• Title/Summary/Keyword: harmful material

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A Thermal Study of the Harmful Chemical Species of Charcoal and Their Transformation during Combustion (숯의 유해물질과 이들의 연소 중 상변화에 대한 열분석 연구)

  • Yoon, Hye-On;Kim, Ki-Hyun
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.2
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    • pp.101-110
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    • 2011
  • Charcoal burning in the process of manufacture and ordinary use often release many constituent chemical species. As a result of open burning, the chemical composition as well as the physical properties of original material changes through the modification of surface properties of charcoal. Surface modification could be more responsible toward the outside elements for surface adsorption, it becomes easy to adsorb more toxic elements through surface adsorption. In this study, four kinds of commercially available charcoal were studied against the chemical and thermal stability along with the heavy metals and organic hazardous substances. Thermo gravimetric analysis (TGA) and differential scanning calorimetry, from room temperature to $400^{\circ}C$, were performed to study the weight loss and the changes in the behavior of those substances. According to TGA analysis, about 10% of weight loss was happened before $200^{\circ}C$. It was found that related weight loss of this temperature region may responsible to the gas phase organic matter. Natural charcoal, K1 and C1 show 15% of loss during the reaction heated to $400^{\circ}C$, while the artificial charcoal K2, C2 show the weight loss of about 20% was found. This is consistent with the main organic matter and VOC analysis results shown. Chemical composition based on the x-ray diffraction analysis was carried out. X-ray diffraction analysis reveals the existence of chemical additive in the forms of $Ba(NO_3)_2$, $BaCO_3$, and $NaNO_3$.

Preparation of Natural Wall Paint by Using Sericite Clay (견운모를 이용한 벽마감용 천연페인트 제조)

  • Kim, Munui;Lalhmunsiama, Lalhmunsiama;Lee, Seung-Mok;Jin, Kang-Jung
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.501-505
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    • 2017
  • Due to the rapid urbanization and increased population, there is an increase in airtight nature of buildings which causes serious indoor air pollution. Among several indoor air pollutants, volatile organic compounds (VOCs) emitted from paint are of major concern. Therefore, there is an urge for the development of environmental friendly paint products. In this wok, a natural wall paint (NWP) was prepared by utilizing a natural clay material "sericite" as a main component. A small chamber test was carried out to identify the toxic substances release from NWP and the results were compared with two eco-friendly commercial paints. The total VOCs were detected in trace level inside the test chamber and their concentrations were below the recommended indoor air quality standards. Toluene was not detected for NWP, whereas formaldehyde was observed in trace level. The toxicity index results were compared with two commercial paints and found that NWP exhibited less harmful gas emission. Based on certification rating of building materials, NWP can be classified as the first grade of building materials. Due to the above advantages, the use of sericite as a major component in NWP will be a useful technique to maintain the indoor air quality.

The Ammonia Removal Capacity of a Few Kinds of Filter Media in a Water Reuse quaculture System (순환 여과식 양식 시설에 이용될 수종의 여과 재료의 효능에 관한 연구)

  • KIM In-Bae;KIM Pyong-Kih;CHEE Young-Ok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.6
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    • pp.561-567
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    • 1987
  • The purpose of this study was to find out the removal capacity of harmful ammonia by different filter media in the submerged biological filters in a given space of chamber. Four materials, pile cloth, corrugated skylight roofing plate, embossed plastic plate, and gravel, were used as the experimental filter media. Each filter medium was placed in two aquariums, each aquarium measuring $90cm\times60cm\times60cm\;(depth)$. Under the normal operating condition, the average of mean ammonia removal rates during the first and second functioning periods by each filter material which occupied tile space in the filter chamber (aquarium) was as follows: 1. Pile cloth: $8.381\;g{\cdot}m^{-3}.\;day^{-1}$ 2. Corrugated skylight roofing plate: $7.834\;g{\cdot}m^{-3}.\;day^{-1}$ 3. Embossed plastic plate: $7.797\;g{\cdot}m^{-3}.\;day^{-1}$ 4. Gravel: $7.051\;g{\cdot}m^{-3}.\;day^{-1}$ Thus, there were no significant differences between the media, but at the time of practical application of these materials, some other factors such as investment cost, easiness for the removal of excess detritus accumulated in tile interstices of filter media, etc. should be fallen into consideration. When large units are required, in particular, removal of excess detritus from tile gravel bed is extremely difficult, and in case of pile cloth filters the installation work is much complicated and a problem in supporting the structure when drained also exists. In these respects, corrugated skylight roofing plate and embossed plastic plate seem to be more optimal, but again in practice the local situation for the availability and the price of the materials should be rechecked and the fitness of tile materials in the particular filter chambers under use or under consideration for construction must be taken into account.

