• Journal of Korea Foundry Society
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• v.9 no.4
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• pp.336-344
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• 1989

The matrix structure and the morphology of CV graphite are affected by the addition of many kinds of elements, which are contained in the CV graphite cast iron, additives, fading time and cooling rate. The effects of cooling rate on the matrix structure, the shape of CV graphite, mechanical properties and propagation of ultrasonic wave in eutectic CV graphite cast iron were studied. When the diameters of the samples are 50mm, 35mm and 20mm 1. CV graphite number showed average 13.8% increase and CV graphite length showed 12.3% decrease with decreasing diameter of the samples. 2. The amount of graphite and ferrite showed average 10.6, 4.3% decrease and the amount of pearlite showed average 23.4% increase. 3. Hardness and tensile strength showed average 3.2%, 9.5% increase and impact strength showed average 1.3% decrease. 4. Ultrasonic wave velocity showed average 1.1% increase.

• Journal of the Korean Chemical Society
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• v.7 no.1
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• pp.51-57
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• 1963

It is well known that the graphite flakes become spherulite, when a suitable amount of nodulizing element, such as cerium or magnesium, is added to the cast iron. The change of graphite from flake to nodular shape improves not only the tensile strength but the ductility as well. However, the mechanism of spheroidization of graphite in cast iron has not yet been clearly understood, and various theories proposed by a number of investigators were such that it may be due to the special nucleation effect, prevention of flake formation by the adsorption of magnesium vapour on the graphite surface or file surface free energy difference between plain graphite and magnesium-adsorbed graphite. Regardless of the speculations of spheroidizing mechanism of the graphite in the cast iron, the final phenomenon comes to the conclusion that it may be due to the lack of wettability between graphite and iron matrix. In order to collaborate this fact through an experimental method, the authors have constructed a vacuum arc furnace for the wettability measurement as its first step. Our study and experiments were then directed to the comparison of the wettability between iron and graphite on the two cases (namely, the one where magnesium was preliminarily coated on the graphite surface and the other not coated), by means of contact angle measurements. The result was such that a significant difference of the contact angles has been shown between the above two cases. indicating the spheroidization of graphite which might have resulted from the lack of wettability between magnesium-adsorbed graphite and iron matrix.

• Analytical Science and Technology
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• v.6 no.2
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• pp.149-156
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• 1993

The formation of the graphite spherulites has been studied experimentally in the Ni-C liquid under high pressure and temperature. In the diamond-stable region the graphite spherulites were formed and grew stably. They were not the polycrystalline particles but the single crystals of the fullerene-type, respectively, grown spirally with much imperfection. And they were proved to be in a mixture state of carbon atoms with $sp^2$- and $sp^3$-bonding by an Auger electron spectroscope and a high resolution transmission electron microscope. As the pressure decreased from the diamond-stable region to the graphite-stable region, the shape of the graphite particles changed gradually from the sphere to the flaky shape. The formation of the graphite spherulites was attributed to the stable existence of the carbon atoms with $sp^3$ bonding in the diamond-stable region. The formation of the large fullerene-type graphite spherulites with much imperfection is well agreed with Kroto's prediction for growth of the giant fullerene.

• Journal of Korea Foundry Society
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• v.14 no.6
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• pp.520-529
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• 1994

This study describes the influence of the trace amount of sulphur on the nucleation behavior of graphite crystals in high purity Fe-C-Si alloys prepared by levitation melting method. Detailed microstructural analyses of high purity(HP) and sulphur added(HP＋S) samples showed that the nucleation of graphite crystals was prevented by sulphur. With decreasing the sulphur content, the shape of graphite crystals tended to spherulitic, and below 2ppm S, that of graphite crystals was only nodular. The critical cooling rate for the nucleation of griphite crystals was calculated as $1.5{\times}10^3k/s$. It is obvious from this work that residual C-C clusters act as an effective nucleation site for graphite crystals and one of the important role of nodularizing elements is to act as scavenger which removes harmful impurities from the solution.

• Journal of the Korean Ceramic Society
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• v.43 no.7 s.290
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• pp.439-444
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• 2006

Artificial graphite generally manufactured by carbonization sintering of shape-body of kneaded mixture using granular cokes as filler and pitch as binder, going through pitch impregnation process if necessary and finally applying graphitization heat treatment. Graphite materials are used for core internal structural components of the High-Temperature Gas-cooled Reactors (HTGR) because of their excellent heat resistibility and resistance of crack progress. The HTGR has a core consisting of an array of stacked graphite fuel blocks are machined from IG-110, a high-strength, fine-grained isotropic graphite. In this study, crack stabilization and micro-structures were measured by bend strength and fracture toughness of isotropic graphite grade IG-110. It is important to the reactor designer as they may govern the life of the graphite components and hence the life of the reactor. It was resulted crack propagation, bend strength, compressive strength and micro-structures of IG-110 graphite by scanning electron microscope and universal test machine.

