• 제목/요약/키워드: group contribution method

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서울 및 근교에 거주하는 한국인의 연령별 식생활 비교 및 평가: (2) 식품 섭취 비교 (Comparative Analysis and Evaluation of Dietary Intakes of Koreans by Age Groups: (2) Food and Food Group Intakes)

  • 백희영;심재은;문현경;김영옥
    • Journal of Nutrition and Health
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    • 제34권5호
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    • pp.568-579
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    • 2001
  • This study was conducted to identify the characteristics of Korean diet in the view of food and food group intakes. The study subjects consisted of preschool children(PC), elementary school children(EC), high school students(HS), college students(CS), and adults over 30 years old living Seoul and the surrounding areas. The subjects over 30 years old were classified to 30-49 years, 50-69 years, and over 70 years. A dietary survey was conducted using 24-hour recall method and data were collected from 2392 subjects. Rice was a major contributor to many nutrients intake because of the amount of consumption. Vegetable oil made great contribution to fat intakes and eggs, squid, and anchovy supplied much cholesterol compared to other foods in all the age groups. Milk was major contributor of fat and cholesterol as well as calcium in younger age group, and seasoning gave much contribution to iron intakes. Mean dietary variety score(DVS) was 32 for EC group and 17 for subjects over 70 years, and tended to decrease along the increasing age. EC group consumed most variable number of foods of all groups but they consumed many junk foods, therefore the MAR value was low despite their high DVS value. Mean dietary diversity score(DDS) of each age group from PC group to subjects over 70 years was 4.34, 4.28, 3.79, 3.89, 3.76, 3.56, and 3.25, respectively. Food group, which was consumed below the minimum amount, was mainly fruits in all the age groups, and many subjects in HS group and over 30 years consumed dairy products below the minimum amount. From these results, age specific nutritional problems were found. PC group and subjects over 50 years seemed to need more diverse food intake than now, EC group did nutrient dense food, and HS group and subjects over 30 years did dairy products. Also, subjects took various nutrients from rice and seasoning contributed to some nutrients intakes. (Korean J Nutrition 34(5) : 568∼579, 2001)

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점토와 모래가 포함된 다층지반의 경험토압 산정방법에 관한 연구 (The Calculation Method of Apparent Earth Pressure in Multi-Layered Ground with Clay and Sand)

  • 김병일;홍강한;김진해;한상재
    • 한국지반신소재학회논문집
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    • 제20권1호
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    • pp.21-34
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    • 2021
  • 단일지반에서의 경험토압을 다층지반에 적용할 때 각 지층이 토압에 기여하는 효과를 고려할 수 없는 문제 등을 해결하고자 국내외에서 지반굴착시 측정된 토압을 조사하고 분석하였다. 다층지반의 토압은 단일지반의 경험토압과 상이하고, 대표 토질이 아닌 지층의 토압 기여 효과를 고려할 수 없음을 확인하였다. 본 연구에서는 기존의 단일지반에 대한 경험토압 산정방법을 다층지반까지 확장하여 단일지반과 다층지반 모두 적용 가능한 방법을 제안하고 검증하였다. 제안방법은 굴착심도 0.1Z/H 이하에서 실측값에 더 근접한 토압을 예측하는 등 기존 단일지반의 토압보다 예측 신뢰도가 우수한 것으로 평가되었다. 제안방법 중 주동상태에서의 파괴면적비를 고려하는 방법이 지반공학적 타당성을 갖추고도 실측토압과 가장 유사한 결과를 도출하였다. 또한, 제안방법의 적용성을 확인하고자 실제 설계사례에 대해 제안방법과 기존 방법의 설계 결과를 비교 분석하여 제시하였다.

UNIFAC 그룹 기여 모델에 의한 n-Octnae+n-Decane 계와 n-Octane+n-Dodecane 계의 인화점 계산 (Flash Point Calculation for n-Octane+n-Decane and n-Octane+n-Dodecane by UNIFAC Group Contribution Model)

  • 하동명;이성진
    • 한국안전학회지
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    • 제30권4호
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    • pp.86-91
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    • 2015
  • The flash point is used to categorize inflammable liquids according to their relative flammability. Such a categorization is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary liquid mixtures(n-octane+n-decane and n-octane+n-dodecane) has been measured for the entire concentration range using Seta-flash closed cup tester based on the ASTM D3278 method. The closed cup flash point temperature was estimated using the UNIFAC(Universal Functional Activity Coefficient) group contribution model. The experimentally derived flash point was also compared with the predicted flash point from the UNIFAC model. The UNIFAC model is able to estimate the flash point fairly well for n-octane+n-decane mixture and n-octane+n-dodecane mixture.

