• Transactions of Materials Processing
• /
• v.13 no.1
• /
• pp.53-58
• /
• 2004

The microstructural changes of Al-Zn-Mg-Cu alloy containing Sc during hot extrusion and post heat treatment were investigated. Two kinds of Al-Sc alloys with different alloying elements (B1, B2) were hot extruded to make T-shape bars at extrusion temperature of $380^{\circ}C$, then the bars were solution treated at $480^{\circ}C$ for 2hrs followed by artificial aging at $120^{\circ}C$ for 24hrs. The interior microstructure of as extruded bar consisted of elongated grains, however, fine equiaxed grains were also observed around surface. The microstructural gradient suggested that different restoration process could proceed during the hot extrusion. For B1 and B2, different grain growth behaviors were found around the surface during the post heat treatment. Rapid grain growth behavior was observed for B1 around the surface, however, it was not observed for B2. Orientation pinning, which was related with the evolution of preferred orientation, and precipitation were thought to be responsible for the rapid grain growth.

• Computers and Concrete
• /
• v.20 no.5
• /
• pp.529-537
• /
• 2017

Excessively elevated temperature can lead to cracks in prestressed concrete (PC) continuous bridge with box girder on the pier top at cement hydration age. This paper presents a case study for evaluating the behavior of PC box girder during the early hydration age using a two-stage computational model, in the form of computer program ANSYS, namely, 3-D temperature evaluation and determination of mechanical response in PC box girders. A numerical model considering time-dependent wind speed and ambient temperature in ANSYS for tracing the thermal and mechanical response of box girder is developed. The predicted results were compared to show good agreement with the measured data from the PC box girder of the Zhaoshi Bridge in China. Then, based on the validated numerical model three parameters were incorporated to analyze the evolution of the temperature and stress within box girder caused by cement hydration heat. The results of case study indicate that the wind speed can change the degradation history of temperature and stress and reduce peak value of them. The initial casting temperature of concrete is the most significant parameter which controls cracking of PC box girder on pier top at cement hydration age. Increasing the curing temperature is detrimental to prevent cracking.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.19 no.10
• /
• pp.2595-2606
• /
• 1995

Buoyancy-assisted melting of an unconstrained ice in an isothermally heated horizontal enclosure was numerically analyzed in a range of wall temperatures encompassing the density inversion point. The problem as posed here involves two physically distinct domains each of which has its own scales and respective heat transfer mode. These two domains join at the junction where the liquid squeezed out of the film region flushes into the lower melt pool. Both of these domains have been treated separately in the literature by a patching technique which invokes several, otherwise unnecessary, assumptions. The present study eliminates successfully such a superfluous procedure by treating the film and lower melt pool regions as a single domain. As a result of this efficient solution procedure, the interaction of the water stream ejected at the junction and the natural convection in the melt pool could be clarified for different wall temperatures. Though limited by two-dimensionality, the present results conformed indirectly the earlier reported transition of the flow pattern, as the wall temperature was increased over the density inversion point. The transient evolution of the melting surface, the time rate of change in melt volume fraction, the local and temporal variation of the heat transfer coefficients are analyzed and presented.

• Proceedings of the KWS Conference
• /
• 2009.11a
• /
• pp.61-61
• /
• 2009

This paper has been performed in order to figure out the reason of failure in T23 weldments used for boiler tube at 550 $^{\circ}C$. Defects such as cracks and cavities occurred in CGHAZ (coarse grain heat-affected-zone) and multi pass of weld metal, and these crack propagated along grain boundary. Microstructure evolution such as grain growth and carbide precipitation was investigated by optical microscope (OM), transmission electron microscope(TEM). Moreover, Auger electron spectroscope (AES) was employed in order to examine segregation along the grain boundaries. There is significant difference in grain size and precipitation distribution in the region where cracking took place. In addition, sulfur segregation was observed. Based on the results of this investigation, it has been possible to establish that this type of cracks were consistent with reheat cracking and creep damage. Selection of optimal filler metal, heat input, and PWHT temperature is required for prevention in order to avoid this type of cracking.

• Journal of the Korean Society for Heat Treatment
• /
• v.26 no.6
• /
• pp.279-287
• /
• 2013

Oxide Dispersion Strengthened (ODS) Fe with $Al_2O_3$ dispersoid was successfully produced by reactive milling with a mixture of Fe, $Fe_3O_4$ (Magnetite), $Fe_2O_3$ (Hematite) and Al reactants at cryogenic temperature. The milled powders were consolidated by Vacuum Hot Press (HP) at 1323 K, and the consolidated materials were characterized by Transmission Electron Microscopy (TEM), Scanning Transmission Electron Microscopy (STEM), and Energy Dispersive Spectroscopy (EDS); the yield strength and the hardness of the consolidated materials were determined by compressive test and Vickers hardness test at room temperature. The grain size of the materials was estimated by X-ray Diffraction technique using the scherrer's formula. The TEM observations showed that the microstructure was comprised with a mixture of nanocrystalline Fe matrix and $Al_2O_3$ nano-dispersoids with a bimodal size distribution; the 0.2% off-set yield strength of the materials was as high as $758{\pm}29$ MPa and the Vickers hardness was $358{\pm}2$. The effect of the cryogenic milling and addition of extra Fe powder was discussed on the suppression of MSR (Mechanically induced Self-sustaining Reaction) for the desired microstructural evolution of ODS alloys.

