• 제목/요약/키워드: hazardous metal

검색결과 231건 처리시간 0.032초

용출실험에 의한 석분토의 지표환경 오염 평가 (Assessment of Environmental Contamination caused by the Stone-dust using Leaching Tests)

  • 강민주;이평구;염승준
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제15권3호
    • /
    • pp.52-60
    • /
    • 2010
  • The stone-dust is an unavoidable by-product of aggregate production, which is produced about 0.8~1.0 million $m^3$ annually. The stone-dust is currently regarded as a hazard material on environment because it is classified as an industrial waste in the Waste Management Law of Korea. At present, the stone-dust is considered as a environmentally hazardous material, and is classified as an industrial waste according to the Waste Management Law of Korea. In this study, we assessed the heavy-metal contamination of the stone-dust on surrounding environments by various leaching tests. Leaching experiments (such as Korea Standard Leaching Procedure (KSLP), Soil Environment Preservation Act of Korea (SEPAK), Toxicity Characteristic Leaching Procedure (TCLP), and Synthetic Precipitation Leaching Procedure (SPLP)) show that very low heavy metals (As, Cd, Cu, Pb, Zn, Hg) and CN are leached out, or much less than each regulatory thresholds. The resuts of the leaching test with time in acidic solution (initial pH 5 and 3) indicate that pH-buffering minerals are present in the stone-dust. These results suggest that the stone-dust can not potentially affect adverse impact on surrounding environments such as surface water, groundwater and soil etc..

온산공단(溫山工團) 주변 농작물(農作物)의 중금속(重金屬) 농도조사 (A Survey on the Heavy Metal Concentrations of Crop Materials Grown near Onsan Industrial Complex)

  • 이서래;송기준
    • 한국환경농학회지
    • /
    • 제5권1호
    • /
    • pp.43-47
    • /
    • 1986
  • 온산(溫山)공업단지 조성(造成)에 따른 농작물(農作物)의 오염(汚染)가능성을 조사하기 위하여 1978년 3월부터 12월에 걸쳐 주변 농경지에서 재배된 농작물(農作物)(수도, 보리, 대두, 채소, 과일)중의 중금속 농도를 분석한 결과는 다음과 같다. 중금속 함량은 농작물의 종류, 부위, 재배지역에 따라 약간의 차이가 있었으나 일정한 경향은 찾아 볼 수 없었다. 분석한 농작물 시료의 평균치(平均値)를 보면(풍건물(風乾物)기준) As 0.23 ppm, Cd 0.46 ppm, Cu 4.88 ppm, Hg 0.09 ppm, Pb 3.86 ppm, Zn 41.3 ppm으로서 이 지역에 대한 자연함유량(自然含有量) 기준(基準)으로 이용할 수 있을 것이다.

  • PDF

PEO-PPO-PEO 블록공중합체를 사용한 마이셀 증진 한외여과법 (유해유기물의 가용화 및 분리특성) (Micellar Enhanced Ultrafiltration Using PEO-PPO-PEO Block Copolymer)

  • 최영국;이동진;김정훈;김동권;이수복
    • 한국막학회:학술대회논문집
    • /
    • 한국막학회 1998년도 춘계 총회 및 학술발표회
    • /
    • pp.83-86
    • /
    • 1998
  • 1. Introduction : Low molecular harmful organics such as 1-naphthol and phenol are widely used in industries, and pose serious environmental problems. Wastewater containing low molecular harmful organics may be ejected from various sources including metal-plating industries, circuit-board manufacturing process, photographic and photo-processing industries, refineries and metal-tailing leachate. The pollution of nation harbors, waterways and ground water resources with these organics has reached critical portions, and might also give hazardous influence on human health. Micellar enhanced ultrafiltration(MEUF) is a recently developed process to remove dissolved organics and/or heavy metals present in small or trace quantities from aqueous solution. In this system, the fatal defect is leakage of surfactants especially at low concentration below CMC(critical micelle concentration), which becomes a secondary pollution. Our group proposed to use biosurfactant and polymeric micelle to solve problems mentioned above. In this study we investigated a modified MEUF using PEO-PPO-PEO (polyethyleneoxide-polypropyleneoxide-polyethyleneoxide) block copolymers for the removal of organic solutes such as 1-naphthol and phenol from aqueous wastewater. We proposed PEO-PPO-PEO block copolymers as new surfactants for forming micelles in MEUF, and investigated the solubilization characteristics and efficiency for the removal of 1-naphthol and phenol. PEO-PPO-PEO block copolymers are, environmentally mild and safe as biosurfactants.

