• Title/Summary/Keyword: glass beads

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Photocatalytic Degradation of Phenol in $UV/TiO_2$ Packed-bed System ($UV/TiO_2$ 충진 반응기에서 페놀의 광산화 반응)

  • Park, Kil-Soon;Kim, Jong-Hwa;Lee, Sang-Wha
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.939-945
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    • 2005
  • The Photocatalytic activity was investigated with the increase of flow rate in a $UV/TiO_2$ packed-bed system. The rate of phenol degradation over $UV/TiO_2$ (dia. = 5 mm) was increased up to 300 mL/min and reached a plateau beyond 400 mL/min. The bead photocatalysts did not exhibit a distinct difference of the phenol degradation rate irrespective of corrosion rates of glass beads and $TiO_2$ coating amounts. Degussa P25 exhibited a higher photocatalytic activity in comparison to other $TiO_2$ sols(Ishihara & N). The performance(activity and durability) of $UV/TiO_2$ packed-bed system can be enhanced by the use of $TiO_2$-coated glass beads instead of granular types that is easily attrited by the shearing force of flowing fluids.

High Performance Glass Beads for Traffic Marking in Wet Weather (차선의 우천시 야간 시인성 향상을 위한 그라스 비드 적용 연구)

  • Lee, Chang-Geun;Lee, Hyun-Seock;Oh, Heung-Un
    • International Journal of Highway Engineering
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    • v.14 no.1
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    • pp.9-16
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    • 2012
  • The performance of road markings is classified into the visibility at daytime, night time, wet condition and rainy conditions. The objective of this study is to obtain the driving safety of drivers under conditions of unstable weather condition such as the rain. The visibility of road markings is closely related to the preview time and detection distances and the ways to improve road marking materials and increase the dry retroreflectivity and wet retroreflectivity, which are the measures of daytime and nighttime visibility is researched to decrease the traffic accidents. For this purpose, Road marking glass beads with the refraction rate of 1.5 and 2.2 are introduced to raise the retroreflectivity. After investigating the minimum threshold retroreflectivity and Install Minimum retroreflectivity at home and abroad, minimum control values for the roadmarking visibility and improvement of nightime rainy retroreflectivity are suggested by physical properties and retroreflectivity experiments.

Immobilization of Fungal Laccase on Keratin-Coated Soil and Glass Matrices

  • Ginalska, G.;Lobarzewski, J.;Cho, Nam-Seok;Choi, T.H.;Ohga, S.;Jaszek, M.;Leonowicz, A.
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.3
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    • pp.112-122
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    • 2001
  • Laccase enzymes from Cerrena unicolor and Trametes versicolor were immobilized on the activated glass beads (CPG), silica gel (SG) and soil (SL). The heterogeneous matrices were activated by ${\gamma}$-aminopropyltriethoxysilane (APTES) and glutaraldehyde (GA), and their surfaces were coated by keratin (KER) on activated or non-activated CPG, SG and SL. The laccase activities were tested in the aqueous solution for the native and immobilized preparations using different pH and temperature conditions. By keratin coating on supports, in the cases of CPG-KER and SL-KER, the immobilization yield was increased from about 80% to 90%. Moreover, much less protein was immobilized in keratin coated matrices than in inorganic ones alone (e.g. on CPG-KER 57.6%, whereas on CPG alone 80.6%). Laccase immobilization on keratin coated inorganic matrices was generally more effective than that of non-coated matrices. Concerned to pH dependency, the optima pH for immobilized laccases generally shifted towards to higher values, 5.5-5.8 and even 5.9 in the case of keratin for C. unicolor and from 5.3 to 5.7 for T. versicolor, respectively, and decreased less gradually both in acidic and alkaline regions. The immobilized laccase was more stable against thermal denaturation. This seems particularly true at $75^{\circ}C$ in the case of C. unicolor, where the activity of immobilized enzyme is > 50% higher than that of the free enzyme. For T. versicolor the respective values were $65^{\circ}C$, and 50%.

