• The Journal of Korean Academy of Prosthodontics
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• v.38 no.2
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• pp.226-241
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• 2000

Recently a new generation of crown and bridge veneering resins containing submicron glass fillers was introduced. These ultrasmall particle hybrid composite materials distinguish themselves, compared with conventional microfill crown and bridge resins, through improved mechanical properties. It is claimed that these composites are suitable for metal free crowns and even bridges using fiber reinforcement. The purpose of this study was to evaluate the effect of thermal cycling on the tensile strength of the following veneering composites: Artglass(Heraeus Kulzer Co., Wehrheim, Germany), Estonia(Kuraray Co.. Japan), Sculpture(Jeneric Pentron Co., Wallingford, U.S.A.), and Targis(Ivoclar Co., Schaan Liechenstein). According to manufacturer's instructions, rectangular tensile test specimens measuring $1.5{\times}2.0{\times}4.5mm$ were made using a teflon mold. Whole specimens were divided into two groups. One group was dried in a desiccator at $25^{\circ}C$ for 10 days, and another group was subjected to thermal cycling($10,000{\times}$) in water($5/55^{\circ}C$). All test specimens were placed in a universal testing machine and loaded until fracture with a crosshead speed of 0.5mm/min. Weibull analysis and Tukey's test were used to analyze the data. The fracture surfaces of specimens were observed in SEM and the aliphatic C=C absorbance peak of Estenia and Targis resin was analyzed using Fourier transform infrared(FTIR) spectroscopy. Within the limitations imposed in this study, the following conclusions can be drawn: 1. Both in drying condition and thermal cycling condition, the highest tensile strength was observed in Estenia testing group(p<0.05). 2. The strength data were at to single-mode Weibull distribution, and the Weibull modulus of all veneering composite resin specimens increased after thermal cycling treatment. 3. After thermal cycling test, the highest tensile strength was observed in the Estenia group, and the lowest value was observed in the Targis group. The tensile strength values showed the significant differences between each group(p<0.05) 4. The aliphatic C=C absorbance peak of Estonia and Targis resin was decreased after light curing, and there was no distinct change after thermal cycling.

• Journal of the Korean Society of Propulsion Engineers
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• v.9 no.4
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• pp.23-30
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• 2005

The Hygrothermal aging of the laminates of $Avimid^(R)$ K3B/IM7 in $80^{\circ}C$ water was studied as a function of immersion time prior to forming microcracks. The factors causing the $80^{\circ}C$ water to degradation of the laminates could be the degradation of the matrix toughness, the change in residual stresses or the interfacial damage between the fiber and the matrix. The times to saturation in $80^{\circ}C$ water for the laminates and for the neat resin were 100 hours and 500 hours. After 500 hours aging of the neat resin, the glass transition temperature was changed less than 1% by DSC test, and the weight gain was 1.55% increase with the diffusion coefficient $7\times10^{-6}m/s^2$ and the fracture toughness was decreased about 41%. After 100 hours fully saturated aging of the ${[+45/0/-45/90]}_s$ K3B/IM7 laminates in $80^{\circ}C$ water, the weight gain was 0.41% increase with the diffusion coefficient $1\times10^{-6}m/s^2$. In 100 hours, the loss of the fracture toughness of the laminates was 43.8% of the original toughness by the microcracking fracture toughness criterion. Therefore, the main factor to degrade the microcracking toughness of the laminates could be the degradation of the matrix fracture toughness.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.17 no.3
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• pp.319-332
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• 2004

Due to their high strength to weight ratios and excellent durability, fiber reinforced polymer(FRP) is widely used in construction industries. In this paper, a shape optimum design of FRP bridge decks haying pultruded cellular cross-section is presented. In the problem formulation, an objective function is selected to minimize the volumes. The cross-sectional dimensions and material properties of the deck of FRP bridges are used as the design variables. On the other hand, deflection limits in the design code, material failure criteria, buckling load, minimum height, and stress are selected as the design constraints to enhance the structural performance of FRP decks. In order to efficiently treat the optimization process, the cross-sectional shape of bridge decks is assumed to be a tube shape. The optimization process utilizes an improved Genetic Algorithms incorporating indexing technique. For the structural analysis using a three-dimensional finite element, a commercial package(ABAQUS) is used. Using a computer program coded for this study, an example problem is solved and the results are presented with sensitivity analysis. The bridge consists of a deck width of 12.14m and is supported by five 40m long steel girders spaced at 2.5m. The bridge is designed to carry a standard DB-24 truck loading according to the Standard Specifications for Highway Bridges in Korea. Based on the optimum design, viable cross-sectional dimensions for FRP decks, suitable for pultrusion process are proposed.