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Physiochemical Characteristics of Calcium Supplement Manufactured using Starfish (불가사리를 이용하여 제조한 칼슘보충제의 이화학적 특성)

  • Park, Hee-Yeon;Lee, Jung Im;Nam, Ki-Ho;Jang, Mi-Soon
    • Food Science and Preservation
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    • v.19 no.5
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    • pp.727-734
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    • 2012
  • For developing calcium supplement from the harmful marine organism starfish, the physiochemical property of the powdered starfish skeletal plate and the hydrolysis condition of the starfish digestive enzyme were studied. The optimal hydrolysis condition of the starfish digestive enzymes was at $55^{\circ}C$ for 12 h. The bulk densities of the powdered starfish skeletal plates of Asterias amurensis and Asterina pectinifera were $1.1{\pm}0.0$ and $1.2{\pm}0.0g/cm^3$, respectively. As for the median size, the values were 10.738 and $11.799{\mu}m$, respectively. According to the added concentration of sodium polyacrylate, the dispersibility rate of the powdered starfish skeletal plate was shown to be 6h at 0.0%, 3 days at 0.1%, 20 days at 0.2%, and until 30 days at 0.4%. The elementary composition of the powdered starfish skeletal plates from A. amurensis and A. pectinifera mainly consisted of calcium, and it formed 98.95 and 98.52% of the powdered starfish skeletal plates, respectively. The results of the X-ray diffraction (XRD) analysis showed that they were present in the form of $CaCO_3$. Based on these results, it is suggested that starfish skeletal plate can be utilized as a functional material for a calcium supplement.

Studies of Physicochemical Properties of Baby Powder Developed from Rice-flour (쌀 분말을 이용한 유아용 파우더의 이화학적 특성 연구)

  • Han, Sang-Ik;Jang, Ki Chang;Seo, Woo Duck;Oh, Seong-Hwan;Ra, Ji-Eun;Song, Yu-Cheon;Lee, Jong-Hee;Kim, Byung-Joo;Nam, Min-Hee;Lee, Jin-Tae
    • Journal of Life Science
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    • v.23 no.7
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    • pp.879-885
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    • 2013
  • Baby powder is an astringent powder used to prevent diaper rash. It also has other cosmetic uses. In general, it is composed of talc powder (talcum powder). Talc powder is harmful if inhaled because it can cause significant lung damage. With the aim of developing a new rice-based baby powder, three kinds of rice varieties were selected and pulverized. To determine the cost-effectiveness of the different states of rice powder, several milling processes were tried, and the powder characteristics of the resulting rice powder, such as particle size, biological activities, digitalized color value, and moisture content before and after coating treatment with essential oil and silicon oil, were examined. "Goami" showed good flour characteristics with respect to lightness (92.0, $L^*$[D65] value) and particle size ($8.9{\mu}m$). SEM analysis showed that the rice powder particles coated in the essential oil and silicon oil showed a smoother and rounder appearance than those of the talc powder. In addition, the average particle size was decreased by the essential oil and silicon oil coating. The silicon oil coating solved the problem of moisture absorption in rice flour. Rice flour properly coated with essential oil and silicon oil shows great potential as a new material source of powder.

Study on the Correlation between Air Emission Gas and Alternative Fuels Used in Cement Sintering Process (시멘트 소성공정에 사용된 대체연료와 대기배출가스간 상관관계 연구)

  • Choi, Jaewon;Baek, Ju-Ik;Kwon, Sang-Jin;Won, Pil-Sung;Kang, Bong-Hee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.286-293
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    • 2020
  • In this study, we tried to verify the correlation of the amount of combustible industrial by-products, household waste used as fuels on cement sintering process and the amount of NOx, and CO, harmful components in the exhaust gas. The analysis uses coal as natural fuel, soft plastics (plastics with properties that tend to be scattered by wind, such as vinyls), hard plastics (plastics with properties that are not scattered by wind, such as PETs, wate rubbers), and reclaimed oils as alternative fuels. Utilizing the response surface analysis (RSM) technique using the process data of 2019, such as the fuel input and combustion temperature of a domestic A cement manufacturer's sintering facilities as independent variables, and the NOx, and CO emissions to the stack as dependent variables. Correlation was analyzed. As a result, it was confirmed that the impact on the emission material differs for each waste. In particular, it was analyzed that the hard plastics increase the CO emission but have an excellent effect of reducing NOx.