Theoretical Studies on Phenyl Group Rearrangement of Protonated Ketones

  • 김창곤;이진각;박형연;이익춘
    • Bulletin of the Korean Chemical Society
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    • 제18권6호
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    • pp.657-662
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    • 1997
  • Gas-phase phenyl group migration within the protonated ketones has been studied MO theoretically using the AM1 method. The initial state structure shows relatively strong resonance delocalization of positive charge into the nonmigrating (Y) ring, while the ring migration (Z-ring) is nearly complete in the transition state. These results are reflected in the large $p^+_Z$ (<0) and $p^+_$Y (>0) values and in the predominant contribution of resonance (r) over inductive (field, f) effect, r/f ranging from 1.3 ($p^+_r$) to 1.5 ($p^+_z$). The cross-interaction constant $p_{YZ}$ is vanishingly small ($p_{YZ}$=0.03) which is in contrast to the larger magnitudes for benzilic ($p_{YZ}$=-0.48) and azibenzil ($p_{YZ}$=-0.53) rearrangement processes. The relationship found between the extent of resonance contribution in the initial state and the magnitude of $p_{YZ}$ provides strong support for the proportionality between the magnitude of $p_{YZ}$ and the change in the intensity of interaction, ${\Delta}I^{\cdot}_{YZ}$, in the activation process.

黃砂의 量的推定을 위한 基礎硏究 (Basic Research on the Quantitative Estimation of Yellow Sand)

  • 김동술
    • 한국대기환경학회지
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    • 제6권1호
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    • pp.11-21
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    • 1990
  • To quantitatively estimate the effect of yellow sand(loess) fromt he Northern China, various soil sources having similar chemical compositions to yellow sands should be separated and identified. After that, mass contribution for yellow sand can be calculated. The study showed that it was impossible to solve this problem by the traditional bulk analyses. However, particle-by-particle analysis by a CCSEM (computer controlled scanning electron microscope) gave enormous potentials to solve it. To perform this study, seven soil source data analyzed by CCSEM were obtained from Texas, U.S.A. Initially, each soil date was classified into two groups, coarse and fine particle groups since the particle number distribution showed a minimum occurring at 5.2$\mu$m of aerodynamic diameter. Particles in each group were then classified into one of the 283 homogeneous particle classes by the universal classification rule which had been built by an expert system in the early study. Further, mass fractions and their uncertainties for each class in each source were calculated by the Jackknife method, and then source profile matrix for the 7 soil sources was created. To use the profile matrix in the study of source contribution, it is necessary to test the degree of collinearity among sources. The profiles were tested by the singular value decomposition method. As a result, each soil source characterized by artificially created variables was totally independent each other and is ready to use in source contribution studies as a receptor model.

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A Study on Spin-Lattice Relaxation of $^{19}$F Spins in Benzotrifluoride: Contributions from Dipole-Dipole Interaction and Spin-Rotation Interaction

  • Hyun Namgoong;Jo Woong Lee
    • Bulletin of the Korean Chemical Society
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    • 제14권1호
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    • pp.91-95
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    • 1993
  • In this work we have studied the spin-lattice relaxation of $^{19}$F spins in benzotrifluoride in our quest for a reliable method of discriminating the contribution due to dipolar relaxation mechanism from that due to spin-rotational mechanism for nuclear spins located on methyl or substituted methyl group in organic molecules. Over the temperature range of 248-268 K the decay of normalized longitudinal magnetization was found to be well described by a two parameter equation of the form R(t) = exp(-st){$\frac{5}{6}$exp(-s$_1$)+$\frac{1}{6}$} which was derived under the assumption that interactions in the A3 spin system are modulated randomly and predominantly by internal rotational motions of -CF_3$ top, and it was shown that the separation of contribution due to dipolar interactions from that due to spin-rotation interaction could be successfully achieved by least-square fitting of observed data to this equation. The results indicate that the spin-rotational contribution is overwhelmingly larger than that of dipolar origin over the given temperature range and becomes more deminating at higher temperature.

