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• pp.17-25
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• 1996

Usual experimental adsorption isotherms as a function of relative humidity were constructed from adsorbed water contents in soils, which were kept more than 2 days in vacuum desiccators with constant humidities controlled by sulfuric acids of various concentrations. From the experimental data, the adsorption surface areas were calculated on the basis of the existing adsorption theory, such as Langmuir, BET, and Aranovich. Based on the Gibbs function describing chemical potential of perfect gas, the relative humidities in the desiccators were transformed into their chemical potentials, which were assumed to be the same as the potentials of equilibratedly adsorbed water in soils. Moreover, the water potentials were again transformed into the equivalent capillary pressures, heads of capillary rise, and equivalent radius of capillary pores, on the basis of Laplace equation for surface tension pressure of spherical bubbles in water. Adsorption quantity distributions were calculated on the profile of chemical potentials of the adsorbed water, equivalent adsorption and/or capillary pressures, and equivalent capillary radius. The suggested theories were proved through its application for the prediction of temperature rise of sulfuric acid due to hydration heat. Adsorption heat calculated on the basis of the potential difference was dependant on various factors, such as surface area, equilibrium constants in Langumuir, BET, etc.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.269-274
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• 1999

Various method have been developed for mass concrete structures to reduce the temperature increase of concrete mass due to exothermic hydration reactions of concrete compounds and thereby to avoid thermal cracks. One of the methods widely acceptable for practical use is pipe cooling, in which cooling is achieved by circulating cold water through thin-wall steel pipes embedded in the concrete. A numerical simulation was performed to investigate the effectiveness of pipe cooling. A three-dimensional finite element method was proposed to analyse the transient three-dimensional heat transfer between the hardening concrete and the cooling water in pipe and to predict the stress development during the curing process. The effects of the cement type and content and the environment were taken into consideration by the heat generation rate and the boundary conditions, respectively. In order to test the validity of the numerical simulation, a model RC structure with pipe cooling was constructed and the time-dependent temperature and stress distributions within the structure as well as the variation of the temperature of cooling water along the pipe were measured. The results of the simulation agreed well the experimental measurements. The results of this study have important implications for the optimal design of the cooling pipe layout and for the estimation of thermal stress in order to eliminate thermal cracks.