• Radiation Oncology Journal
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• v.32 no.4
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• pp.256-261
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• 2014

Purpose: We performed invasive thermometry to verify the elevation of local temperature in the liver during hyperthermia. Materials and Methods: Three 40-kg pigs were used for the experiments. Under general anesthesia with ultrasonography guidance, two glass fiber-optic sensors were placed in the liver, and one was placed in the peritoneal cavity in front of the liver. Another sensor was placed on the skin surface to assess superficial cooling. Six sessions of hyperthermia were delivered using the Celsius TCS electro-hyperthermia system. The energy delivered was increased from 240 kJ to 507 kJ during the 60-minute sessions. The inter-session cooling periods were at least 30 minutes. The temperature was recorded every 5 minutes by the four sensors during hyperthermia, and the increased temperatures recorded during the consecutive sessions were analyzed. Results: As the animals were anesthetized, the baseline temperature at the start of each session decreased by $1.3^{\circ}C$ to $2.8^{\circ}C$ (median, $2.1^{\circ}C$). The mean increases in temperature measured by the intrahepatic sensors were $2.42^{\circ}C$ (95% confidence interval [CI], 1.70-3.13) and $2.67^{\circ}C$ (95% CI, 2.05-3.28) during the fifth and sixth sessions, respectively. The corresponding values for the intraperitoneal sensor were $2.10^{\circ}C$ (95% CI, 0.71-3.49) and $2.87^{\circ}C$ (1.13-4.43), respectively. Conversely, the skin temperature was not increased but rather decreased according to application of the cooling system. Conclusion: We observed mean $2.67^{\circ}C$ and $2.87^{\circ}C$ increases in temperature at the liver and peritoneal cavity, respectively, during hyperthermia. In vivo real-time thermometry is useful for directly measuring internal temperature during hyperthermia.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.8
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• pp.913-920
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• 2011

We describe the evaluation of the fatigue life and strength of a lightweight railway bogie frame made of glass fiber/epoxy 4-harness satin-woven composites. To obtain the S-N curve for the evaluation of the fatigue characteristics of the composite bogie frame, we performed a tension-compression fatigue test for composite specimens with different stacking sequences of the warp direction, fill direction, and $0^{\circ}/90^^{\circ}$ direction. We used a stress ratio (R) of -1, a frequency of 5 Hz, and an endurance limit of $10^7$. The fatigue strength of the composite bogie frame was evaluated by a Goodman diagram according to JIS E 4207. The results show that the fatigue life and strength of the lightweight composite bogie satisfy the requirements of JIS E 4207. Given its weight, its performance was better than that of a conventional metal bogie frame based on an SM490A steel material.

• The Journal of Engineering Geology
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• v.23 no.3
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• pp.283-292
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• 2013

A calcareous rock slope failed during excavation of the slope for construction of a tunnel entrance. The slope is located at the construction site for widening highway in Yeongwol, Korea. Field surveys, laboratory tests, and numerical analyses were performed to determine the reason for the slope failure. The numerical analysis revealed that the safety factor of the slope before construction of the entrance was less than 1, and that this decreased after construction. After construction of the entrance, the sliding zone of the slope increased and slope stability decreased because the shear strain and plastic zone in the slope over the tunnel entrance showed an increase relative to the lower part of the slope. To enhance the stability of the slope for construction of the tunnel entrance, countermeasures such as rock bolts, rock anchors, and FRP (Fiber glass Reinforced Plastic) grouting were adopted in light of the field conditions. Serial field monitoring performed to confirm the reinforcing effects of the adopted countermeasures revealed a small amount of horizontal deformation of the slope soils, most of the elastic deformation that can regain its former value. In addition, the axial forces of the rock bolt and anchor were more strongly affected by slope excavation during construction of the tunnel entrance than by tunnel excavation or the rainy season, and the axial forces tended to converge after excavation of the tunnel. Therefore, we can confirm that the slope is currently safe.

• Journal of Korean Society of Steel Construction
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• v.16 no.5 s.72
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• pp.609-619
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• 2004

An investigation was conducted on the activities around Europe in order to solve the problem of the thermal bridging of steel studs, which had caused a significant disadvantage. This study included the following: diminishing the contact area between the studs and the sheathing, lengthening the heat transfer route, replacing the steel web with a less conductive material, and placing foam insulation in locations where the thermal shorts are most critical. Although energy efficiency is usually the focus of such foreign cases because their stud application is mostly limited to low-rise residential buildings, both structural and thermal performance are taken into consideration in this study because these target middle-story buildings. A hybrid stud composed of steel and polymer was also developed. This hybrid stud, which is 150 SL in size, is made of a galvanized steel sheet (SGC58) and a glass fiber reinforced polymer (GFRP) withepoxy bonding. A total of 32 specimens were manufactured. Its parameters comprise two types of connection detail,s: the thickness of steel (1.0mm and 1.2mm) and of the GFRP (4mm-4ply and 6mm-6ply), and the ratio of the length to the depth (L/D = 3, 6, 9, 12). Steel stud specimens with the same conditions were compared to the hybrid stud. The test revealed that in the case of the steel specimen with a thickness of 1.0mm, the maximum load of hybrid studs increased an average of 1.62 times comparedto that of the steel stud. In the case of the steel specimen with a thickness of 1.2mm, on the other hand, the average increase was 1.46times. All specimens showed full composite action until the collapse.

