• Title/Summary/Keyword: hazardous substances

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Studies on Circumstances of Agricultural Water Quality (농업용수(農業用水)의 수질환경(水質環境) 조사분석(調査分析))

  • Suh, Seung Duk;Kim, Tae Han;Yoon, Kyung Duk
    • Current Research on Agriculture and Life Sciences
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    • v.1
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    • pp.85-93
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    • 1983
  • Total annual water requirements for agricultural use are exceedingly large. In many areas of the country, particularly in the arid regions, irrigation water requirements comprise the bulk of the total developed water supply. On the other hand, we are, at present, poorly prepared to evaluate the hazards of many substances in the water phase of the agricultural environments. This study is to survey the water quality phase of agricultural conditions and to give some ideas to prevent disasters from the environmental hazards such as PH, Electric Conductivity, BOD, DO, Cu, Pb, and Cd. In the analysed results, mean PH was 6.5 to 7.8, maximum EC was $200{\mu}{\Omega}/cm$ at $25^{\circ}C$, the maximum BOD was less than 10 ppm (standard value), the DO was 4.2 to 12.0 mg/L (standard value is more than 2.0 mg/L) and the Cu, Pb, Cd were estimated in scope of safety value respectively. Especially BOD is gradually closed with the hazardous point in the few places. At present, the hazardous environmental conditions originated from the municipal sewage, industrial waste, and human and domestic animals excrements etc. have to strongly be improved much better than before.

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A comparison of Health Hazard Effects by Solvent-based and Water-based Painting materials (유용성 도료와 수용성 도료의 유해성 비교에 관한 연구 (자동차 보수용 도료를 중심으로))

  • Kwon, Eun-Hye;Kim, Gwang-Sik;Oh, Jung-Ryong;Choi, Jung-Keun;Jeong, Yoon-Sok;Lee, You-Jin;Kim, Eun-A;Song, Se-Wook;Jung, Ho-Keun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.11 no.1
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    • pp.17-25
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    • 2001
  • The purpose of this study is to substitute water-based painting materials for the current solvent-based ones used in motor-repairing process to minimize the exposure of organic solvents to the painters. This study assessed the exposure of organic solvents to the painters using water-based and solvent-based painting materials and compared compositions, painting processes and the health hazards of the application of these alternative painting mate rials. The results of this study are as follows. 1. solvent-based painting materials used in motor-repairing process consist of various organic solvents, which consist primarily of toluene, xylene, ethyl benzene, ethyl methyl benzene, trimethyl benzene, ethyl acetate, butyl acetate, methyl isobutyl ketone, 2-ethoxy ethanol, 2-ethoxy ethyl acetate and toluene-2,4-diisocianate and the others. These organic solvents are known as health-hazardous substances. But water-based painting materials are high-solid, low-solvent one sand consist of such two organic solvents as 2-butoxy ethanol and 2-heptanone and the others. 2. The painters us ing solvent-based painting mate rials in motor-repairing process are exposed to various organic solvents which consist of toluene, xylene, ethyl acetate, butyl acetate, methyl isobutyl ketone, trimethyl benzene, 2-ethoxy ethanol, and 2-ethoxy ethyl acetate. But the painters using solvent-based ones are only exposed to 2-butoxy ethanol and 2-heptanone. 3. By using water-based painting materials in stead of solvent-based painting materials containing health-hazardous organic solvents, the exposure of such organic solvents in the painter's breathing zone can be largely prevented. 4. This study recommends water-based painting materials as substitutes for the current solvent-based ones used in motor-repairing process to minimize the exposure of organic solvents to the painters.

