• Environmental Engineering Research
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• v.24 no.2
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• pp.191-201
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• 2019

Petroleum industry produces one of the popular hazardous waste known as Petroleum Sludge. The treatment and disposal of petroleum sludge has created a major challenge in recent years. This review provides insights into various approaches involved in the treatment, and disposal of petroleum sludge. Various methods used in the treatment and disposal of petroleum sludge such as incineration, stabilization/solidification, oxidation, and bio-degradation are explained fully and other techniques utilized in oil recovery from petroleum sludge such as solvent extraction, centrifugation, surfactant EOR, freeze/thaw, pyrolysis, microwave irradiation, electro-kinetic method, ultrasonic irradiation and froth flotation were discussed. The pros and cons of these methods were critically considered and a recommendation for economically useful alternatives to disposal of this unfriendly material was presented.

• Journal of environmental and Sanitary engineering
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• v.18 no.4
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• pp.36-44
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• 2003

The cement-based system among S/S(Solidification/Stabilization) is widely used to treat hazardous wastes. In this study, tannery sludge was solidified to evaluate the stabilization effects of using admixtures in the cement-based S/S. Fly ash as substitute also used to increase the strength of the S/S of hazardous waste. The compressive strength measurement and leaching experiment of chromium metal of solidified mortar were carried out to compare and evaluate the physical and chemical characteristics of solidified hazardous waste sludge. From the result of this study, there was increased of compressive strength by using AEW-3(early-hardening AE water reducing agent), and leaching concentration of chromium became low enough to satisfy the regulatory criteria. The successful solidification for the organic contaminant and heavy metal in hazardous waste should enable to treat by cement-based system using early-hardening AE water reducing admixture and fly ash as substituted cement.

• Journal of the Korea Organic Resources Recycling Association
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• v.4 no.2
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• pp.47-53
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• 1996

This study was carried out to estimate the amount and the characteristics of sewage sludge disposed of in the Nanjido sludge landfill site. Boring test was conducted to estimated the landfill volume and to get sludge samples to be analyzed. Total analysis and leaching test were performed to find the characteristics of sewage sludge. The Nanjido sludge landfill site had the surface area of $50,000m^2$ and the average depth of 15m. The estimated sludge volume was 600,000ton. Sewage sludge in Nanjido sludge landfill site was very stable. Results of total analysis of heavy metals indicated that the sludge could be classified as a non-hazardous waste according to the California state regulation. The sludge also could be used as compost based on compost quality criteria of foreign countries. Results of Korea Extraction Procedure showed that sewage sludge in Nanjido sludge landfill site was not a hazardous waste.

• Journal of environmental and Sanitary engineering
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• v.24 no.3
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• pp.28-36
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• 2009

We have closely examined the concentration change characteristics, emission amounts, and the material balance of hazardous air pollutants at both early and later stages of the prevention facilities. These results will be uses as the basic data when preparing for the regulatory and management plans for hazardous air pollutants. The results of the study on heavy metals illustrated that the content of heavy metals in sludge across five facilities were as follows: copper> zinc> chrome> nickel> cadmium> mercury. In terms of heavy metal content in swage sludge, the sludge in incinerating facilities other than the sludge in the D incinerating facility containing industrial water waste, was examined in order to satisfy the ocean contamination standard and fertilizer specifications. Most of the items were shown to have satisfied the emission tolerance standards in the latter part of the prevention facilities(The average elimination rate was over 90%). Therefore, it is concluded that swage sludge containing high-concentrate heavy metals needs to be incinerated rather than recycled as fertilizer.

• Magazine of the Korean Society of Agricultural Engineers
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• v.40 no.4
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• pp.77-84
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• 1998

Adsorption and leaching characteristics of the artificial soils produced from water and wastewater treatment sludges were examined. The batch adsorption test and TCLP leaching test were used, and constituents of interest were heavy metals and nutrients. As, Cr, Cu, Pb, and Cd were analyzed for metals, and nitrogen and phosphorus were analyzed for nutrients. All the artificial soils showed strong adsorption and low leaching for the heavy metals, which implies that the artificial soils may not be hazardous to the environment due to heavy metals and even they can be utilized effectively to remove metals in solution like mine and industrial wastewaters. This is quite promising result because in most case heavy metals are the most concern in the application of sludge product to the farmland. For the nutrients, generally, artificial soils showed high adsorption and low leaching except artificial soil from wastewater sludge produced by low temperature firing. The artificial soils produced from water treatment sludge were active in adsorbing nutrients and showed low leaching that they can be practically used to remove nutrients in advanced treatment process of the wastewater. The artificial soils produced from wastewater treatment sludge were less active in adsorbing nutrients and showed high teaching. However, they could be used usefully if applied properly to the plant growing because of their fertilizing effect. Based on the test results, overall, the artificial soils were thought to be not hazardous to the environment and they could be more useful if applied properly.

