• 대한기계학회논문집B
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• 제20권11호
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• pp.3706-3713
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• 1996

A numerical study on natural convection induced by free surface heat flux and cold left and hot right walls in glass melting furnaces has been performed. A function of heat flux derived from the combustion environments of actual glass melting furnace is applied to thermal boundary condition at free surface. Fundamentally there exist two flow cells in cavity (left counterclockwise one and right clockwise one). The effects of heat flux and Rayleigh number are investigated through two-dimensional steady-state assumption. The convection strength of two flow cell located in left region continuously increases. In the mean time the strength of flow cell in right region increases and then decreases. Critical Rayleigh number in which two flow cells take place above and below show linear dependence on the free surface heat flux. To maintain the traditional flow pattern (left and right flow cells) in glass melting furnace, Rayleigh number is recommended to be below 10$^{5}$ .

• 한국연소학회지
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• 제9권1호
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• pp.1-10
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• 2004

The results of a series of experiments executed by using two pilot-scale oxy-fuel burners are presented. The oxy-fuel burners are designed for maximum capacity of 50,000kcal/hr, 200,000kcal/hr and installed in the test furnace. The effects of turn-down ratio, excess oxygen ratio, nozzle exit velocity, injection angle, and swirl vane angle on the combustion characteristic are investigated. Temperature distributions are measured using R-type and Molybdenum sheathed C-type thermocouple at various points of the flame. The results showed that maximum temperature and mean temperature increase with the increase of turn-down ratio and momentum. The maximum flame temperature was increased about 35% compared to the case of equivalent air operated condition. In addition, optimum burner type, excess oxygen ratio and nozzle characteristics are obtained for this oxy-fuel glass melting furnace.

• 공학논문집
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• 제2권1호
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• pp.125-131
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• 1997

유리용해로의 축열실은 폐연소가스로 열을저장하며, 유리용해로에 유입되는 흡입공기를 예열시키는 역할을 한다. 유리용해산업에서 연료소비를 줄이기 위하여 절연법, 단열벽돌, 공기누출등이 오래 연구되었다. 또한 새로운 형태의 단열벽돌과 Rider arch가 유리용해로의 수명연장을 위하여 연구되고 있다. 본 연구는 연구대상공장의 이전설치시 유리용해로의 축열실이 5.64m에서 7.89m로 높이가 높아졌고 이에 따른 축열실 하중증가에 의하여 Rider arch가 더 높은 응력을 받게 되었다. 이런 조건에서 Rider arch의 기계적 안정성을 본 연구에서 검토하였다. 계산식에 의하면 하중증가에 따른 Rider arch의 응력은 안정한 것으로 평가되었고 Rider arch가 견딜수 있는 최대 압축응력은 163kg/$cm^2$이고, 최대전단응력은 6.37kg/$cm^2$이다.

• 대한금속재료학회지
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• 제46권2호
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• pp.65-68
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• 2008

Generally CCM (cold crucible melting) is not suitable for melting glass. However, in this study we described the quantitative relationship between the basic property of glass and power balance, the power absorption in the melt, the losses in the coil and the cold crucible, for melting glass in CCM. The dependence of power balance on the applied frequency and the electric conductivity has been found. Above 300 kHz, the glass (B) contained alkali ion which has the low resistance $3.0{\Omega}{\cdot}cm$ at $900^{\circ}C$ and $1.36{\Omega}{\cdot}cm$ at $1,100^{\circ}C$ was melted easily and 60% of the overall power was absorbed in the melt and 30% and 10% of the overall power was lost in the cold crucible and coil respectively. Under the same condition, the glass (A) contained non-alkali ion was not melted easily and 50% of the overall power was absorbed in the melt and 40% and 10% of the overall power was lost in the cold crucible and coil respectively. In conclusion, the small absorbed power of the overall power in melt prevented a successful melting as for glass A, and the successful melting depends on the relative size of the absorbed power in melt irrespective of the melting volume. Hence, as typical for direct induction heating method(CCM), the successful melting strongly depended on the chosen working frequency based on electric conductivity of glass, power balance and the control of the critical power which was absorbed in melt.

• 한국재료학회지
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• 제29권11호
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• pp.727-733
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• 2019

