• Elastomers and Composites
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• v.52 no.3
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• pp.194-200
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• 2017

After the grafting of methacrylic acid (MA) to ethylene propylene diene monomer (EPDM), a new peak at $1704cm^{-1}$ corresponding to the carboxylic acid group was observed in the infrared (IR) spectrum. This characteristic MA molecule peak grew larger as the MA contents were increased. After casting films were prepared from pure EPDM and MA-grafted EPDM, differential scanning calorimeter (DSC) measurements were made the pure EPDM exhibited a melting point of approximately $45^{\circ}C$ while that of the MA-grafted EPDM was $135{\sim}140^{\circ}C$. As the graft ratio of MA increased, the absorbed heat capacity increased at temperatures near $135{\sim}140^{\circ}C$, indicating that an increased amount of MA reacted. Furthermore, owing to the addition of crystalline MA, it is expected that strength of the elastomer will improve as the graft ratio increases, as a result of the increased number of hard segments.

• Elastomers and Composites
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• v.45 no.3
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• pp.156-164
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• 2010

Thermoplastic elastomers (TPEs) exhibit both elastomeric behaviors at used temperature range and melt processibility. Polyamide based thermoplastic elastomers (TPAEs) are segmented block copolymers with hard blocks consisting of polyamide segments, while the soft blocks usually consist of flexible segments having a low glass transition temperature. The TPAE is one of the engineering TPEs possessing high thermal stability, excellent mechanical performances, chemical resistance and excellent processibility. And they showed wide range of physical and functional properties depending upon the structure of each segment and their relative contents and the hybridization with various inorganic particles. In this review, synthesis, properties, and possible applications of TPAEs are summarized.

• Journal of Information Processing Systems
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• v.18 no.5
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• pp.688-700
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• 2022

A composite bionic soft gripper integrated with electromagnets and magneto-active elastomers is designed by combining the structure of the human hand and the snake's behavior of enhancing friction by actively adjusting the scales. A silicon-based polymer containing magnetized hard magnetic particles is proposed as a soft finger, and it can be reversibly bent by adjusting the magnetic field. Experiments show that the length, width, and height of rectangular soft fingers and the volume ratio of neodymium-iron-boron have different effects on bending angle. The flexible fingers with 20 vol% are the most efficient, which can bend to 90° when the magnetic field is 22 mT. The flexible gripper with four fingers can pick up 10.51 g of objects at the magnetic field of 105 mT. In addition, this composite bionic soft gripper has excellent magnetron performance, and it can change surface like snakes and operate like human hands. This research may help develop soft devices for magnetic field control and try to provide new solutions for soft grasping.

• Elastomers and Composites
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• v.48 no.1
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• pp.67-75
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• 2013

E-TPE (Engineering Thermoplastic Polyether Ester) was Ester Elastomer with functional groups as recycling and fast processability. In addition, if the car's lightweight enough to highlight eco-friendly materials that help to improve fuel economy has become. Have all the attributes of the rubber and engineering plastics E-TPE the available temperature area is spacious, heat resistance and oil resistance is excellent but getting attention as a new material in the field of auto parts in the field of electrical and electronic domestic depends entirely on imports by the lack of core technology and has been research and development is urgently needed. In this study, the hard segments, polyester (TPEE) as the base soft elastomers of the segments Ethylen-prophylene-Copolymer and CSM (Choloro sulphonated polyethylene Rubber), VAMAC (Ethylene Acrylic Rubber), NBR (Acrylonitrin Butadiene Rubber), 1, 3-Phenylene-bisoxazoline is dealing with Dynamic Vulcanized by content and added rubber properties, thermal variation observed. As a result, the properties of the dynamic vulcanization with NBR compared to other rubber heat resistance and oil resistance is on the increase.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 1995.04a
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• pp.515-528
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• 1995

Slips and falls are the major causes of the pedestrian injuries in the industry and the general community throughout the world. With the awareness of these problems, the friction coefficients of the interface between floorings and footwear have been measured for the evaluation of slip resistant properties. During this measurement process, the surface texture has been shown to be substantially effective to the friction mechanism between shoe heels and floor surfaces under various types of walking environment. Roughness, either of the floor surface or shoe heels, provides the necessary drainage spaces. This roughness can be designed into the shoe heel but this is inadequate in some cases, especially a wear. Therefore, it is essential that the proper roughness for the floor surface coverings should be provided. The phenomena that observed at the interface between a sliding elastomer and a rigid contaminated floor surface are very diverse and combined mechanisms. Besides, the real surface geometry is quite complicate and the characteristics of both mating surfaces are continuously changing in the process of running-in so that a finite number of surface parameters can not provide a proper description of the complex and peculiar shoe - floor contact sliding mechanism. It is hypothesised that the interface topography changes are mainly occurred in the shoe heel surfaces, because the general property of the shoe is soft in the face of hardness compared with the floor materials This point can be idealized as sliding of a soft shoe heel over an array of wedge-shaped hard asperities of floor surface. Therefore, it is considered that a modelling for shoe - floor contact sliding mechanism is mainly depended upon the surface topography of the floor counterforce. With the model development, several surface parameters were measured and tested to choose the best describing surface parameters. As the result, the asperity peak density (APD) of the floor surface was developed as one of the best describing parameters to explain the ambiguous shoe - floor interface friction mechanism. It is concluded that the floor surface should be continuously monitored with the suitable surface parameters and kept the proper level of roughness to maintain the footwear slip resistance. This result can be applied to the initial stage of design for the floor coverings.

• Polymer(Korea)
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• v.38 no.1
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• pp.9-15
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• 2014

Polyamide4 (PA4)-polyurethane (PU)-PA4 triblock copolymers were synthesized by isocynated (NCO)-terminated PU prepared from 4,4'-diphenyl methane diisocyante (MDI) and polytetramethylene glycol (PTMG) as an initiator and potassium pyrrolidonate (P-py) as a catalyst for anionic ring opening polymerization of 2-pyrrolidone. Subsequently copolymer was controlled to contain different or same molecular weight of PA4 hard block with same or different molecular weight of PU soft block in order to investigate the effects of those differences on various properties of triblock copolymers as a thermoplastic elastomer. As the results shown in typical properties of block copolymeric elastomers, the mechanical strength and melting point ($T_m$) of the copolymers increased with an increase in molecular weight of PA4 block while the elongation at break increased with an increase in that of PU block.