• 대한치과보철학회지
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• 제40권3호
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• pp.236-245
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• 2002

The acrylic resin was first introduced as denture base materials in 1937 and it is commonly used for denture base fabrication nowadays. Three different curing cycles (Conventional curing cycle, short curing cycle and long curing cycle) and three commercially available heat-activated acrylic resins (Vertex RS, Lucitone 199 and ProBase Hot) were investigated to find the curing cycle and material that showed the minimum shrinkage of the resin during polymerization process. A brass master mold was fabricated and duplicated by additional silicone impression material. Stone molds were made by pouring of type III dental stone (SILKY-ROCK YELLOW, Whip-Mix, Louisville, Kentucky). It was embedded in the flask. Strain gauge and thermocouple were embedded in the specimen. Strain gauge and thermocouple were connected to signal conditioning amplifier and data was recorded by pre-programmed software. The parameters ESmax (Maximum expansion strain), Sb (Strain measured just before deflasking procedure), Sa (Strain measured just after deflasking procedure) and Sf (Strain measured at the end of the experiment) were measured. ${\Delta}$S was calculated from Sb and Sa (${\Delta}$S=Sb-Sa). In the experiment concerned about materials, the parameters 90-ESmax (Maximum expansion strain measured during early 90 minutes of curing procedure), 180-ESmax (Maximum expansion strain measured from 90 minutes to 180 minutes), Sb, Sa, ${\Delta}$S and Sf were measured and the following conclusions were made. 1. The ESmax value of conventional curing cycle showed the largest value and the 180-ESmax value of Lucitone 199 showed the smallest value. 90-ESmax values showed no significant difference (p<0.05). 2. ${\Delta}$S values of conventional curing cycle showed the positive values. ${\Delta}$S values of short curing cycle and long curing cycle showed the negative values. All three materials cured by conventional curing cycle showed the positive values. 3. The Sf values of long curing cycle and ProBase Hot (cured by conventional curing cycle) showed the smallest values.

• 미생물학회지
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• 제24권2호
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• pp.106-112
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• 1986

자연계에서 분리한 Pseudomonas에서 크기가 매우 큰 plasmid (약 180 megadaltons:를 분리하였다. 이 plasmid는 기존의 plasmid 검출방법보다 더 온화한 조건에서 분리되었다. Alkalin., sodium dodecyl sulfate (pH 12. 45)를 사용하여 chromosomal DNA를 변성시킨 뒤 $55^{\circ}C$로 열처리 하여 covalently closed circular DNA 의 손실을 최대한으로 방지하였고, polyethylene glycol을 최종농도 10%로 첨가하여 plasmid DNA를 선택적으로 농축하였다. 한편, 이 plasmid는 mitomycin C를 처리하여 얻은 cured sitrains에서는 나타나지 않아 salicylate를 분해하는 새로운 plasmid로 확인되었다.

• 폴리머
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• 제25권3호
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• pp.327-333
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• 2001

아세틸렌기가 치환된 fluorene 유도체 2-ethynylfluorene과 2,7-diethynylfluorene을 합성하였고 이를 진공 증착하여 박막을 제조하였다. 심중결합이 치환된 fluorene 유도체들은 자외선 및 열에 의해 경화가 가능하였다. DSC 측정 결과 2-ethynylfluorene은 $231^{\circ}C$에서 그리고 2,7-diethynylfluorene은 198$198^{\circ}C$에서 경화가 일어나는 것이 관측되었다. 경화된 poly(2-ethynylfluorene) 및 poly(2,7-diethynylfluorene)의 분해는 380 및 385$^{\circ}C$에서 일어나기 시작하였으며 T$T_g$는 관측되지 않았다. 경화된 박막의 광발광 특성은 단량체와 매우 유사하나, 발광 효율은 3에서 10배 정도 감소하였다.

• Composites Research
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• 제14권2호
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• pp.33-42
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• 2001

DSC(differential scanning calorimetry)를 이용하여 S2-유리섬유/폴리에스터 프리프레그 복합재료의 경화반응식을 구성하였다. 구성된 경화식과 블리더의 수지 함침에 의한 열전달 조건의 변화를 고려하여, 두꺼운 복합재료의 두께 방향 위치에 따른 온도분포를 계산하였다. 유래섬유 복합재료의 경화중 온도과승을 줄이기 위한 방법으로 냉각 및 재가열 구간을 도입하여 경화 사이클을 개선하였다. 냉각-재가열 구간이 없는 기존의 경화 사이클과 개선된 경화 사이클로 두꺼운 복합재료를 각각 제조하여 short beam shear 시험 및 Barcol 경도시험을 실시하고, 그 결과를 비교하였다.

• 한국연초학회지
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• 제7권1호
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• pp.49-55
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• 1985

low grade leaves of flue-cured (N.C. 2326) and air-cured (Br 21) have been heated at $140^{\circ}C$ for 10 and 20 minutes, respectively. As heating duration increased, each contents of nicotine, total nitrogen, total sugar and free amino acid decreased in both leaves. The result obtained from this experiment are as following 1. Nicotine content decreased in both leaves. Heating for 10 and 20 minutes showed respectively nicotine decrease of 13.2% and 21.6% for Br 21 and 8.2% and 13.2% for N.C.2326. Decrease of total nitrogen and total sugar was inversely proportional to the heating duration. N.C. 2326 in the decrease out numbered Br.21 by the ratio 2: 1 for 10min.-heating, and 5:4 for 20 min.-heating. 3. Total free amino acid was decrease by 17.1% and 13.85 for N.C. 2326 and Br 21, respectively when heated for 10 min., and 25.6% and 26.5% respectively when heated for 20 min. When sucrose was added to Br 21, th decrease ratio of total free amino acid of Br.21 was increased. It is suggested that the addition of sucrose could promote the browning reaction in Br 21 leaves.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
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• pp.504-507
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• 1987