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A Study on the Improvement of Marine Pollution and Marine Litter Managements in Korea (우리나라 해양오염 및 해양폐기물관리 개선에 관한 연구)

  • Park, Kwang-Ha;Kwon, Young-Du;Kim, Jong-Sung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.4
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    • pp.33-43
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    • 2013
  • That occur in the ocean and the efficient management of marine litter on marine pollution oil spill response one step further strategies are needed. Marine pollution accidents occurred in 2011, a total of 287 and was found in runoff 369 kL, respectively compared to the previous year decreased by 13% and 39%. Average amount of marine materials during 5-years represent the oil flow of 310.5 kL (heavy fuel oil of 106.0 kL, diesel of 178.9 kL, oily bilge water of 22.3 kL, other oil of 7.7 kL) and the waste of 62.3 tons, the hazardous and noxious substances (HNS) was 510.6 kL. Marine emissions in 2011 by type of waste that a total amount of dumping 3,972 $m^3$, and livestock manure 795 $m^3$(20%), waste water 1,431 $m^3$(36%), sewage sludge 887 $m^3$(22%), wastewater sludge, 813 $m^3$(21%), manure 5 $m^3$(0.1%), other 41 $m^3$(0.9%), respectively. The concept of marine waste and needs to be more clearly defined. Integrated management of hazardous chemicals according to the incident management system should be established. To remove of coastal pollution, response officer needs korean coast response system. Like the marine pollution response, coastal pollution response systems also require step response.

A study on the development of phthalate plasticizers CRM in ABS resin (ABS 중 phthalates 가소제 CRM 개발에 대한 연구)

  • Jung, Jung-Sul;Park, Jung-Woo;Yoo, Seok;Kweon, Seong-Il;Hong, Sung-Taeg;Sun, Yle-Shik;Park, Cheon-Min;Choi, Chang-Hyoo
    • Analytical Science and Technology
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    • v.25 no.5
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    • pp.273-283
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    • 2012
  • Phthalate plasticizers are regulated by RoHS, REACH and CPSC as hazardous substances. Responding to these international environmental restrictions, we developed ABS certified reference material (CRM) for determination of phthalate plasticizers such as DMP, DEP, DBP, BBP, DEHP and DnOP. The candidate material has been made with ABS resin widely used in electric and electronic products and 6 kinds of phthalate plasticizers. The making of the material involved a series of processes like extruding, cooling, pelletizing, and drying using twin screw extruder. Then it has been certified according to ISO Guide 35. Using isotope dilution-gas chromatography/mass spectrometry (ID-GC/MS), homogeneity, short-term stability, and long-term stability were evaluated. The certified values were determined by using primary reference material (PRM) of KRISS for traceability. From now on, we will provide ABS CRM to national and international companies and research institutes after certification as certified reference material and registering on COMAR (code of reference material).

Characterization of Secondary Exposure to Chemicals and Indoor Air Quality in Fire Station (소방서 실내공간의 화학적 유해인자 2차노출과 실내공기질 특성)

  • Kim, Soo Jin;Ham, Seunghon;Jeon, Jeong Seok;Kim, Won
    • Fire Science and Engineering
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    • v.33 no.4
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    • pp.140-151
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    • 2019
  • It is to assess the indoor air quality of the chemical hazardous materials exposed to the fire after firefighters returned to the fire scene. The research subject randomly selected four fire stations located in Seoul, Korea. Two fire stations were set up as control groups after the return of the firefighting activities at the actual fire scene, and two other fire stations were set up as control groups to measure the air quality of the room at normal levels regardless of the action. We conducted 24-hour monitoring for all fire accidents that occurred in Seoul Metropolitan using fire safety map computer system. Also, indoor air quality was measured immediately after homecoming if the experiment group was to be dispatched due to an accident of intermediate or larger scale. 11 hazardous substance items such as fine dust, formaldehyde, volatile organic compounds, PAH, VCM, acidity, asbestos, CO2, NO2, O3 were measured according to the process test method. Three of 11 types of harmful substances exceeded domestic and foreign standards, and one of them was found to be close to foreign standards. In particular, total volatile organic compounds, carbon dioxide and sulfuric acids were 2.5 times, 2.2 times and 1.1 times higher than the standard. Also, for formaldehyde and sulfuric acid, it was measured higher in the control group than in the case group. This findings could be used in policies to improve indoor air quality in the fire station of the Seoul Metropolitan Government.