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Quantification of 3D Pore Structure in Glass Bead Using Micro X-ray CT (Micro X-ray CT를 이용한 글라스 비드의 3차원 간극 구조 정량화)

  • Jung, Yeon-Jong;Yun, Tae-Sup
    • Journal of the Korean Geotechnical Society
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    • v.27 no.11
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    • pp.83-92
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    • 2011
  • The random and heterogeneous pore structure is a significant factor that dominates physical and mechanical behaviors of soils such as fluid flow and geomechanical responses driven by loading. The characterization method using non-destructive testing such as micro X-ray CT technique which has a high resolution with micrometer unit allows to observe internal structure of soils. However, the application has been limited to qualitatively observe 2D and 3D CT images and to obtain the void ratio at macro-scale although the CT images contain enormous information of materials of interests. In this study, we constructed the 3D particle and pore structures based on sequentially taken 2D images of glass beads and quantitatively defined complex pore structure with void cell and void channel. This approach was enabled by implementing image processing techniques that include coordinate transformation, binarization, Delaunay Triangulation, and Euclidean Distance Transform. It was confirmed that the suggested algorithm allows to quantitatively evaluate the distribution of void cells and their connectivity of heterogeneous pore structures for glass beads.

Chemical Compositions of Glass Beads from Tombs of Bupwha-ri Site, Yeongdong (영동 법화리유적 출토 유리구슬의 화학적 특성: 토광묘 6호 및 8호)

  • Chung, Kwang-Yong;Kang, Hyung-Tae;Koh, Min-Jeong;Kim, Hwa-Jung
    • Journal of Conservation Science
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    • v.27 no.3
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    • pp.243-250
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    • 2011
  • Seven glass beads from Bupwha-ri site, Yeongdong dated Joseon dynasty were analyzed with SEM/EDS and X-ray diffraction methods. Six samples were classified to potash glass system($K_2O-CaO-SiO_2$) with HCA(High CaO and $Al_2O_3$) and high concentration of MgO suggested raw materials to plant ashes. Especially one sample from tomb no. 8 was highly different concentration of $K_2O$ and MgO with others. It was shown that they were different sources of raw materials. Mostly coloring agents of potash glasses were owing to Fe and Cu. One sample was found to lead glass system(PbO-$SiO_2$) with 12% PbO. The content of PbO was differentiated with other lead glasses since we analyzed so far. It needs more study for compositions of lead glasses with regions and ages.

Effect of Frequency and Fixed Solid Catalyst for Radical Production in Sonocatalysis (초음파 촉매 공정에서 주파수와 고정된 고체 촉매가 라디칼 생성에 미치는 영향)

  • Cho, Eunju;Na, Seungmin;Lee, Seban;Khim, Jeehyeong
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.219-223
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    • 2012
  • The fixed solid catalysts such as glass bead, steel mesh, and $TiO_2$ coated ceramic bead were used to investigate effect of radical production at different frequencies. The radical production rate at 300 kHz was faster than that at 35 kHz without solid, but the tendency was changed with the presence of glass bead. The presence of glass beads create non-continuous points between the solid and liquid phases leading to increased formation of cavitation bubbles. However, the radical production decreased when steel mesh was used at 35 kHz although the surface area of contact with liquid was same when glass bead was used. Hence the solid catalyst did not always enhance the radical production. The radical production using $TiO_2$ coated ceramic bead was dramatically increased at 35 kHz due to the breakage of $TiO_2$ coated ceramic bead. Therefore the radical productions at 300 kHz using fixed solid catalysts generally increased while at 35 kHz the results fluctuated according to the experimental conditions.

