• Resources Recycling
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• v.23 no.2
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• pp.81-89
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• 2014

Approximately 8.5 million tons of fly ash and 740,000 tons of briquette ash were produced in 2010. Inefficient recycling of coal ash has been a heavy economic and environmental burden and economical coal ash utilization technologies are required to turn coal ash into valuable resources. In this study the patents and literature were analyzed to understand the present situation of coal ash recycling technologies and to promote utilization of coal ash for producing a non-sintering green cement, geopolymer. The survey was based on the open patents of USA, European Union, Japan and Korea, and the papers in SCI - indexed journals published between 1979 and 2013. Technical key words were used for data collection and noise filtering. Trends of recycling technologies in utilization of coal ash for producing geopolymers were discussed in terms of time periods, countries, companies and various forms of technologies.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.3
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• pp.152-160
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• 2013

The purpose of this study is to enhance the mechanical strength of specimens containing fly ash from fluidized bed type boiler, which the recycling rate will be eventually increased. Specimens containing fly ash in a certain portion were made and aged for 3, 14, and 28 days. Specimens were carbonated under the supercritical condition at $40^{\circ}C$. The carbonation process under the supercritical condition was performed to enhance the mechanical property of specimens by filling the voids and cracks existing inside cement specimen with $CaCO_3$ reactants. The additional aging effect after the supercritical carbonation process on mechanical strength of specimens was also investigated by comparing the compressive strength with and without 7 day extra aging. Under the supercritical condition and additional 7 day aging specimens were very effective for enhancement of mechanical strength and compressive strength increased by 44 %.

• The Journal of Engineering Geology
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• v.20 no.1
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• pp.1-12
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• 2010

The objective of this study was to examine the hydrogeochemical and microbiological characteristics for stable maintenance of coastal LPG storage cavern. Cavern seepage water and groundwater in the vicinity of the LPG storage cavern were sampled and analyzed (February, May, August and October 2007). Groundwater samples of propane cavern showed high pHs of 8.1~12.4 due to dissolution of cement grouting materials that had been applied during the well and cavern construction. The EC values showed distinctive seasonal variation. The negative ORP indicated reduced condition. The seepage and surrounding groundwater are classified as Na-Cl type, which represents seawater effects. All of aerobic bacteria, anaerobic bacteria, slime forming bacteria and sulfate reducing bacteria were less than 500 CFU/mL, which indicated that there was no abrupt increase of bacteria in the cavern. Therefore there exist no hydrochemical symptoms to indicate unstable conditions of the cavern operation. However, regular and continuous monitoring is essentially required.

• Journal of the Korea Concrete Institute
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• v.13 no.3
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• pp.213-220
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• 2001

Incorporation of wastes glass aggregate in mortar may cause crack and this may result in the strength reduction due to alkali-silica reaction(ASR) and expansion. The purposes of this study were to investigate the properties of alkali-silica expansion and strength loss through a series of experiments which had a main experimental variables such as waste glass aggregate contents, glass colors, fiber types, and fiber contents. The steel fibers and polypropylene fibers were used for constraining the ASR expansion and mortar cracking. From the result, green waste glass was more suitable than brown one because of low expansion. And in this accelerated ASTM C 1260 test of waste glass, pessimum content can not be found. Also, when used the fibers with waste glass, there is an effect on reduction of expansion and strength loss due to ASR between the alkali in the cement paste and the silica in the waste glass. Specially, adding 1.5 vol.% of steel fiber to 20% of waste glass, the expansion ratio was reduced by 40% and flexural strength was developed by up to 110% comparing with only waste glass(80$\^{C}$ H$_2$O curing).

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.440-448
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• 2002

Waste glass has been increased with the development of industry. The utilization of waste glass for concrete can cause the concrete to be cracked and to be weakened due to an expansion by alkali-silica reaction(ASR). In this study, ASR expansion and properties of strength were analyzed in terms of waste glass color(amber, emerald-green), industrial by-products(ground granulated blast-furnace slag, fly ash), and the content of industrial by-products for reducing ASR expansion caused by the waste glass. The possibility of using glass ground as pozzolanic properties was also analyzed. From the result of this study, the pessimum size of waste glass was 2.5∼1.2 mm regardless of waste glass color. And the smaller than 2.5∼1.2 mm waste glass is, the more decreasing expansion of ASR is. Also, the combination of waste glass with industrial by-products have an effect on reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass, and the glass ground of less than 0.075 mm is applicable as a pozzolanic material.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1009-1012
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• 2008

