• Title/Summary/Keyword: grain composition

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The Effect of Sulfurization Temperature on CuIn(Se,S)2 Solar Cells Synthesized by Electrodeposition

  • Kim, Dong-Uk;Yun, Sang-Hwa;Yu, Bong-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.97-97
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    • 2014
  • The properties of thin film solar cells based on electrodeposited $CuIn(Se,S)_2$ were investigated. The proposed solar cell fabrication method involves a single-step $CuInSe_2$ thin film electrodeposition followed by sulfurization in a tube furnace to form a $CuIn(Se,S)_2$ quaternary phase. A sulfurization temperature of $450-550^{\circ}C$ significantly affected the performance of the $CuIn(Se,S)_2$ thin film solar cell in addition to its composition, grain size and bandgap. Sulfur(S) substituted for selenium(Se) at increasing rates with higher sulfurization temperature, which resulted in an increase in overall band gap of the $CuIn(Se,S)_2$ thin film. The highest conversion efficiency of 3.12% under airmass(AM) 1.5 illumination was obtained from the $500^{\circ}C$-sulfurized solar cell. The highest External Quantum Efficiency(EQE) was also observed at the sulfurization temperature of $500^{\circ}C$.

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Mechanical Properties and Mold Filling Capability of Al-Si-Mg Casting Alloy Fabricated by Lost Foam Casting Process (소실모형주조공정으로 제조한 Al-Si-Mg계 주조합금의 기계적 성질 및 주형 충전성)

  • Kim, Jeong-Min;Ha, Tae-Hyung;Choe, Kyeong-Hwan
    • Journal of Korea Foundry Society
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    • v.36 no.5
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    • pp.153-158
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    • 2016
  • The lost foam casting process was used to fabricate Al-Si-Mg cast specimens, and the effects of the chemical composition and process variables on the tensile properties and the mold filling ability were investigated. Some porosity formation was observed in thick sections of the casting and better tensile properties were obtained for thin sections, presumably because of their lower porosity and the higher cooling rate. Tensile properties were not clearly enhanced by grain refining treatment with Ti; however, the elongation was significantly improved by Sr modification of the Al-Si-Mg alloy. The mold filling distance was generally proportional to the pouring temperature of the melt, and the distance was also increased by the addition of Ti.

Electrical Characteristics of the Piezoelectric Transformer as a Function of Piezoelectric Properties and Load Variations (압전특성 및 부하변화에 따른 압전트랜스포머의 전기적 특성)

  • 민석규;윤광희;류주현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.4
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    • pp.289-296
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    • 2001
  • The piezoelectric transformers of 2.0x10x48 ㎣ size were fabricated with PSN-PMN-PZT(T10 and PNW-PMN-PZT(T2) composition ceramics. Effects of micro structural and piezoelectric properties on the electrical characteristics of the piezoelectric transformers were investigated. Under the fixed output power of 6 W, temperature rise of T1 transformer at the optimum load was smaller than T2 one because of fine grain size effect. Voltage step-up ratio of T1 transformer showed higher value than T2 one T1 transformer showed an excellent properties with voltage step-up ratio of 12.41, efficiency of 95.23% and temperature rise of 7.2$^{\circ}C$ at 200㏀ load resistance. And also, T2 transformer showed an excellent properties with voltage step up ratio of 9.81, efficiency of 95.51% and temperature rise of 9$^{\circ}C$ at 150㏀ load resistance.

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Dielectric Properties of $Al_{2}O_{3}-Doped$ BSCT Thick Films ($Al_{2}O_{3}$가 첨가된 BSCT 후막의 유전특성)

  • Lee, Sung-Gap;Kim, Chang-Il;Kim, Jeong-Phil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.338-341
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    • 2002
  • $(Ba_{1-x}Sr_{0.4}Ca_x)TiO_{3}$ (x=0.10, 0.15, 0.20) powders were prepared by the sol-gel method and BSCT thick films were fabricated by the screen-printing method. Their structural and dielectric properties were investigated with variation of composition ratio and $Al_{2}O_{3}$ doping contents. As results of the X-ray diffraction and microstructure analysis, the grain size of BSCT thick films was decreased with increasing $Al_{2}O_{3}$ amount. The thickness of BSCT thick films by 4-coating/drying is about $110{\sim}120{\mu}m$. The tunability increased with decreasing Ca content, and the BSCT(50/40/10) specimen doped with 1.0wt% $Al_{2}O_{3}$ showed the highest value of 12.94% at 5kV /cm.

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The effect of $Nb_{2}O_{5}$ Addition on Microstructure and Piezoelectric characteristics of PNW-PMN-PZT Ceramics ($Nb_{2}O_{5}$첨가가 PNW-PMN-PZT세라믹스의 미세구조 및 압전특성에 미치는 영향)

  • Kim, Chul-Hee;Oh, Dong-On;Hong, Jae-Il;Ryu, Ju-Hyun;Ryu, Sung-Lim;Park, Chang-Yub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.280-283
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    • 2002
  • In this study, the effects of $Nb_{2}O_{5}$ addition on microstructure and piezoelectric characteristics of PNW-PMN-PZT ceramics were investigated. As $Nb_{2}O_{5}$ addition amount is increased, grain size is gradully decreased. At 0.3wt%$Nb_{2}O_{5}$ addition composition ceramics, maximum density, tetragonality and piezoelectric characteristics were obtained.