Analysis of Amperometric Response to Cholesterol according to Enzyme-Immobilization Methods (효소고정화 방법에 따른 콜레스테롤 검출용 바이오센서의 전류 감응도 분석)

  • Ji, Jung-Youn;Kim, Mee-Ra
    • Journal of the East Asian Society of Dietary Life
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    • v.21 no.5
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    • pp.731-738
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    • 2011
  • Cholesterol is the precursor of various steroid hormones, bile acid, and vitamin D with functions related to regulation of membrane permeability and fluidity. However, the presence of excess blood cholesterol may lead to arteriosclerosis and hypertension. Moreover, dietary cholesterol may affect blood cholesterol levels. Generally, cholesterol determination is performed by spectrophotometric or chromatographic methods, but these methods are very time consuming and costly, and require complicated pretreatment. Thus, the development of a rapid and simple analysis method for measuring cholesterol concentration in food is needed. Multi-walled carbon nanotube (MWCNT) was functionalized to MWCNT-$NH_2$ via MWCNT-COOH to have high sensitivity to $H_2O_2$. The fabricated MWCNT-$NH_2$ was attached to a glassy carbon electrode (GCE), after which Prussian blue (PB) was coated onto MWCNT-$NH_2$/GCE. MWCNT-$NH_2$/PB/GCE was used as a working electrode. An Ag/AgCl electrode and Pt wire were used as a reference electrode and counter electrode, respectively. The sensitivity of the modified working electrode was determined based on the amount of current according to the concentration of $H_2O_2$. The response increased with an increase of $H_2O_2$ concentration in the range of 0.5~500 ${\mu}M$ ($r^2$=0.96) with a detection limit of 0.1 ${\mu}M$. Cholesterol oxidase was immobilized to aminopropyl glass beads, CNBr-activated sepharose, Na-alginate, and toyopearl beads. The immobilized enzyme reactors with aminopropyl glass beads and CNBr-activated sepharose showed linearity in the range of 1~100 ${\mu}M$ cholesterol. Na-alginate and toyopearl beads showed linearity in the range of 5~50 and 1~50 ${\mu}M$ cholesterol, respectively. The detection limit of all immobilized enzyme reactors was 1 ${\mu}M$. These enzyme reactors showed high sensitivity; especially, the enzyme reactors with CNBr-activated sepharose and Na-alginate indicated high coupling efficiency and sensitivity. Therefore, both of the enzyme reactors are more suitable for a cholesterol biosensor system.

Effect of Yijin-tang on Gastric Motility between Normal Intact and Partial Pyloric Obstructed Rats (이진탕(二陳湯)이 정상 및 위 유문부가 부분폐색된 흰 쥐의 위 운동성에 미치는 효과)

  • Han, Soak-Young;Yoon, Sang-Hyub
    • The Journal of Internal Korean Medicine
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    • v.30 no.1
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    • pp.107-118
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    • 2009
  • Objectives : This study was aimed to investigated the effect of Yijin-tang on gastric motility and its mechanism of action in normal intact and partial pyloric obstructed rats. Methods : Gastric emptying was measured by the number of glass beads expelled from the stomach (containing one hundred of glass beads. ${\phi}1mm$) in 1 hour or 2 hours after glass beads and test drugs (normal saline. Yijin-tang 90mg/kg. Yijin-tang 270mg/kg) administration in normal intact and partial pyloric obstructed rats. In another series of experiments to evaluate the mechanism of Yijin-tang 270mg/kg under delayed conditions, normal intact rats were treated with atropine sulfate (1mg/kg,s.c.), cisplatin (10mg/kg,i.p.), quinpirole HCI (0.3mg/kg,i.p.) and NAME (NG-nitro-L-arginine methyl ester. 75mg/ kg,s.c.), respectively. Partial pyloric obstructed rats were modified by wrapping the nonabsorbable rubber ring (D :6mm, W:4mm, T: 1mm) around the 1st portion of the duodenum for 8 weeks. The myoelectrical activity of the gastric smooth muscle was recorded by a bipolar electrode placed at the abdominal surface in normal intact and partial pyloric obstructed rats. The gastric myoelectrical activity was measured for 30 minutes before and after orogastric administration of each solution (normal saline, Yijin-tang 270mg/kg) and expressed as dominant frequency, percent of normogastria and power ratio. Results : Yijin-tang improved gastric emptying more than normal saline in normal intact(p<0.001) and partial pyloric obstructed rats(p=0.002). Under the delayed gastric emptying induced by atropine sulfate, cisplatin, quinpirole HCI and NAME. Yijin-tang enhanced gastric emptying significantly in the cisplatin treated group(p<0.001). but didn't in other treated groups. Administration of Yijin-tang 270mg/kg has no significant effect on the myoelectrical activity of the gastric smooth muscle in both normal intact rats and partial pyloric obstructed rats. Conclusions : Yijin-tang seems to stimulate the gastric motility through suppressing the 5HT3 receptor and promoting the antroduodenal flow. We expect that Yijin-tang would be effective especially in dysmotility-like functional dyspepsia with partial pyloric obstruction or the side effects of cisplatin such as nausea, vomiting, abdominal discomfort, and delay of gastric emptying.