• Environmental Engineering Research
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• v.21 no.2
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• pp.140-144
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• 2016

Owing to the kinetic differences in ammonia oxidation among ammonia-oxidizing microorganisms (AOM), there is no standard set of kinetic values that can be used as a representative set for nitrifying wastewater treatment plant (WWTP) design. As a result, this study clarified a link between the half-saturation constants for ammonia oxidation (Ks) and the dominant ammonia-oxidizing bacterial (AOB) groups in sludge from full-scale WWTPs and laboratory-scale nitrifying reactors. Quantitative polymerase chain reaction analyses revealed that AOB affiliated with the Nitrosomonas oligotropha cluster were the dominant AOM groups in the sludge taken from the low-ammonia-level WWTPs, while AOB associate with the Nitrosomonas europaea cluster comprised the majority of AOM groups in the sludge taken from the high-ammonia-level WWTPs and nitrifying reactors. A respirometric assay demonstrated that the ammonia Ks values for the high-ammonia-level WWTPs and nitrifying reactors were higher than those of the low-ammonia-level plants. Using the Ks values of available AOM cultures as a reference, the Ks values of the analyzed sludge were mainly influenced by the dominant AOB species. These findings implied that.different sets of kinetic values may be required for WWTPs with different dominant AOM species for more accurate WWTP design and operations.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.165-172
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• 2004

Co-incineration of coal and wastewater sludge was r;erfonn:rl in a O.lMWth bench scale circulating fluidized bed combustor(CFBC) Sludge was received from a wastewater treatment plant in a dye industrial complex in Busan. Metropolis. Moisture content of received sludge was 80%. Coal and sludge mixture was prepared with weight ratio of 90/10, 85/15 and 80/20. Co-combustion characteristics of the coal and sludge mixture demonstrated stable combustion conditions. Component analysis, incineration characteristics, boiler performance was measured before and after the test and application for commercial 59MWth CFBC boiler. The release of hazardous components such as $SO_2$ and Cl was suppressed by the presence of inherent minerals of Ca, Na, K in coal and sludge mixture. Pre-drying was not essential but it was recommended for the benefits of manageability of sludge.

• Journal of Environmental Health Sciences
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• v.19 no.2
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• pp.46-54
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• 1993

This study was carried out on the stabilized/solidified treatment for the reducing leachability of hazardous heavy metals copper, lead, chromium and cadmium in the hazardous sludge which treated to be unleached heavy metals by sodium diethyl dithiocarbamate. Cement matrix was analyzed for the leachability of 24 hrs and dynamic leaching test, structure and the optimum condition for the stabilization and solidification of the hazardous sludge. In 28 days of curing time the unconfined compressive strength was 21.5 kg/cm$^2$ at the ratio of portland cement (0.5)+fly ash (0.25) and 23.5 kg/cmz at the ratio of portland cement (0.5)+fly ash (0.25) + cake (0.25). High concentration of Pb, Cr and Cd in the sea water and Cu in the distilled water were leached at the dynamic leaching test. The concentration of leaching heavy metals for specimens which were tested 24 hrs were found low leachability with decreasing pH of leachant. According to dynamic leaching test, the low level of copper, lead, cadmium and chromium were leached in the cement matrix with sodium diethyl dithiocarbamate. But the effective diffusion coefficient of unleached cement matrix which was treated sodium diethyl dithiocarbamate was decreased above 2 times than that of cement matrix. The relation of leachant renewal period (Y) and cumulative fraction ion leached (X) was the following regression equations. Solidification with unleached agent. Y$_{Cu}$ = 1413752X + 247, Y$_{Pb}$ = 223501IX + 214, Y$_{Cr}$ = 8310601X - 472, Y$_{Cd}$ = 168787X + 1061 The structure of' solidified matrix with X-ray diffraction analysis was composed more Ca(OH)$_2$, Si, Mg(OH)$_2$ and Al in the unleached cement matrix than those in cement matrix.

• Analytical Science and Technology
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• v.19 no.2
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• pp.172-180
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• 2006

This study was performed to establish new methods for hazardous substances and to develop an analytical method in specified wastes for preventing the environmental pollution caused by hazardous wastes. Therefore, the trends of international management, regulatory criteria, and items of hazardous wastes in various countries were investigated. Based on this study, target priority of new hazardous substances in specified wastes was established. An analytical method was developed using the waste standard reference materials of sludge, oil, bottom ash, etc., which contain the new hazardous substances (Ba, Be, Cr(VI), F, Ni, Sb, Se, and V). A total of 37 waste samples from the representative facilities, which are emitting new hazardous substances, were analyzed.

• Environmental Engineering Research
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• v.10 no.1
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• pp.38-44
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• 2005

Electro-thermal production of white phosphorus(WP, P4) generates substantial amount of highly toxic phossy water and sludges. Because of their high phosphorus contents and lack of reliable processing technology, large tonnages of these hazardous wastes have accumulated from current and past operations in the United States. In this study, two different methods for treatment of phosphorus sludge were investigated. These were bulk removal of WP by physical separation(froth flotation) and transformation of WP to oxyphosphorus compounds by air oxidation in the sludge medium. Kerosene, among other collectors, resulted in selective flotation of WP from the associated mineral gangue. Solvent action of kerosene occurring on the WP surface(by rendering WP particles hydrophobic) might produce the high selectivity of WP. The WP recovery in the froth was 79.3% from a sludge assaying 34.2% of WP. In the oxidation study, air gas was dispersed in the sludge medium by the rapid rotation of the impeller blades. The high level of sludge agitation intensity caused a fast completion of the oxidation reactions and it resulted in the high percentage conversion of WP to PO4-3 with PO3-3 making up almost all portion of oxyphosphorus compounds. The WP analysis on the treated sludge showed that supernatant solution and solid residue contained an average of 4.2 μg/L and 143 ppm respectively from the sludge containing about 26 g of WP. Further investigation will be required on operational factors to better understand the processes and achieve an optimum condition.