• Journal of Korea Foundry Society
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• v.2 no.3
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• pp.2-15
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• 1982

In this study, the influenced of graphite shape on the boriding of cast iron and boride structure was investigated. Gray cast iron, ferritic and pearlitic ductile cast iron were borided at 750,850,900 and $950^{\circ}C$ for 1,3 and 5 hours by powder pack method with the mixture of $B_4C_9\;Na_2B_4O_7$, $KBF_4$ and Shc. The boride layer was consisted of FeB(little), $Fe_2B$ (main) and graphite. Some possibility of the existence of unknown Fe-B-C compound in the boride layer was suggested. And precipitates in the diffusion zone was $Fe_3(B,C)$. The concentration of Si and precipitation of $Fe_3(B,C)$ in the ${\alpha}$ layer raised the hardness of this Zone. The depth and hardness of boride layer increased with the increase of treating temperature and tim. But high temperature (over $950^{\circ}C)$ caused pore at graphite position and long treating time (5hrs) sometimes caused formation of graphite layer beneath the boride layer. So, for the practical application of borided cast iron, treating in short time and at low temperature was recommended. And for ductile cast iron, ferritizing or pearlitizing heat treatment was seemmed to be possible at the same time with boriding. The graphite in the boride layer was deeply concerned with the qualitx and characteristics of the boride layer. And it greatly influenced on the shape of the boride phase, structure of the boride layer. Generally speaking, the existance of graphite restrained the growth of the boride phase. But the boundary between the gsaphite and the matrix acted as the shortcut of boron diffusion. So, for gray cast iron, the graphite layed length-wise led the formation of boride layer.

• Journal of the Korean institute of surface engineering
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• v.44 no.5
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• pp.226-231
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• 2011

Graphene was coated on STS 316L by electro spray coating method to improve its properties of corrosion resistance and contact resistance. Exfoliated graphite (graphene) was made of the graphite by chemical treatment. Graphene is distributed using dispersing agent, and STS 316L was coated with diffuse graphene solution by electro spray coating method. The structure of the exfoliated graphite was analyzed using XRD and the coating layer of surface was analyzed by using SEM. Analysis showed that multi-layered graphite structure was destroyed and it was transformed into fine layers graphene structure. And the result of SEM analysis on the surface and the cross section, graphene layer was uniformly formed with 3~5 ${\mu}m$ thickness on the surface of substrate. Corrosion resistance test was applied in the corrosive solution which is similar to the PEM fuel cell stack inside. And interfacial contact resistance test was measured to simulate the internal operating conditions of PEM fuel cell stack. The results of measurements show that stainless steel coated with graphene was improved in corrosion resistance and surface contact resistance than stainless steel without graphene coating layer.

• Journal of Korea Foundry Society
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• v.9 no.1
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• pp.80-88
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• 1989

SGCI(Spheroidal Graphite Cast Iron), CVGCI(CV Graphite Cast Iron) and FGCI(Flake Graphite Cast Iron) having different contents of Mn($0.25%{\sim}0.85%$) and Ni($0.3%{\sim}1.2%$) were produced, respectively. The thermal expansion and thermal conductivity of the cast iron were investigated in the temperature range of $50^{\circ}C{\sim}300^{\circ}C$. As the graphite nodularity of the cast iron increases, thermal expansion coefficient increases, thermal conductivity and electrical conductivity to thermal conductivity ratio decrease. The thermal expansion coefficient of the cast iron increases with increasing Mn content and decreases with increasing Ni content. The thermal conductivity of the cast iron decreases with increasing Mn and Ni contents.

• Journal of Powder Materials
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• v.24 no.1
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• pp.17-23
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• 2017

In this study, a finite element analysis approach is proposed to predict the fluid-structure interaction behavior of active materials for lithium-ion batteries (LIBs), which are mainly composed of graphite powder. The porous matrix of graphite powder saturated with fluid electrolyte is considered a representative volume element (RVE) model. Three different RVE models are proposed to consider the uncertainty of the powder shape and the porosity. P-wave modulus from RVE solutions are analyzed based on the microstructure and the interaction between the fluid and the graphite powder matrix. From the results, it is found that the large surface area of the active material results in low mechanical properties of LIB, which leads to poor structural durability when subjected to dynamic loads. The results obtained in this study provide useful information for predicting the mechanical safety of a battery pack.

• Transactions of Materials Processing
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• v.22 no.2
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• pp.108-113
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• 2013

This paper demonstrates the lubricant performance in T-shape hot forging of Mg alloys. This processes induces complex plastic material flow of the initial billet such as simultaneous compression and extrusion deformations. Five lubricants with different amounts of graphite are applied to the T-shape forging at temperatures of 300 and $350^{\circ}C$. As the amount of graphite in the lubricant increases, the extruded depth gradually increases, which improves hot forgeability for Mg alloys. However, the lubricant performance decreases as forging temperature increases from 300 to $350^{\circ}C$. As the punch stroke increases, forgeability is considerably influenced by the lubricant. Thus, the selection of lubricants in hot forging of Mg alloys is critical when plastic deformation is severe.