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암석의 SIP 측정 시스템 구축

  • Sin, Seung-Uk;Seong, Nak-Hun;Park, Sam-Gyu;Jo, Seong-Jun;Park, Gye-Sun
    • 한국지구물리탐사학회:학술대회논문집
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    • 2009.10a
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    • pp.196-197
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    • 2009
  • 지하에 전류를 흘려보내 분극현상을 유도하고, 이 유도분극 현상을 측정하는IP탐사는 금속 광물 탐사에서 널리 이용되고 있다. 특히 광대역주파수를 이용하는SIP탐사는 IP탐사에서 측정하는 전기비저항과 더불어 위상정보까지 제공해 줄 수 있어 금속광물의 종류를 구분하는 등 보다 효과적인 탐사 방법으로 제시되고 있다. 이 연구는 최근 원자재가 급등에 따른 국내 외 광산개발에 필요한 자원탐사 기술 개발의 일환으로 광석 중에 포함되어 있는 금속광물의 SIP 효과에 대한 기초적 연구를 수행한 것이다. 암석의 SIP를 측정 시스템은 GDP-32 system과 Lab transmitter(Zonge)를 사용하여 구성하였으며, 주파수에 따른 IP 효과를 측정하기 위하여 KCl 0.01 mol 용액으로 포화시킨 Glass beads에 황철석 분말의 중량비를 증가 시키면서 SIP를 측정하였다. 실험에 사용된 Glass beads의 직경은 $0.75{\sim}1.0\;mm$의 범위이고, 황철석은 원광석을 분쇄하여 $20{\sim}25$ mesh를 통과한 분말을 사용하였다. 실험방법은 아크릴 수지로 만든 육면체 시료홀더를 사용하여 처음에는 KCl 0.01 mol 용액으로 포화시킨 Glass beads의 SIP를 측정하고, 그 다음에 Glass beads 내에 황철석 분말을 중량비로 $1{\sim}10%$까지 증가 시키면서 SIP를 측정하였다. 이 때 사용한 주파수 대역은 $0.016{\sim}1024\;Hz$ 이며, 측정결과로부터 전기비저항과 Phase를 산출하여 도시하였다.

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Development of Precision Instrument for attaching Micro-structure(Glass Bead) on the AFM cantilever (마이크로 구조물의 원자현미경 캔티레버 부착을 위한 정밀기구개발)

  • Park, C.H.;Chae, Y.H.;Kweon, H.K.
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.6
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    • pp.117-124
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    • 2013
  • Recently, the cell adhesion phenomenon that occurs in or between cells and other substances has become an important field of research in biology and biomedical engineering. Among the research, the foundational studies primarily experiment using biomedical materials (e.g. Glass Beads) attached to an AFM cantilever. For cell adhesion research, the mechanism where biomedical materials can be attached to the cantilever must be developed for this purpose; however, the mechanism remains an insufficient step. In this paper, a new stage where the Glass Bead can be attached to the cantilever is designed and fabricated;, the mm range movement in the stage is controlled using the stepping motor with a minimum displacement of $1{\mu}m$. The adhesive flow is also controlled using a PZT actuator. In addition, through the air suction, the cantilever holder can be fixed to the stage. The new stage including the bond inflows mechanism is evaluated and analyzed using theory and experiments.