A Study of Working Environment for Automotive Painting in Auto Repair Shops and Workers' Exposure to Hazardous Chemicals (자동차 정비업체 도장공정의 작업환경 및 근로자 노출 실태에 관한 연구)

  • Sim, Sang-Hyo;Jeoung, Chun-Hwa;Lim, Jin-Suk;Lee, Hyung-Gu;Kim, Yoon-Shin
    • Journal of Environmental Health Sciences
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    • v.35 no.3
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    • pp.153-161
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    • 2009
  • The purpose of this paper is to evaluate 1) blood lead levels of workers at auto repair shops as Biological Exposure Indices (BEI) of toxic substances such as lead and toluene that are produced during automotive painting process, 2) the differences depending on personal characteristics of workers who have been exposed to toluene by using urine hippuric acid concentration as a marker and 3) the correlation between the concentration of hazardous chemicals in each workplace and the BEL. All subjects were male with a mean age of 36.2 years. In terms of age, most were in the 30 to 40 age group (13 persons, 48.1%). In relation to the length of work experience, the highest proportion had experience of 10 years of less (18 persons, 66.7%). Twenty three workers were cigarette smokers (85.2%) while 4 (14.8%) were non-smokers. In addition, more than 80% of the workers drank alcohol. Dust concentration and toluene exposure during automotive painting showed no significant difference with age, length of work experience, smoking and drinking while a significant difference (p<0.05) has been detected between lead concentration and smoking. The geometric mean of dust concentration, lead concentration and toluene concentration were $0.38mg/m^3,\;0.0021mg/m^3$ and 1.08ppm respectively. In addition, the geometric mean of blood lead levels and urine hippuric acid concentration were $1.70{\mu}g/dl$ and 0.25g/g respectively, which were lower than the standard levels suggested by the Ministry of Labor. To determine the influential factors on blood lead and urine hippuric acid concentrations, a correlation analysis has been conducted with variables of air, lead and toluene concentrations, age, length of work experience and amount of cigarette smoking. According to the analysis, a relatively high correlation (p<0.01) has been observed between air lead concentration and biological sample concentration.

Limits of Innovation in Korean Medicine Industry (한의학산업의 혁신 저해요인)

  • Ku, Nam-Pyong;Seol, Sung-Soo
    • Journal of Korea Technology Innovation Society
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    • v.18 no.4
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    • pp.667-692
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    • 2015
  • The study examined the Korean medicine industry from the perspective of the innovation system theory of each business, while it concentrated on the conflict between traditional Korean medicine and Western medicine, which have a major influence on the innovation system of Korean medicine industry, rather than the innovation system itself. The Korean healthcare system is a dual system of Western and Korean medicine, yet the definitions of Western medical practices and Korean medical practices are ambiguous. Thus the distinction of dual system depends on judicial precedents, and the innovation of Korean medicine has been inhibited due to the excessive emphasis placed on the Western medical practice in both healthcare system and pharmaceutical system. First of all, the usage of most medical devices derived from the development of modern medical engineering is not permitted in the Korean medicine industry, on the basis that most of the medical devices were originated from the Western medicine field. Secondly, new drugs using natural substances, once approved by the drug administration, cannot be prescribed by the Korean medicine industry although they are developed based on Korean medicine. Thirdly, the major safety issues on herbal medicine are about hazardous materials in medicinal herbs and liver toxicity of prescribed herbal medicine. The problem of hazardous materials can be solved by appropriate quality and safety tests in the cultivation and importation process. Whereas the Korean medicine circles points out that the liver toxicity issue is only a unilateral condemnation by the Western medicine circles.