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Fabrication of $Si_3N_4-SiC$ Nanocomposites by Hot Pressing (Hot Pressing에 의한 $Si_3N_4-SiC$ 나노복합체의 제조)

  • 김성현;김인술;박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.1021-1029
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    • 1994
  • SiC ultrafine particles of 1, 10, 20 and 30 vol% were dispersed in $\alpha$-Si3N4 matrix and hot-pressed under the condition of 30 MPa at 1800 and 190$0^{\circ}C$ respectively. Physical, mechanical properties and microstructures of sintered Si3N4-SiC nanocomposites were investigated. Flexural strength and density of Si3N4-10 vol% SiC nanocomposites hot-pressed at 190$0^{\circ}C$ represented the 1002 MPa and 97.9%T.D respectively, and it was confirmed as a remarkable improvement of 67% compared to Si3N4 monolith. Fracture toughness was shown as 7.2 MPa.m1/2 when the same composition was hot pressed at 180$0^{\circ}C$. This effect was supposed to be due to the improvement of microstructure by the adequate suppression of the excessive growth of Si3N4 grain with SiC nano-particles.

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Expansion Behavior of Iron-copper Compact Made from (Fe-Cu) Prealloyed Powder

  • Kim, Youn-Che;Suk, Myung-Jin
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.812-813
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    • 2006
  • Dimensional change of compact made from (Fe-Cu) prealloyed powder and copper powder compared to that of compact made from iron-copper elemental powder. The compact made from the prealloyed powder with a copper content of 7.18mass% which is nearly equal to its solution limit and copper powder showed only the large contraction in spite of penetration of liquid copper into grain boundary of the prealloyed powder. But the compact made from iron-copper elemental powder showed the large expansion in spite of same chemical composition with former case.

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[ $Ni_3Al-Fe-Cr$ ] Alloy Processed by Combined Mechanical Alloying - Reactive Synthesis

  • Orban, Radu L.;Lucaci, Mariana
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1316-1317
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    • 2006
  • The paper investigates the possibility to avoid extrinsic embrittlement of $Ni_3Al$, also increasing the high temperature strength, by alloying with both Fe - of a high strengthening effect and Cr - able to remove a part of diffused oxygen along the grain boundaries. As Cr homogenization in $Ni_3Al$ is difficult because of its low diffusion coefficient, for its improving a mechanical alloying (MA) step before the compound synthesis by Self-propagating High-temperature Synthesis (SHS) was adopted. The obtained better homogenization resulted in higher mechanical resistance and deformability than of the unalloyed $Ni_3A/Ni_3Al$ alloys of the same composition obtained without MA step.

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Microstructure and Magnetic Properties of $Nd_2Fe_{14}B/{\alpha}-Fe$ Nanocomposite Prepared by HDDR Combined with Mechanical Milling

  • Hu, Lianxi;Wang, Erde;Guo, Bin;Shi, Gang
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1286-1287
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    • 2006
  • [ $Nd_2Fe_{14}B/{\alpha}-Fe$ ] nanocomposite powders with a nominal composition of $Nd_{12}Fe_{82}B_6$ were prepared by HDDR combined with mechanical milling. The microstructure was studied by Mossbauer spectrometry and TEM. The magnetic properties were investigated by VSM using bonded magnet samples. The results showed that the annealing temperature had significant influence on both the recombination kinetics and the grain size of the $Nd_2Fe_{14}B$ and ${\alpha}-Fe$ phases, and the bonded magnets presented the best magnetic properties when the nanocomposite powders were prepared by annealing at $760^{\circ}C$ for 30 min.

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Transient-Liquid-Phase Bonding of Fe-Base MA956 ODS Alloy (Fe기 MA956 산화물분산강화합금의 천이액상확산접합에 관한 연구)

  • 강지훈
    • Journal of Powder Materials
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    • v.2 no.1
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    • pp.53-62
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    • 1995
  • TLP(Transient-Liquid-Phase) bonding of Fe-base MA956 ODS alloy was performed. As insert metal a commercially available Ni-base alloy(MBF50) and an MA956 alloy with additive elements of 7wt% Si and 1wt% B were used. To confirm the idea that a concurrent use of MA956 powder with Insert metals can enhance the homogenization of constituent elements and thereby reduce the thickness of joint interface, MA956 powder was also inserted In a form of sheet. SEM observation and EDS analysis revealed that Cr-rich phase was formed in the bonded interface in initial stage of isothermal solidification during the bonding process, irrespective of kind of insert metals. Measurement of hardeness in the region of bonded interface and EDS analysis showed that a complete homogenization of composition could not be obtained especially in case of MBF50. Joints using either BSi insert metals only or BSi insert together with MA956 powder interlayer showed, however, a remarkable improvement in a compositional homogenization, even though a rapid grain growth in the bonded interface could not be hindered.

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