In this study, the glass melting properties are evaluated to examine the possibility of using refused coal ore as replacement for ceramic materials. To fabricate the glass, refused coal ore with calcium carbonate and sodium carbonate in it (which are added as supplementary materials) is put into an alumina crucible, melted at $1,200{\sim}1,500^{\circ}C$ for 1 hr, and then annealed at $600^{\circ}C$ for 2 hrs. We fabricate a black colored glass. The properties of the glass are measured by XRD (X-ray diffractometry) and TG-DTA (thermogravimetry-differential thermal analysis). Glass samples manufactured at more than $1,300^{\circ}C$ with more than 60 % of refused coal ore are found by XRD to be non-crystalline in nature. In the case of the glass sample with 40 % of refused coal ore, from the sample melted at $1,200^{\circ}C$, a sodium aluminum phosphate peak, a disodium calcium silicate peak, and an unknown peak are observed. On the other hand, in the sample melted at $1,300^{\circ}C$, only the sodium aluminum phosphate peak and unknown peak are observed. And, peak changes that affect crystallization of the glass according to melting temperature are found. Therefore, it is concluded that glass with refused coal ore has good melting conditions at more than $1,200^{\circ}C$ and so can be applied to the construction field for materials such as glass tile, foamed glass panels, etc.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 제5회 영호남 학술대회 논문집
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• pp.48-52
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• 2003

Low melting crystalline solder glasses for CRT sealing were prepared from the composition of PbO 73.0~75.5 wt%, ZnO 12~15 wt%, $B_2O_3$ 7.0~9.0 wt%, BaO 1.5~3.5 wt%, $P_2O_5$ 1.0~2.5 wt%, $Bi_2O_3$ 0.5~20 wt%. The nucleation and crystallization of the crystalline solder glasses were studied by DTA, SEM and XRD. $2PbO{\cdot}ZnO{\cdot}B_2O_3$ crystalline phase was formed from glass matrix by heat-treatment of glass frits Crystalline solder glasses developed from this paper have good firing condition of $430{\sim}440^{\circ}C$ for 10min and good physical properties

• 한국전기전자재료학회논문지
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• 제14권8호
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• pp.652-657
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• 2001

Vanadate glasses containing 10~20mol% glass former, P$_2$O$_{5}$ were prepared by melting the batch in platinum crucible and quenching on the copper plate. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics having LiV$_3$O$_{8}$ were obtained by heat-treatment of this glass in crystallization temperature. The glass-ceramics showed singnificantly good capacity and long cycles life according to heating condition. In this paper, we described electrochemical properties during crystallization process and found the best crystallizaton condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass as cathode material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics heat-treated at 233$^{\circ}C$ for 3 hors showed good rechargeable capacity of 220mAh/g in the cycling range between 2.0 and 3.9V.en 2.0 and 3.9V.

• 한국재료학회지
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• 제34권7호
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• pp.355-362
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• 2024

AR (alkali resistant)-glass fibers were developed to provide better alkali resistance, but there is currently no research on AR-glass fiber manufacturing. In this study, we fabricated glass fiber from AR-glass using a continuous spinning process with 40 wt% refused coal ore. To confirm the melting properties of the marble glass, raw material was put into a (platinum) Pt crucible and melted at temperatures up to 1,650 ℃ for 2 h and then annealed. To confirm the transparent clear marble glass, visible transmittance was measured and the fiber spinning condition was investigated by high temperature viscosity measurement. A change in diameter was observed according to winding speed in the range of 100 to 700 rpm. We also checked the change in diameter as a function of fiberizing temperature in the range of 1,240 to 1,340 ℃. As winding speed increased at constant temperature, fiber diameter tended to decrease. However, at fiberizing temperature at constant winding speed, fiber diameter tended to increase. The properties of the prepared spinning fibers were confirmed by optical microscope, tensile strength, modulus and alkali-resistance tests.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 영호남학술대회 논문집
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• pp.311-315
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• 2000

Vanadate glass in the $LiO_2-P_2O_5-Bi_2O_3-V_2O_5$ system containing 10mol% glass fonner, $P_2O_5$ and $Bi_2O_3$ was prepared by melting the batch in pt. crucible followed by Quenching on the copper plate. We found that $LiO_2-P_2O_5-Bi_2O_3-V_2O_5$ glass-ceramics obtained from nucleation of glass showed signifieantly higher capacity and longer cycle life than conventionally made crystalline $LiV_3O_{8}$. In the present paper, we describe the charge / discharge properties during crystallization process and find the best crystallization condition of $LiO_2-P_2O_5-Bi_2O_3-V_2O_5$ glass as cathod material.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
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• pp.157-159
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• 2000

Vanadate glass in the $Li_2O-P_2O_5-V_2O_5$ system with 60mol% $V_2O_5$ was prepared by melting the bath in pt. crucible followed by quenching on the copper plate. We found that $Li_2O-P_2O_5-V_2O_5$ glass ceramics obtained from nucleation of $Li_2O-P_2O_5-V_2O_5$ glass showed significantly higher capacity and longer cycle life than conventionally made crystalline $LiV_3O_8$. In the present paper, We describe the charge/discharge properties during crystallization process and find the best crystallization condition of $Li_2O-P_2O_5-V_2O_5$ glass as cathode material. The Charge and discharge capacity of $Li_2O-P_2O_5-V_2O_5$ glass was about 220mAh/g for the cell heat-treated at $250^{\circ}C$ for 2.5hr.