• Macromolecular Research
• /
• 제11권3호
• /
• pp.152-156
• /
• 2003

We investigated epitaxial relations of phase transitions between the lamellar (L), hexagonally perforated layers (HPL), and gyroid (G) morphologies in styrene-isoprene diblock copolymer (PSI) and polyisoprene (PI)/PSI blend using rheology and small angle X-ray scattering (SAXS) techniques. In HPLlongrightarrowG transitions, six spot patterns of G phase were observed in two-dimensitional SAXS pattern. On the other hand, in direct L-longrightarrowG transition without appearance of HPL phase, the polydomain patterns of G phase were observed. From present study, it was understood that direct LlongrightarrowG transition of blend may be suppressed by high-energy barrier of transition and mismatches in domain orientation between epitaxially related lattice planes.

• Bulletin of the Korean Chemical Society
• /
• 제22권9호
• /
• pp.948-952
• /
• 2001

Periodic mesoporous organosilicas with rope-based morphology from a reaction gel composition of 1 BTME : 0.57 ODTMABr : 2.36 NaOH : 353 H2O were synthesized. While long rope-shaped product dominated in case of static synthesis condition , gyroid type products instead of rope shaped product appeared and rope shaped product disappeared with agitation. PMO with such a long rope shaped morphology is firstly reported. Additionally, various rope-based morphologies depending on the degree of bending, twisting, folding and winding of rope such as spirals, discoids, toroids, and worm-like aggregates were observed. White powdered products were characterized by X-ray diffraction, N2 sorption measurement, SEM and TEM. From XRD pattern and TEM image, ODTMA-PMO with hexagonal symmetry was identified. The pore diameter and BET surface area of ODTMA-PMO are $32.9{\AA}$ and 799 m2g-1 , respectively. Hexagonally arrayed channels run with long axis of rope and rope-based shapes with various degree of curvature, which was elucidated by using TEM images.