The fiber dispersion performance in fiber-reinforced cementitious composites is a crucial factor with respect to achieving desired mechanical performance. However, evaluation of the fiber dispersion performance in the composite PVA-ECC(Polyvinyl alcohol-Engineered Cementitious Composite) is extremely challenging because of the low contrast of PVA fibers with the cement-based matrix. In the present work, an enhanced fiber detection technique is developed and demonstrated. Using a fluorescence technique on the PVA-ECC, PVA fibers are observed as green dots in the cross-section of the composite. After capturing the fluorescence image with a Charged Couple Device(CCD) camera through a microscope. The fibers are more accurately detected by employing a series of process based on a categorization, watershed segmentation, and morphological reconstruction.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.577-583
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• 2022

In this study, the characteristics of self-healing mortars produced using an inorganic self-healing material consisting of ground granulated blast furnace slag, expansion agent, and anhydrite, were investigated. For three types of self-healing mortars with different amounts of the inorganic healing material, compressive strength was measured and the self-healing performance was evaluated through the constant water head permeability test. The healing rate and equivalent crack width according to crack-induced aging were used as indicies of healing performance evaluation. Considering the development of compressive strength of the self-healing mortars, the change in the healing rate with healing periods, and the economic feasibility, the optimal amount of inorganic self-healing materials was suggested as 20 % of the mass of cement.

• Resources Recycling
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• v.31 no.3
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• pp.16-26
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• 2022

Limestone is the largest mineral resource in South Korea and is used in various industries, particularly as a primary raw material in the cement and iron industries. However, research on the utilization of limestone in fields such as agriculture, powder, and green chemistry is severely lacking. In this review, studies concerning the crop antibacterial industry using unslaked or slaked lime produced from limestone were analyzed. Reports regarding lime bordeaux mixture were also considered. By compiling research results, processing technologies for improving the antibacterial efficiency of lime bordeaux mixture are discussed. In addition, plans for the revitalization of research on crop antibacterial agents through the limestone processing industry were summarized.

• Journal of the Korea Institute of Building Construction
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• v.23 no.3
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• pp.261-272
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• 2023

This research concentrates on the potential explosion hazards that could arise from unforeseen accidents in the rapidly proliferating hydrogen refueling stations and Energy Storage System(ESS) facilities. It underscores the pivotal role of structural protection technology in alleviating such risks. The research contributes primary data for the formulation of structure protection design by assessing the impact resistance across various reinforcement techniques used in cement composites. The experimental results elucidate that reinforced concrete, serving as the quintessential structural material, exhibits a 20% advancement in impact resistance in comparison to its non-reinforced counterpart. In situations typified by rapid loads, such as those seen with high-velocity impacts, the reinforcement of the matrix with fibers is demonstrably more beneficial than local reinforcement. These insights accentuate the importance of judiciously choosing the reinforcement method to augment impact resistance in structural design.

• Advances in nano research
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• v.15 no.5
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• pp.467-484
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• 2023

Despite the significant features of fiber-reinforced cementitious composites (FRCCs), including better mechanical, fractural, and durability performance, their high content of cement has restricted their use in the construction industry. Although ground granulated blast furnace slag (GGBFS) is considered the main supplementary cementitious material, its slow pozzolanic reaction stands against its application. The addition of nano-sized mineral modifiers, including nano-silica (NS), is an alternative to address the drawbacks of using GGBFS. The main object of this empirical and numerical research is to examine the effect of NS on the strain-hardening behavior of cementitious composites; ten mixes were designed, and five levels of NS were considered. This study proposes a new method, using a four-point bending test to assess the use of nano-silica (NS) on the flexural behavior, first cracking strength, fracture energy, and micromechanical parameters including interfacial friction bond strength and maximum bridging stress. Digital image correlation (DIC) was used for monitoring the initiation and propagation of the cracks. In addition, to attain a deep comprehension of fiber/matrix interaction, scanning electron microscope (SEM) analysis was used. It was discovered that using nano-silica (NS) in cementitious materials results in an enhancement in the matrix toughness, which prevents multiple cracking and, therefore, strain-hardening. In addition, adding NS enhanced the interfacial transition zone between matrix and fiber, leading to a higher interfacial friction bond strength, which helps multiple cracking in the composite due to the hydrophobic nature of polypropylene (PP) fibers. The findings of this research provide insight into finding the optimum percent of NS in which both ductility and high tensile strength of the composites would be satisfied. As a concluding remark, a new criterion is proposed, showing that the optimum value of nano-silica is 2%. The findings and proposed method of this study can facilitate the design and utilization of green cementitious composites in structures.