  • PDF

Review on metallic components released due to the use of electronic cigarettes

  • Mishra, Vinit K.;Kim, Ki-Hyun;Samaddar, Pallabi;Kumar, Sandeep;Aggarwal, M.L.;Chacko, K.M.
    • Environmental Engineering Research
    • /
    • 제22권2호
    • /
    • pp.131-140
    • /
    • 2017
  • The use of electronic cigarettes (ECs) is recognized as a source of many pollutants, just like conventional cigarettes (CCs). The analysis of EC aerosol samples has confirmed the presence of various metallic species. Most of these metals originate from various parts of the cartomizer, e.g., solder joints, wires, and silicate beads. The metal concentration levels in EC samples were shown to be generally two to four orders of magnitude lower than those of CCs. However, the use of ECs can still pose significant human health hazards as consumers are exposed to the toxicity of those metals and many other hazardous pollutants released simultaneously via the vaping of ECs. The review also describes the detection and quantification of various metals in ECs and CCs. This review was carried out to assess the level of metal species released from ECs and to suggest proper guidelines to control consumer exposure.

Effect of creep on behaviour of steel structural assemblies in fires

  • Cesarek, Peter;Kramar, Miha;Kolsek, Jerneja
    • Steel and Composite Structures
    • /
    • 제29권4호
    • /
    • pp.423-435
    • /
    • 2018
  • There are presently two general ways of accounting for hazardous metal creep in structural fire analyses: either we incorporate creep strains implicitly in hardening model ('implicit-creep' plasticity) or we account for creep explicitly ('explicit-creep' plasticity). The first approach is simpler and usually used for fast engineering applications, e.g., following proposals of EN 1993-1-2. Prioritizing this approach without consideration of its limitations, however, may lead to significant error. So far the possible levels of such error have been demonstrated by few researchers for individual structural elements (i.e., beams and columns). This paper, however, presents analyses also for selected beam-girder assemblies. Special numerical models are developed correspondingly and they are validated and verified. Their important novelty is that they do not only account for creep in individual members but also for creep in between-member connections. The paper finally shows that outside the declared applicability limits of the implicit-creep plasticity models, the failure times predicted by the applied alternative explicit-creep models can be as much as 40% shorter. Within the limits, however, the discrepancies might be negligible for majority of cases with the exception of about 20% discrepancies found in one analysed example.

Toxicometallomics of Cadmium, Manganese and Arsenic with Special Reference to the Roles of Metal Transporters

  • Himeno, Seiichiro;Sumi, Daigo;Fujishiro, Hitomi
    • Toxicological Research
    • /
    • 제35권4호
    • /
    • pp.311-317
    • /
    • 2019
  • The transport systems for metals play crucial roles in both the physiological functions of essential metals and the toxic effects of hazardous metals in mammals and plants. In mammalian cells, Zn transporters such as ZIP8 and ZIP14 have been found to function as the transporters for Mn(II) and Cd(II), contributing to the maintenance of Mn homeostasis and metallothionein-independent transports of Cd, respectively. In rice, the Mn transporter OsNramp5 expressed in the root is used for the uptake of Cd from the soil. Japan began to cultivate OsNramp5 mutant rice, which was found to accumulate little Cd, to prevent Cd accumulation. Inorganic trivalent arsenic (As(III)) is absorbed into mammalian cells via aquaglyceroporin, a water and glycerol channel. The ortholog of aquaporin in rice, OsLsi1, was found to be an Si transporter expressed in rice root, and is responsible for the absorption of soil As(III) into the root. Since rice is a hyperaccumulator of Si, higher amounts of As(III) are incorporated into rice compared to other plants. Thus, the transporters of essential metals are also utilized to incorporate toxic metals in both mammals and plants, and understanding the mechanisms of metal transports is important for the development of mitigation strategies against food contamination.

Surface removal of stainless steel using a single-mode continuous wave fiber laser to decontaminate primary circuits

  • Song, Ki-Hee;Shin, Jae Sung
    • Nuclear Engineering and Technology
    • /
    • 제54권9호
    • /
    • pp.3293-3298
    • /
    • 2022
  • Removing radioactive contaminated metal materials is a vital task during the decommissioning of nuclear power plants to reduce the cost of the post-dismantling process. The laser decontamination technique has been recognized as a key tool for a successful dismantling process as it enables a remote operation in radioactive facilities. It also minimizes exposure of workers to hazardous materials and reduces secondary waste, increasing the environmental friendless of the post-dismantling processing. In this work, we present a thorough and efficient laser decontamination approach using a single-mode continuous-wave (CW) laser. We subjected stainless steels to a surface-removal process that repetitively exposes the laser to a confined region of ~75 ㎛ at a high scanning rate of 10 m/s. We evaluate the decontamination performance by measuring the removal depth with a 3D scanning microscope and further investigate optimal removal conditions given practical parameters such as the laser power and scan properties. We successfully removed the metal surface to a depth of more than 40 ㎛ with laser power of 300 W and ten scans, showing the potential to achieve an extremely high DF more than 1000 by simply increasing the number of scans and the laser power for the decontamination of primary circuits.