Interpenerating Polymer Networks (IPNs) are unique type of polymer blend, synthesized by swelling a crossed polymer (Epoxy) with second polymer (Silicon) and also we adopted Urethane as the second polymer. The relationship between dielectric and mechanical properties of high temperature curing IPNs(E/S, E/U) are investigated. The ratios of weight that we formed we re two kind of thing, one (E/S) about 1[wt%]. 3[wt%], 5[wt%], 7[wt%], 10[wt%], and the other (E/U) about 5[wt%], 15[wt%], 25[wt%]. It was heat-cured for 24hours at $100^{\circ}C$ 48 hours at $10^{\circ}C$, 5 hours at $130^{\circ}C$, 15hours at $130^{\circ}C$ in E/S and also for 5 hours at $130^{\circ}C$ in E/U. From the viewpoint of dielectric and mechanical properties, the optimum condition is obtained from the sample cured for 5hours at $130^{\circ}C$ for 1[wt%] in the E/S, and also obtained from the sample cure d for 5 hours at $130^{\circ}C$ in E/U.

• 한국연초학회지
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• 제18권2호
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• pp.150-159
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• 1996

In this study, to obtain the basic data for the optimum moisture control system, moisture adsorption characteristics, adsorption isotherms models for water and surface physical characteristics of burley and flue-cured tobacco were investigated. By the hypothesis' the phenomenon of moisture adsorption of tobacco is the same as the first order reaction, the wetting constant (k) and equilibrium moisture content were obtained. And activation energy, frequency factors were also calculated by applying its data to Arrhenius equation. The Kamei's empirical formula of moisture adsorption isotherms showed the best agreement with the experimental data and its correlation coefficient (r) was 0.997. It can be seen that specific surface area of burley is 157 m2/g, that of flue-cured is 152 m2/g, -△H1 of adsorbed monolayer is 45,972 J/mol, 45,486 J/mol, respectively, and the condensation heat (40,595 J/mol) being caught in adsorbed multilayer is less than that of monolayer.

• Advances in concrete construction
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• 제5권4호
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• pp.345-358
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• 2017

This paper describes the experimental investigation carried out to develop geopolymer concrete using rice husk ash (RHA) along with alccofine. The study reports the fresh and hardened properties of the geopolymer concrete (GPC) activated using alkaline solution. GPC were prepared using different RHA content (350, 375 and $400kg/m^3$), the molarity of the NaOH (8, 12 and 16M). The specimens were cured at $27^{\circ}C$ and $90^{\circ}C$. GPC was activated using NaOH, $Na_2SiO_3$, and alccofine. Prepared GPC samples were tested for compressive and splitting tensile strengths after 3, 7 and 28 days. RHA was suitable to produce geopolymer concrete. Results indicate that behavior of GPC prepared with RHA is similar to fly ash based GPC. Workability and strength can be improved by incorporating the alccofine. Further, alccofine and heat curing improve the early age properties of the GPC. Heat curing is responsible for the initial polymerization of GPC which leads to high workability and improved mechanical properties of the GPC. High strength can be achieved by using the high concentration alkaline solution in terms of molarity and at elevated heat curing. Further, RHA based geopolymer concrete has tremendous potential as a substitute for ordinary concrete.

• Elastomers and Composites
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• 제55권2호
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• pp.95-102
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• 2020

Currently, peroxide cure is a widely used cure system for rubber materials. To improve its effectivity, co-agents are used to enhance the peroxide efficiency and mechanical properties of rubber materials. Co-agents are multifunctional organic compounds that are highly reactive towards free radicals. These co-agents provide higher cross-link densities for a given peroxide concentration and improve the mechanical properties of peroxide-cured rubber composites. In this study, trimethylolpropane trimethacrylate (TMPTMA) and high vinyl 1,2-polybutadiene (HVPBD) were used as co-agents. In order to obtain a concentration that achieves a favorable balance between mechanical properties and co-agent concentration, this research investigated the effects of co-agent content on the curing characteristics, chemical structures, and mechanical properties of HNBR composites. Additionally, the heat aging properties and compression sets of HNBR composites were investigated. Based on the results, we found that the HNBR composites with TMPTMA co-agents exhibited higher Shore A hardness and 10% modulus and better heat aging resistance and compression set than that of the HVPBD co-agent. The heat aging resistance and compression set deteriorated with increasing HVPBD content.

• 대한치과기공학회지
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• 제35권4호
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• pp.333-341
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• 2013

Purpose: The purpose of this study was to evaluate the flexural strength of indirect composite resins with different polymerization conditions. Methods: Ten specimens ($2mm{\times}2mm{\times}25mm$) of each composite resins (Tescera (T), Gradia (S) and Sinfony (S)) were fabricated by two polymerization methods : manufacturers's and light heat pressure. Composite resins polymerized by manufacturers's method and light heat pressure served as control (TS, GS and SS) and experimental groups (TE, GE and SE), respectively. The composite resins were tested for flexural strength and the surface of composite resins were observed with scanning electron microscope (SEM) under X1,000 magnification. Results: The flexural strength values of cured composite resin decreased in the following order: TE (195.4MPa), TS (179.8MPa), GE (169.9MPa), SE (137.7MPa), SS (111.1MPa) and GS (100.9MPa) groups. Conclusion: The flexural strength values between the control and the experimental groups were not significantly different although experimental groups showed higher flexural strength values than control groups.