• Journal of the Korean Wood Science and Technology
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• v.36 no.4
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• pp.19-25
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• 2008

This study was carried out to investigate the bending strength properties of the unreinforced glulam beams and the GFRP laminated glulam beams according to the volume ratio of GFRP. The 7-layer glulam beams ($10cm(b){\times}14cm(h){\times}180cm(l)$) were manufactured, using Larch (Larix kaempferi Carr.) laminae ($2cm(h){\times}10cm(b){\times}360cm(l)$), which were dried to the moisture content of 8% and specific gravity of 0.54. GPRP of 0.1 and 0.3 cm was reinforced between the outmost layer of bottom and next layer. When the glulam beams were reinforced with GFRP at the volume ratio of 0.7% and 2.1%, respectively, the bending strength was increased by 12% and 28%, respectively, in the reinforced beams than in control glulam beams. Also, the GFRP reinforced layer of the glulam beams with GFRP laminations blocked the progression of rupture, and the unbroken part held about 90% of the bending strength. In the results of glue joints test, the block shear strength is higher than $7.1N/mm^2$, the standard of KS F3021, and in the result of delamination, the adhesive strength is good as the water soaking and boiling delamination was less than 5%.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.30 no.2
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• pp.134-152
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• 2020

Objectives: The objective of this study was to evaluate volatile organic compounds (VOCs) and toluene diisocyanates (TDIs) exposure among polyurethane waterproofing workers in the construction industry. Methods: Task-based personal air samplings were carried out at seven construction sites using organic vapor monitor for VOCs (n=88) and glass fiber filters coated with 1-(2-pyridyl)piperazine(1-2PP) for TDIs (n=81). The concentration of VOCs and TDIs were shown for four different work types(mixing paint, primer roller painting, urethane resin spread painting, painter assistant) at five different worksites (rooftop, ground parking lot, piloti, bathroom, and swimming pool). The two TDI sampling methods (filter vs impinger) were evaluated in parallel to compare the concentrations. Results: The geometric mean(GM) concentration of VOCs Exposure Index (EI) was highest for primer roller painting (1.4), followed in order by, urethane resin spread painting (0.85), mixing paint (0.53), and painter assistant (0.35) by work types. The GM of VOCs EI was highest for bathroom (1.4) followed in order by, swimming pool (0.85), piloti (0.89), ground parking lot (0.82) and rooftop (0.57) by worksites. The GM of 2,4-/2,6-TDI concentration was 0.052 ppb and 0.432 ppb each. There was no statistical difference in TDIs concentrations among worksites. The concentration of 2,6-TDI was ten times higher than that of 2,4-TDI. The concentration of 2,6-TDI by impinger method was 5.7 times higher than that by filter method. Conclusions: In this study, we found 38.6% of the VOCs samples exceeded the occupational exposure limits and 19.8% of the 2,6-TDI samples exceeded 1 ppb among polyurethane waterproofing workers. The most important determinants that increase the concentration of VOCs and TDIs was indoor environment and primer painting work.

• Membrane Journal
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• v.25 no.3
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• pp.223-230
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• 2015

We synthesized novel polyimides with high gas permeability and selectivity for application of gas separation membrane. 2,2-bis(3,4-carboxylphenyl) hexafluoropropane dianhydride (6FDA) and two kinds of amines with high permeability and solubility were used to prepare the novel polymide. 2,4,6-Trimethyl-1,3-phenylenediamine (DAM) was used to improve gas permeability and 4,4-Methylenedianiline was used to improve the gas selectivity respectively. The polyimide copolymers were synthesized by commercial chemical imidization method using Triethylamine and Acetic anhydride and their average molecular weights were over 100,000 g/mol. The glass temperature (Tg) and the thermal degradation temperature were characterized using differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). The synthesized copolymers showed high Tg over $300^{\circ}C$ and high thermal degradation temperature over $500^{\circ}C$. The gas permeation properties were measured by time-lag equipment. Although general polyimides showed very low gas permeability, synthesized polyimide copolymer showed high $O_2$ permeability of 10.1 barrer with high $O_2/N_2$ selectivity around 5.3. From this result, we confirm that these membranes have possibility to apply to gas separation membrane.