농작물중(農作物中) 중금속오염도(重金屬汚染度)와 1일섭취량(日攝取量) 및 허용기준설정(許容基準設定)에 관(關)한 연구(硏究) (A Study on the Crops Pollution with Heavy Metal)

  • 염용태;배은상;윤배중
    • Journal of Preventive Medicine and Public Health
    • /
    • 제13권1호
    • /
    • pp.3-12
    • /
    • 1980
  • Certain heavy metals which may lead peoples to poisonous status are widely used in industry and their uses have been increasing along with rapid industrialization of this country. Such an increasement of metal uses aggravates the status of environmental pollution affecting foodstuffs which are the most important life supporting factor of animal and humanbeing. Concerning the safety measures to minimize food-borne transmission of such hazardous metals, surveillance is the backbone of them and probably more so with a potential problem such as intoxication. Theoretically, this surveillance should include the determination of levels of heavy metal toxicants in foods, the determination of food consumption patterns and typical total diet, and the estimation of total load of the metal contaminant from all sources of exposure including air, water, and occupational sources. In recent year, actually, such estimates on the total daily intake of some heavy metals from foods have been made in several developed countries and a wide variation of date by season, locality, and research method was recognized. Also in this country, this kind of research data is vitally needed to make up for the serious shortage or lack of references to estimate the total amount of heavy metal intake of the people. In this study, a modification model for estimation of the total daily intake of cadmium copper, nickel, zinc, and lead through foods was applied and concentrations of the above metals in crops cultivated in this country were measured with atomic absorption spectro photometer to get the following results. 1. Level of heavy metal concentration in crops Generally, the levels of such metals in essential crops such as rice, cucumber, radish. chinese cabbage, apple, pear, grape, and orange are similar or lower than those in Japan and other developed countries. By the way, a striking result on cadmium concentration was increasement of its concentration in rice from $0{\sim}0.035ppm$ in 1970 to 0.11ppm in this study. However, the value is still far below the. Japanese Permissible Lebel of 1.0ppm. 2. Estimation of total daily intake per capita from foods A new model for estimation was devised utilizing levels of metal concentration in foods, amount of food consumed, and other food factors. Based on the above method, the daily intake of cadmium was estimated to be $70.53{\mu}g/man/day$ in average which was as high as the Limit Value of ILO/WHO(up to $71.4{\mu}g/man/day$). Also, 3.89mg of Zinc, 1.65mg of cuppor, 0.32mg of lead were given as the total daily intake per capita by this research. 3. Efficacy of washing or skinning to decrease the amount of metals in crops After washing the crops sufficiently with commercial linear alkylate sulfonate, the concentration of heavy metals could be reduced to $50{\sim}80%$ showing decreasement rate of $20{\sim}50%$. Also, after skinning the fruits, decreasement rate of the heavy metal concentration shelved $0{\sim}50%$.

  • PDF

Welding Fume and Others from Welding Processes

  • Yoon, Chung-Sik
    • 한국환경보건학회지
    • /
    • 제30권4호
    • /
    • pp.320-328
    • /
    • 2004
  • A number of health hazards are generated in welding processes. In this paper, the characteristics of fumes and some other hazardous agents in welding are reviewed. Fumes in welding are generated by complex mechanism like physical ejection of particles, oxidation-enhanced vaporization, vaporization-condensation-oxidation, and spatter contribution. Fume generation rates could be described as a power function in a given process. Most of fume constituents was originated from consumables rather than base metal. The mass distribution for the welding fumes is unimodal and very small to penetrate respiratory system. So, almost fractions of fumes are classified into the respirable particulate mass. Total chromium contents in FCAW were similar to those from SMAW whereas hexavalent chromium concentrations in fume were similar to those produced from MIG welding fume. Hexavalent chromium was mostly soluble which was similar to the characteristic solubility of fume hexavalent chromium from SMAW.

지중 금속구조물 부식감시를 위한 측정단자함 인입형 소형 계측 장치개발에 관한 연구(II) (development of small size corrosion monitoring system for under ground metal structures)

  • 이재덕;배정효;하태현;이현구;하윤철;김대경
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2004년도 학술대회 논문집 정보 및 제어부문
    • /
    • pp.104-106
    • /
    • 2004
  • There are many under grounds facilities like oil pipes, gas pipes, water pipes, oil tanks, etc. and severe corrosion of these facilities made big problems. Fire, wide area water and soil pollution, massive and hazardous explosion, etc. can make big problems and cause big economical loss. So, various technologies were developed to keep these undergrouns facilities safely, and cathodic protection is one of it. For cathodic protection, one must detect potential of pipes, and there are so many test box to check pipes potentials. In this thesis, we describe on the development of small size corrosion monitoring system that measure pipes potentials easily and economically.

  • PDF