• Title/Summary/Keyword: heat of hydration heat

Search Result 712, Processing Time 0.027 seconds

Effect of Fiber Addition for Improving the Properties of Lightweight Foamed Concrete (경량 기포콘크리트의 성능향상에 대한 섬유혼입의 영향)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
    • /
    • v.15 no.4
    • /
    • pp.383-389
    • /
    • 2015
  • The objective of this study is to develop mixture proportioning approach of crack controlled lightweight foamed concrete without using high-pressure steam curing processes, as an alternative to autoclaved lightweight concrete blocks (class 0.6 specified in KS). To control thermal cracks owing to hydration heat of cementitious materials, 30% ground granulated blast-furnace slag (GGBS) was used as a partial replacement of ordinary portland cement (OPC). Furthermore, polyvinyl alcohol (PVA) and polyamid (PA) fibers were added to improve the crack resistance of foamed concrete. The use of 30% GGBS reduced the peak value of hydration production rate measured from isothermal tests by 28% and the peak temperature of foamed concrete measured from semi-adiabatic hydration tests by 9%. Considering the compressive strength development, internal void structure, and flexural strength of the lightweight foamed concrete, the optimum addition amount of PVA or PA fibers could be recommended to be $0.6kg/m^3$, although PA fiber slightly preferred to PVA fiber in enhancing the flexural strength of foamed concrete.

A Study on the Basic Properties of Concrete and Characteristics of Blended Low Heat Cement (혼합형 저발열 시멘트의 특성과 콘크리트 기초 물성에 관한 연구)

  • 송용순;한정호;강석화;김상철
    • Magazine of the Korea Concrete Institute
    • /
    • v.10 no.5
    • /
    • pp.177-187
    • /
    • 1998
  • 최근 국내에서 해양 구조물, 장대 교량의 하부구조물, LNG저장탱크 등 매스콘크리트의 증가추세에 따라 구조물의 고내구성과 관련하여 시멘트의수화열에 의한 온도균열의 발생을 최소화 시킬 수 있는 3성분계 혼합형 저발열시멘트가 개발되어 실 구조물의 적용단계에 있으나, 저발열시멘트가 개발되어 실 구조물의 적용단계에 있으나 저발열시멘트의 특성에 대한 전반적인 연구보고가 국내에서는 미진한 실정이다. 따라서 본 연구에서는 3성분계 혼합형 저발열시멘트의 특성 및 코\ulcorner리트의기초물성을 1종 보통포틀랜트 시멘트, 5종 내황산염시멘트, 슬래그시멘트와 비교하였다. 글 결과 저발열 콘크리트의 찹축강도는 초기재령에서 강도발현률이 적은 반면 장기강도발현률은 상당히 큰 경향을 보였다. 또한 수화열은 1종시멘트를 사용한 콘크리트에 비하여 1/3~1/2정도로 매스콘크리트의 수화열을 대폭적으로 저감시킬 수 있을 뿐만 아니라 염소이온에 대한 저항성이 상대적으로 높게 나타나 거대 해양 구조물의 적용에 매우 유리한 시멘트로 판단되었다.

Assessment of the Mechanical Performance of Nano-Silica and Nano-Calcite Incorporated Limestone Calcined Clay Cement (LC3) Paste (나노실리카와 나노칼사이트 혼입 석회석 소성 점토 시멘트(LC3) 페이스트의 기계적 성능 평가)

  • Kim, Gyeong-Ryul;Cho, Seong-Min;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2023.05a
    • /
    • pp.151-152
    • /
    • 2023
  • This study investigates the effect of nano-silica and nano-calcite on the hydration properties and mechanical performance of limestone calcined clay cement (LC3) paste. The pastes were synthesized by replacing limestone with nano-silica and nano-calcite in order to enhance the mechanical properties in both early and late stages of hydration. The nano-calcite enhanced the strength of LC3 pastes at 1 day of hydration, however, the strength decreased compared to the ordinary LC3 pastes afterwards due to excessive amount of carboaluminate produced in the pastes. On the other hand, nano-silica improved the mechanical properties of LC3 pastes at all ages of hydration. This is mainly due to the nucleation effect and pozzolanic reaction of nano-silica, affecting the early age and late ages of hydration, respectively. The nucleation effect of both nanomaterials were confirmed by the analysis of hydration heat, supporting the enhanced early age strength of nanomaterial incorporated LC3 pastes. Furthermore, the dense matrix was shown in the pore size distribution, and the increased C-S-H due to the pozzolanic reaction evidence the improved compressive and splitting tensile strength of nano-silica incorporated LC3 pastes.