• Korean Journal of Materials Research
• /
• v.25 no.11
• /
• pp.612-615
• /
• 2015

In this work, on-site corrosion behavior of heat resistant tubes of T91, used as components of a superheater in a power plant for up to 25,762 h, has been investigated using scanning electron microscopy(SEM), energy dispersive X-ray spectroscopy (EDS), and electron backscattered diffraction(EBSD), with the objectives of studying the composition, phase distribution, and evolution during service. A multi-layer structure of oxide scale was found on both the steamside and the fireside of the tube surface; the phase distribution was in the order of hematite/magnetite/spinel from the outer to the inner matrix on the steamside, and in the order of slag/magnetite/spinel from the outer to the inner matrix on the fireside. The magnetite layer was found to be rich in pores and cracks. The absence of a hematite layer on the fireside was considered to be due to the low oxygen partial pressure in the corrosion environment. The thicknesses of the hematite and of the slag-deposit layer were found to exhibit no significant change with the increase of the service time.

• Analytical Science and Technology
• /
• v.8 no.4
• /
• pp.583-590
• /
• 1995

Pitch-based mesophase carbon fibers prepared at different temperatures were heat-treated at temperatures lower than those of the preparation and the electrochemical Li doping/undoping characteristics were evaluated in relation to the data of IR, mass, etc. Presence of surface hydroxyls were confirmed by FTIR for lower temperature sample which showed poor anode characteristics. Upon oxidative heating, removal of surface hydroxyls took place, resulting in a remarkable improvement of the electrode characteristics. At the same time, surface roughening took place, which was confirmed by SEM and double layer capacity measurements. In situ mass spectra obesrved during the heat-treatments showed gas evolution of $H_2O$, CO, $CO_2$, $C_2H_4$, and/or $H_2$ depending on the conditions. These data together with those of weight loss and conductivity provided us a valuable information in regard to the evaluation of the electrochemical characteristics.

• KIEAE Journal
• /
• v.16 no.2
• /
• pp.23-31
• /
• 2016

Purpose: Recently energy consumption is rapidly increasing due to continuous development of social evolution in various field. In this situation, there is a lot of effort to reduce this energy consumption in many ways, especially in building energy. Preceding studies already started to analyze the housing area such as zero energy house and passive house by researching annual building energy consumption, but to apply the results of housing to office building is insufficient since it has different consumption tendency. Method: In this study, eQuest program was used for simulation and the base model is selected among standard office building in ASHRAE 90.1. Variables are divided into passive and active factors for comparison. Result: In passive factors, glazing system showed the highest energy saving rate by 21.3% with triple low-e glass and enhancing wall u-value showed the lowest energy saving rate by 3.6% with 0.15 m2/K. In active factors, VAV system showed 30.9% energy saving rate when compared to CAV system, and heat exchanger showed 10.2% energy saving rate. For regeneration energy part, photovoltaic panel generated 10.4% of base annual energy usage.

• Carbon letters
• /
• v.1 no.1
• /
• pp.22-26
• /
• 2000

Raman spectroscopy has been used to investigate the structure of coal tar pitch heat-treated up to $3000^{\circ}C$ by using 514.5 run Ar ion laser line. Four critical temperature ranges were found on pyrolyzing coal tar pitch, which correspond to four distinct processes from disordered carbons to the well-ordered graphite structure. The range of heat treat temperature (HTT) below $1000^{\circ}C$ corresponds to gas evolution during the pyrolysis of coal tar pitch. Above the HTT are correlated to rearrangements of enlarged molecules, growth of the molecules along the direction of plane, finally stacking in the normal direction of the plane, in the respective HTT ranges of 1000-2000, above 2000 and $2500-3000^{\circ}C$.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2012.05a
• /
• pp.56.1-56.1
• /
• 2012

The microstructures and mechanical properties of Co-29Cr-6Mo alloy with C and N additions, produced by additive manufacturing using electron beam melting (EBM) method, were studied using X-ray diffraction, electron back scatter diffraction, transmission electron microscope, Vickers hardness tests, and tensile tests, focusing on the influences on the build direction and the various heat treatments after build. It is found that the microstructures for the as built specimens were changed from columnar to equiaxed grain structure with average grain size of approximately $10-20{\mu}m$ due to the heat treatment employing the reverse transformation from a lamellar (hcp + $Cr_2N$) phase to an fcc. Our results will contribute to the development of biomedical Ni-free Co-Cr-Mo-N-C alloys, produced by EBM method, with refined grain size and good mechanical properties, without requiring any hot workings.