• Title/Summary/Keyword: ground-level ozone

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Further evidence of changing stability of atmosphere and climate on spallation product measurement (핵파쇄잔류물질의 지표면도달량 측정결과를 이용한 기후와 대기구조의 불안정변화에 미치는 영향)

  • Hartwig, Sylvius
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.05a
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    • pp.17-20
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    • 2003
  • In a recent paper (Hartwig, ms.) I have shown that it is possible to understand and discuss the changing Austausch (i.e., exchange of air parcels between different atmospheric layers) between the stratosphere and troposphere by means of long-term measurement on series of spallation products. It is well known (Friend 1961; Muet et al. 1966, Hartwig et al. 1969) that there is a seasonal pattern in the 7Be concentration of ground-level air with a maximum during May-June. This maximum is caused by enhanced exchange processes between the atmospheric compartments of the stratosphere and troposphere during this interval. Generally, those exchange processes are a consequence of stability and dynamics of the atmospheric compartments, which themselves result from, among other factors, the distribution of the heat sources in those compartments, namely the ground and the ozone layer. Because of the growing importance of anthropogenic infrared-active gases in the atmosphere, it is to be expected that the relative importance of those original, naturally occurring heat sources will be of lesser significance, thus altering the Austausch. And indeed, it has been shown (Hartwig, ms.) by considering the ratio of the annual maximum and minimum during a 28-yr period of 7Be ground-level concentration at Braunschweig, Germany (10$^{\circ}$33'E, 52$^{\circ}$17'N) (Kolb 1992; Wershofen 1993), that there is a steady decline in that ratio, thus indicating alteration of atmospheric Austausch within the last three decades.(omitted)

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Investigations on aerosols transport over micro- and macro-scale settings of West Africa

  • Emetere, Moses Eterigho
    • Environmental Engineering Research
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    • v.22 no.1
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    • pp.75-86
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    • 2017
  • The aerosol content dynamics in a virtual system were investigated. The outcome was extended to monitor the mean concentration diffusion of aerosols in a predefined macro and micro scale. The data set used were wind data set from the automatic weather station; satellite data set from Total Ozone Mapping Spectrometer aerosol index and multi-angle imaging spectroradiometer; ground data set from Aerosol robotic network. The maximum speed of the macro scale (West Africa) was less than 4.4 m/s. This low speed enables the pollutants to acquire maximum range of about 15 km. The heterogeneous nature of aerosols layer in the West African atmosphere creates strange transport pattern caused by multiple refractivity. It is believed that the multiple refractive concepts inhibit aerosol optical depth data retrieval. It was also discovered that the build-up of the purported strange transport pattern with time has enormous potential to influence higher degrees of climatic change in the long term. Even when the African Easterly Jet drives the aerosols layer at about 10 m/s, the interacting layers of aerosols are compelled to mitigate its speed to about 4.2 m/s (macro scale level) and boost its speed to 30 m/s on the micro scale level. Mean concentration diffusion of aerosols was higher in the micro scale than the macro scale level. The minimum aerosol content dynamics for non-decaying, logarithmic decay and exponential decay particulates dispersion is given as 4, 1.4 and 0 respectively.

Assessment of Air Quality Impact Associated with Improving Atmospheric Emission Inventories of Mobile and Biogenic Sources

  • Shin, Tae-joo
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.1
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    • pp.11-23
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    • 2000
  • Photochemical air quality models are essential tools in predicting future air quality and assessing air pollution control strategies. To evaluate air quality using a photochemical air quality model, emission inventories are important inputs to these models. Since most emission inventories are provided at a county-level, these emission inventories need to be geographically allocated to the computational grid cells of the model prior to running the model. The conventional method for the spatial allocation of these emissions uses "spatial surrogate indicators", such as population for mobile source emissions and county area for biogenic source emissions. In order to examine the applicability of such approximations, more detailed spatial surrogate indicators were developed using Geographic Information System(GIS) tools to improve the spatial allocation of mobile and boigenic source emissions, The proposed spatial surrogate indicators appear to be more appropriate than conventional spatial surrogate indicators in allocating mobile and biogenic source emissions. However, they did not provide a substantial improvement in predicting ground-level ozone(O3) concentrations. As for the carbon monoxide(CO) concentration predictions, certain differences between the conventional and new spatial allocation methods were found, yet a detailed model performance evaluation was prevented due to a lack of sufficient observed data. The use of the developed spatial surrogate indicators led to higher O3 and CO concentration estimates in the biogenic source emission allocation than in the mobile source emission allocation.llocation.

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Ambient air pollution and allergic diseases in children

  • Kim, Byoung-Ju;Hong, Soo-Jong
    • Clinical and Experimental Pediatrics
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    • v.55 no.6
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    • pp.185-192
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    • 2012
  • The prevalence of allergic diseases has increased worldwide, a phenomenon that can be largely attributed to environmental effects. Among environmental factors, air pollution due to traffic is thought to be a major threat to childhood health. Residing near busy roadways is associated with increased asthma hospitalization, decreased lung function, and increased prevalence and severity of wheezing and allergic rhinitis. Recently, prospective cohort studies using more accurate measurements of individual exposure to air pollution have been conducted and have provided definitive evidence of the impact of air pollution on allergic diseases. Particulate matter and ground-level ozone are the most frequent air pollutants that cause harmful effects, and the mechanisms underlying these effects may be related to oxidative stress. The reactive oxidative species produced in response to air pollutants can overwhelm the redox system and damage the cell wall, lipids, proteins, and DNA, leading to airway inflammation and hyper-reactivity. Pollutants may also cause harmful effects via epigenetic mechanisms, which control the expression of genes without changing the DNA sequence itself. These mechanisms are likely to be a target for the prevention of allergies. Further studies are necessary to identify children at risk and understand how these mechanisms regulate gene-environment interactions. This review provides an update of the current understanding on the impact of air pollution on allergic diseases in children and facilitates the integration of issues regarding air pollution and allergies into pediatric practices, with the goal of improving pediatric health.