TREATMENT OF DENTAL CARIES BY ER:YAG LASER IN CHILDREN (소아 환자에서 Er:YAG Laser를 이용한 우식 병소의 처치)

  • Jang, Eun-Young;Lee, Sang-Ho;Lee, Chang-Seop
    • Journal of the korean academy of Pediatric Dentistry
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    • v.27 no.4
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    • pp.558-563
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    • 2000
  • The lasers have been used in dentistry for more than 30 years and the application of lasers for drilling dental hard tissue has been investigated since the early developement of lasers. Recently, the Er:YAG laser was invented for hard tissue ablation. The Er:YAG laser, having a wavelength of 2.94um, is highly absorbed in both water and hydroxiapatite, leading to a very effective material for hard tissue removal by bursting off the solid tissue component that is, enamel and dentin are removed by the Er :YAG laser by water vaporization and microexplosion, without any melting of inorganic tissues. Therefore, the Er:YAG laser produced round craters with well defined margins and the surrounding tissues had no cracks and no charring. When used for cavity preparation, pulpal damage should not occur if hear buildup is minimized by careful selection of exposure parameters and by use of a water spray. The present study demonstrated that the Er:YAG laser cut the tooth substance adequately for composite resin restoration, without having undesirable side effects such as harmful effects on the pulp, discoloration or cracking etc. Also, the child patients were well cooperative during laser treatment mainly because of little noise, lesser vibration and minimal pain compared to conventional means of cavity preparation.

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Development of Air Cleaning Roll-Filter for Improving IAQ in Subway (도시철도 객실 공기질 개선을 위한 롤필터 개발연구)

  • Kwon, Soon-Bark;Park, Duck-Shin;Cho, Young-Min;Kim, Jong-Bum;NanGoong, Seok;Han, Tae-Woo;Cho, Kwan-Hyun;Kim, Tae-Sung
    • Journal of the Korean Society for Railway
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    • v.14 no.4
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    • pp.313-319
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    • 2011
  • In a modern society, various type of transportation modes are utilized, among them the subway system is the one of the main transportation mode which more than 7.21 million people ride a day in Seoul. Due to the increased interests on the indoor air quality (IAQ) of underground facilities, public concerns on IAQ of subway system are increasing also. Platform screen door (PSD) recently installed at the whole stations of Seoul subway and tunnel washing-out appeared to be effective in reducing particulate matters in the platform and tunnel. However there has not been any attempt to improve IAQ of subway cabin inside. Most technologies for removing airborne particulate matters are known to be difficult to adopt on the subway cabin due to the problem of maintenance cost. Therefore, the object of this study is a practical development of cabin air cleaning system which can reduce the concentration of airborne particles and harmful gases at the same time. In this paper, we focused on the development of particle removing system utilizing a roll-filter for increasing operating time of air filter. The prototype of system was designed and manufactured based on the numerical prediction results. For rollfilter device, 5 candidate filter materials were tested in point of particle collection efficiency and pressure drop. It was found that the electrically charged filter material showed the highest performance among them.

Selective Catalytic Oxidation of Hydrogen Sulfide Using $V_{2}O_{5}-TiO_2$ Catalyst Prepared by Nonhydrolytic Sol-Gel Method (비가수분해 솔-젤법으로 제조한 $V_{2}O_{5}-TiO_2$ 촉매를 이용한 황화수소의 선택 산화반응)

  • Kim, Sang-Yun;Cho, Dal-Rae;Park, Dae-Won
    • Clean Technology
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    • v.14 no.3
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    • pp.204-210
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    • 2008
  • A series of $V_{2}O_{5}-TiO_2$ xerogel catalysts were prepared by nonhydrolytic sol-gel method and analysed by various characterization techniques. These catalysts showed much higher surface areas and total pore volumes than conventional V$V_{2}O_{5}-TiO_2$ xerogel and impregnated $V_{2}O_{5}/TiO_2$ catalysts. It was found that the textural property of $V_{2}O_{5}-TiO_2$ material varies with the method and conditions of synthesis. Surface vanadates and $TiO_2$ anatase phase are the crucial factors to obtain high catalytic activities. The selective oxidation of hydrogen sulfide in the presence of excess water and ammonia was studied over these catalysts. Xerogel catalysts prepared by non-hydrolytic sol-gel method showed very high conversion of $H_{2}S$ without harmful emission of $SO_2$. The highest catalytic activity shown by these $V_{2}O_{5}-TiO_2$ catalysts may be due to their high surface area and good dispersion of vanadia species in the titania matrix.

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A Neural Network-Based Tracking Method for the Estimation of Hazardous Gas Release Rate Using Sensor Network Data (센서네트워크 데이터를 이용하여 독성물질 누출속도를 예측하기 위한 신경망 기반의 역추적방법 연구)

  • So, Won;Shin, Dong-Il;Lee, Chang-Jun;Han, Chong-Hun;Yoon, En-Sup
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.38-41
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    • 2008
  • In this research, we propose a new method for tracking the release rate using the concentration data obtained from the sensor. We used a sensor network that has already been set surrounding the area where hazardous gas releases can occur. From the real-time sensor data, we detected and analyzed releases of harmful materials and their concentrations. Based on the results, the release rate is estimated using the neural network. This model consists of 14 input variables (sensor data, material properties, process information, meteorological conditions) and one output (release rate). The dispersion model then performs the simulation of the expected dispersion consequence by combining the sensor data, GIS data and the diagnostic result of the source term. The result of this study will improve the safety-concerns of residents living next to storage facilities containing hazardous materials by providing the enhanced emergency response plan and monitoring system for toxic gas releases.

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