  • PDF

The Use of Semi-Adiabatic Calorimetry for Hydration Studies of Cement Paste

  • Chung, Chul-Woo;Kim, Ji-Hyun;Lee, Soo-Yong
    • Journal of the Korea Institute of Building Construction
    • /
    • v.16 no.2
    • /
    • pp.185-192
    • /
    • 2016
  • The semi-adiabatic calorimetry technique is a robust and easy technique that can be used to measure the temperature rise of concrete. This method is often used for investigating the maturity of concrete, as well as to predict maximum temperature rise of mass concrete using various heat loss compensating models. Semi-adiabatic calorimetry can also be used for predicting setting time of concrete. However, it has seldom been used to investigate the hydration characteristics of various cement paste samples. In this research, semi-adiabatic calorimetry and X-ray diffraction methods were used to investigate the hydration characteristics of 3 different ASTM type I Portland cements. First derivative of temperature rise (dT/dt) curve was used to isolate individual peaks. Based on the results of the experiments, a combination of dT/dt curve with XRD could be used to successfully identify hydration at a specific time period, showing its potential to be used as an alternative tool for hydration studies of cement-based materials.

Hydration Behaviors of Portland Cement with Different Lithologic Stone Powders

  • Xiong, Zuqiang;Wang, Peng;Wang, Yuli
    • International Journal of Concrete Structures and Materials
    • /
    • v.9 no.1
    • /
    • pp.55-60
    • /
    • 2015
  • In this study, influence of different stone powders (SP), including limestone powders (LP), quartzite powders (QP), and granitic powders (GP), on the hydration behaviors of portland cement, for example, setting time, hydration heat, and hydration products, were discussed. The initial and the final setting time both shorten when the content of LP is 5 %, however, they are slightly delayed by the other two SPs. The LP has no obvious influence on the arrival time of the first peak in the exothermal curves, and it makes the peak value decrease; the other two SPs postpone the appearance of the first peak, and they also make the peak value decrease. For the second peak, LP shifts the peak position to the left, QP has no effect on this peak position, and GP makes the appearance of this peak delayed by 143 min. Similarly, three kinds of SPs have different influence on the hydration products of portland cement. The LP precipitates the formation of hydrated calcium carbo aluminate, the QP the formation of hydrated garnet, and the GP makes the amount of Tobermorite increase.

Effect of the $P_2O_5$ Substituted Gypsum on the Early Hydration of $C_3A$ (석고에 고용된 $P_2O_5$$C_3A$의 초기수화에 미치는 영향)

  • 한기성;김용국
    • Journal of the Korean Ceramic Society
    • /
    • v.21 no.4
    • /
    • pp.355-360
    • /
    • 1984
  • The effect of 2% of $P_2O_5$ substituted in gypsum(5 mol% as $HPO_3$) on the early hydration characteristics of $C_3A$ were investigated and then gypsum only and gypsum mixed with $Ca(H_2PO_4)_2$.$H_2O$(2% as $P_2O_5$) were studied separately for comparison. The early hydration reaction of $C_3A$ with each gypsum were examined by measuring the rate of heat libera-tion of hydration with calorimeter and by analysing the hydration products with X-ray diffractometer and differential thermal analyser. It was shown that phosphogypsum substituted with $P_2O_6$ in the crystal lattice accelerated exceedingly the formation of the ettrignite and following hydrated products. However the other gypsum especially gypsum without any phosphate delayed the formation of various hydration products, It was consequently suggested that when phosphogypsum are used as the retarder of cement setting its reta-rding effect for setting of cement is not ascribed to the retardation of ettringite formation.

  • PDF

A Study on the Safety Measures for Thermal Diseases, Focusing on the Cases of Disaster by Construction Industry

  • Hye-Ryeong O;Won-Mo GAL;Ok-Nam Park;Mi-Hwa JANG;Seok-Soon KWO;Seung-Hyuck PARK
    • Journal of Wellbeing Management and Applied Psychology
    • /
    • v.7 no.2
    • /
    • pp.49-56
    • /
    • 2024
  • Purpose: Construction sites are currently facing a socialization problem as the incidence of thermal disease-related disasters increases due to summer heat waves, exacerbated by factors like the concentration of middle-aged and older workers and global warming. The reason why construction sites are particularly vulnerable to heat waves is that there are many outdoor work, which is the peculiarity of the construction industry, and most of the construction workers are elderly. This study analyzes disaster statistics of workers at construction sites for five years to investigate the occurrence of thermal diseases and analyze factors through disaster cases to provide basic data for future disasters to be reduced. Research design, data, and methodology: According to the Construction Workers' Mutual Aid Association, as of June, more than 60% of the construction workers working in the field were in their 50s and 60s. More than 24% are in their 60s and older. Thermal diseases caused by heat waves occur when exposed to high heat or strong sunlight for a long time, accompanied by headaches and dizziness. The problem is that many elderly people have underlying diseases, so if they lose consciousness, they cannot easily recover and are likely to die. Results: According to industrial accident statistics, 182 people were injured by heat-related diseases in the summer from 2016 to 2021, of which 29 died. In particular, in the construction industry, which has a lot of outdoor work, 87 people were injured and 20 people died. Conclusions: In order to prevent heat diseases caused by outdoor work, it is emphasized that exposure time is controlled, and sufficient rest and hydration are essential. Rest, water, and shade are in line with the three principles.