Comparative Assessment of Linear Regression and Machine Learning for Analyzing the Spatial Distribution of Ground-level NO2 Concentrations: A Case Study for Seoul, Korea (서울 지역 지상 NO2 농도 공간 분포 분석을 위한 회귀 모델 및 기계학습 기법 비교)

  • Kang, Eunjin;Yoo, Cheolhee;Shin, Yeji;Cho, Dongjin;Im, Jungho
    • Korean Journal of Remote Sensing
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    • v.37 no.6_1
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    • pp.1739-1756
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    • 2021
  • Atmospheric nitrogen dioxide (NO2) is mainly caused by anthropogenic emissions. It contributes to the formation of secondary pollutants and ozone through chemical reactions, and adversely affects human health. Although ground stations to monitor NO2 concentrations in real time are operated in Korea, they have a limitation that it is difficult to analyze the spatial distribution of NO2 concentrations, especially over the areas with no stations. Therefore, this study conducted a comparative experiment of spatial interpolation of NO2 concentrations based on two linear-regression methods(i.e., multi linear regression (MLR), and regression kriging (RK)), and two machine learning approaches (i.e., random forest (RF), and support vector regression (SVR)) for the year of 2020. Four approaches were compared using leave-one-out-cross validation (LOOCV). The daily LOOCV results showed that MLR, RK, and SVR produced the average daily index of agreement (IOA) of 0.57, which was higher than that of RF (0.50). The average daily normalized root mean square error of RK was 0.9483%, which was slightly lower than those of the other models. MLR, RK and SVR showed similar seasonal distribution patterns, and the dynamic range of the resultant NO2 concentrations from these three models was similar while that from RF was relatively small. The multivariate linear regression approaches are expected to be a promising method for spatial interpolation of ground-level NO2 concentrations and other parameters in urban areas.

Evaluation of Sensitivity and Retrieval Possibility of Land Surface Temperature in the Mid-infrared Wavelength through Radiative Transfer Simulation (복사전달모의를 통한 중적외 파장역의 민감도 분석 및 지표면온도 산출 가능성 평가)

  • Choi, Youn-Young;Suh, Myoung-Seok;Cha, DongHwan;Seo, DooChun
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1423-1444
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    • 2022
  • In this study, the sensitivity of the mid-infrared radiance to atmospheric and surface factors was analyzed using the radiative transfer model, MODerate resolution atmospheric TRANsmission (MODTRAN6)'s simulation data. The possibility of retrieving the land surface temperature (LST) using only the mid-infrared bands at night was evaluated. Based on the sensitivity results, the LST retrieval algorithm that reflects various factors for night was developed, and the level of the LST retrieval algorithm was evaluated using reference LST and observed LST. Sensitivity experiments were conducted on the atmospheric profiles, carbon dioxide, ozone, diurnal variation of LST, land surface emissivity (LSE), and satellite viewing zenith angle (VZA), which mainly affect satellite remote sensing. To evaluate the possibility of using split-window method, the mid-infrared wavelength was divided into two bands based on the transmissivity. Regardless of the band, the top of atmosphere (TOA) temperature is most affected by atmospheric profile, and is affected in order of LSE, diurnal variation of LST, and satellite VZA. In all experiments, band 1, which corresponds to the atmospheric window, has lower sensitivity, whereas band 2, which includes ozone and water vapor absorption, has higher sensitivity. The evaluation results for the LST retrieval algorithm using prescribed LST showed that the correlation coefficient (CC), the bias and the root mean squared error (RMSE) is 0.999, 0.023K and 0.437K, respectively. Also, the validation with 26 in-situ observation data in 2021 showed that the CC, bias and RMSE is 0.993, 1.875K and 2.079K, respectively. The results of this study suggest that the LST can be retrieved using different characteristics of the two bands of mid-infrared to the atmospheric and surface conditions at night. Therefore, it is necessary to retrieve the LST using satellite data equipped with sensors in the mid-infrared bands.

Analysis of Volatile Organic Compounds Produced from Incineration of Papers at 600°C (600°C에서 제지류 소각시 발생하는 휘발성 유기화합물 농도분석 연구)

  • 이병규;조정범
    • Journal of Environmental Science International
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    • v.11 no.10
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    • pp.1109-1116
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    • 2002
  • This study analyzed concentrations of volatile organic compounds (VOCs) produced from incineration of papers at $600^{\circ}C$. The papers used in this study included A4 papers (new, printed with ink-jet, printed with carbon), newspapers (printed with bean oil, printed with a general newspaper ink), packaging box, document envelope, single-use paper cup, and cosmetic tissue. Papers were heated from room temperature upto $600^{\circ}C$ providing air inside of the electric furnace and then they were oxidized for 80 minutes at $600^{\circ}C$ maintaining the same air supply. VOCs emitted from the incineration process were sampled using an air sampling pump and bags for 160 minutes and then the components and concentrations of the VOCs were analyzed by a CC-MS. The most prominent chemical structure of the Vous identified from incineration of the papers was furans and then furans were followed by aromatics and aliphatic alkenes. About 40% of the identified VOCs contained double bonds, which have relatively a high ozone (ground level) formation potential, within their molecular structure. Also, some cancer suspecting compounds like benzene, dichlorormethane and chloroform were identified.