Numerical Modeling for Effect on Bund Overtopping Caused by a Catastrophic Failure of Chemical Storage Tanks (저장시설의 순간 전량 방출 시 방류벽의 월파 효과에 대한 수치모델링)

  • Min, Dong Seok;Phark, Chuntak;Jung, Seungho
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.42-50
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    • 2019
  • As the industry develops in Korea, the use of hazardous chemicals is increasing rapidly and chemical accidents are increasing accordingly. Most of the chemical accidents are caused by leaks of hazardous chemicals, but there are also accidents in which all the substances are released instantaneously due to sudden high temperature/pressure or defection of the storage tanks. This is called catastrophic failure and its frequency is very low, but consequence is very huge when it occurs. In Korea, there were 15 casualties including three deaths due to catastrophic rupture of water tank in 2013, and 64 instances of failures from 1919 to 2004 worldwide. In case of catastrophic failure, it would be able to overflow outside the bund that reduces the evaporation rate and following consequence. This incident is called overtopping. Overseas, some researchers have been studying the amount of external overflow depending on bund conditions in the event of such an accident. Based on the previous research, this study identified overtopping fraction by condition of bund in accordance with Korea Chemicals Controls Act Using CFD simulation. As a result, as the height increases and the distance to the facility decreases while meeting the minimum standard of the bund capacity, the overtopping effect has decreased. In addition, by identifying the effects of overtopping according to atmospheric conditions, types of materials and shapes of bunds, this study proposes the design of the bund considering the effect of overtopping caused by catastrophic failure with different bund conditions.

Korea Total Diet Study-Based Risk Assessment on Contaminants Formed During Manufacture, Preparation and Storage of Food

  • Kwon, Kisung;Jo, Cheon-Ho;Choi, Jang-Duck
    • Journal of Food Hygiene and Safety
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    • v.36 no.3
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    • pp.213-219
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    • 2021
  • Hazardous substances are formed during food manufacturing, processing, or cooking, and may pose a threat to food safety. Here, we present a dietary exposure assessment of Korean consumer's intake of hazardous materials through a Total Diet Study (TDS) which was conducted by the Ministry of Food and Drug Safety (MFDS). The levels of exposure to materials such as acrylamide, furan, biogenic amines, etc., were estimated and risk assessments were then performed. Acrylamide and furan were selected as hazards with high priority of reduction control due to their having a margin of exposure (MOE) lower than 10,000. Risk assessment of exposure to ethyl carbamate, benzene and 3-MCPD showed MOEs higher than 100,000, indicating "safe". Dietary exposure to polycyclic aromatic hydrocarbons and benzopyrene was also found to be safe MOE levels >10,000. In addition, the results indicated safe MOEs (>1,000,000) for heterocyclic amines, nitrosamines, and biogenic amines. Most of the potential food contaminants were being kept at safe levels, however, it is necessary to continue to monitor and control exposure levels in accordance with the 'as low as reasonably achievable' (ALARA) principle.

Safety investigation of the moisturizing medium prepared using the Chinese oak mushroom (Lentinula edodes) based on the presence of residual pesticides, heavy metals, and radioactive materials (중국산 표고(Lentinula edodes) 보습배지의 잔류농약, 중금속 및 방사능 안전성 분석)

  • Jang, Eun-Kyoung;Jeong, Sang-Wook;Jang, Hye-Mi;Ban, Seung-Eon
    • Journal of Mushroom
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    • v.20 no.1
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    • pp.22-28
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    • 2022
  • In order to provide basic data for preparing management standards and to verify the safety of the Chinese oak mushroom-derived moisturizing medium-which is synthesized and imported in large quantities-the presence of 321 residual pesticides, 7 heavy metals, and 3 radioactive materials was analyzed in the moisturizer samples. Examination of residual pesticides in seven moisturizing medium samples prepared using the Chinese oak mushroom and three domestic sawdust samples used for mushroom culture revealed the presence of cypermethrin and iprodione in three moisturizer samples, but the contents of these pesticides were below the standard limits. Zn was detected in ten samples, Cu was detected in nine samples, and Ni was detected in four samples, but their contents were below the standard limits. Pb, Cd, Cr, and Hg were not detected in any sample. No radioactive materials were detected in the samples. In addition, fruiting bodies of the oak mushroom were observed in each medium. Examination did not reveal the presence of any residual pesticides or harmful compounds. In this study, the use of the moisturizing medium prepared using the Chinese oak mushroom was found to be safe. As residual pesticides, heavy metals, and radioactivity-even in trace amounts-remain concentrated in the human body, continuous verification of the safety of hazardous substances and pollutants during the systematic cultivation and management of these mushrooms is required.