Impact of Lignin Determination Method on Oxygen Delignification Chemistry

  • Shin Soo-Jeong;Lai Yuan-Zong
    • 펄프종이기술
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    • 제37권5호통권113호
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    • pp.50-55
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    • 2005
  • In previous report, we investigated the impact of hexeneuronic acid and some residual extractiveson lignin determination. These non-lignin components severely interfered lignin content determination which also affect on the oxygen delignification comparison between aspen and pine unbleached kraft pulps. Very different pattern was observed whether based on uncorrected conventional kappa number or based on corrected kappa number in oxygen delignification comparison. Lower kappa number aspen pulps showed poor response to oxygen delignification when kappa number was used as lignin determination method but better response with using the acid lignin method. Phenolic hydroxyl group in kraft pulps were also compared based on uncorrected or corrected kappa numberfor lignin content. Based on uncorrected kappa number, lower kappa number oxygen-delignified pulps had lower phenolic hydroxyl group. However, lower kappa number oxygen-delignified pulps showed much higher phenolic hydroxyl group based on the corrected lignin content. For accurate comparison for residual lignin properties from different pulps, lignin determination should be corrected from non-lignin components contribution to lignin.

Multigroup cross-sections generated using Monte-Carlo method with flux-moment homogenization technique for fast reactor analysis

  • Yiwei Wu;Qufei Song;Kuaiyuan Feng;Jean-Francois Vidal;Hanyang Gu;Hui Guo
    • Nuclear Engineering and Technology
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    • 제55권7호
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    • pp.2474-2482
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    • 2023
  • The development of fast reactors with complex designs and operation status requires more accurate and effective simulation. The Monte-Carlo method can generate multi-group cross-sections in arbitrary geometry without approximation on resonances treatment and leads to good results in combination with diffusion codes. However, in previous studies, the coupling of Monte-Carlo generated multi-group cross-sections (MC-MGXS) and transport solvers has shown relatively large biases in fast reactor problems. In this paper, the main contribution to the biases is proved to be the neglect of the angle-dependence of the total cross-sections. The flux-moment homogenization technique (MHT) is proposed to take into account this dependence. In this method, the angular dependence is attributed to the transfer cross-sections, keeping an independent form for the total sections. For the MET-1000 benchmark, the multi-group transport simulation results with MC-MGXS generated with MHT are improved by 700 pcm and an additional 120 pcm with higher order scattering. The factors that cause the residual bias are discussed. The core power distribution bias is also significantly reduced when MHT is used. It proves that the MCMGXS with MHT can be applicable with transport solvers in fast reactor analysis.

Novel Synthetic Reactions Using 1-Fluoro-2, 4, 6-trinitrobenzene. An Efficient Direct Esterification Method

  • Kim Sunggak;Ahn Kyo Han;Yang Sungbong
    • Bulletin of the Korean Chemical Society
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    • 제3권2호
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    • pp.70-76
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    • 1982
  • Synthetic utility of 1-fluoro-2,4,6-trinitrobenzene (FTNB) as a condensing agent was investigated. The use of FTNB and DMAP was found to be very effective for direct esterification of carboxylic acids with alcohols or thiols. However, this system was not very effective for macrolactonization. Reaction of 2,4,6-trinitrophenyl esters with several nucleophiles was investigated briefly. Plausible reaction mechanisms of esterification are presented. It seems that the reaction proceeds via the intermediacy of 2,4,6-trinitrophenyl esters by initial formation of 2',4',6'-trinitrophenyl-4-dimethylaminopyridinium salt from which the trinitrophenyl group is transferred to the carboxylic acid.

할로잉 운동 시 시각적 피드백 방법에 따른 복근 두께에 미치는 영향 비교 (Comparison of the Abdominal Muscle Thickness during Abdominal Hollowing Exercise According to the Visual Feedback Method)

  • 김하림;손호희
    • 대한물리의학회지
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    • 제16권3호
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    • pp.107-113
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    • 2021
  • PURPOSE: Selective strengthening of the transverse abdominis muscle (TrA) during abdominal hollowing makes an important contribution to the stability and control of the spine. This study examined the effects of abdominal hollowing exercise (AHE) according to the visual feedback method on the external oblique, internal oblique, and transverse abdominis muscles. METHODS: Twenty healthy subjects were assigned randomly to an AHE with visual feedback from real-time ultrasound image (group A, n = 10), AHE with visual feedback with pressure biofeedback unit (group B, n = 10). Both groups underwent 20 min of AHE with visual feedback once daily, five days/week for two weeks. The changes in the muscle thickness of the TrA, internal oblique abdominal muscle (IO), and external oblique abdominal muscle (EO) were measured by ultrasonography. RESULTS: The thickness of TrA was changed significantly in both groups (p < .05). However, the lowest minimal detectable changes were achieved in Group A. The thickness of the IO and EO muscles in group A was changed significantly, but there were no significant changes in group B. CONCLUSION: Both visual feedback methods were effective for strengthening the TrA muscles selectively. Nevertheless, AHE with visual feedback using real-time ultrasound images may be more useful in trA muscle contraction.