• Economic and Environmental Geology
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• v.47 no.2
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• pp.147-168
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• 2014

The soil geochemical exploration was carried out targeting around Tri Le area far from about 30 km with northwestern direction from Que Phong within Nghe An province. The interval of sampling are horizontal 200 m interval with 23 line and longitudinal 300 m with 10 line, resulting in 228 soil samples. Based on the result of the soil geochemical exploration, the detailed pitting survey was carried out targeting the grid point with high TREO content, resulting in 75 soil samples within 7 pits. The geology of survey area are consisted of Ban Chieng biotite granite complex and granitic gneiss intruding Ban Khang formation comprising of quartz schist and marble. Main mineralization in the study area have the characteristics of occurrence with tin, ruby and REE-bearing monazite and xenotime to be thought as occurring at the alteration zone of granite complex. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. As a analysis result with ICP-MS on the soil samples from the soil geochemical exploration, total REE oxide content of background amount to about 2 times of crustal abundance, enriching the heavy rare earth(about 2 times) and light rare earth(about 1.5 times). As a analysis result with ICP-MS on the soil samples from the soil detailed pit survey, we only identified outcrop considering as economic weathered granite body at the grid point 1-10 pit among 7 pits. As a synthetic consideration on the soil geochemical exploration and detailed pit survey, we tentatively designated Tri Le area as no promising target for REE. In 2014, we have the plan to carry out the soil geochemical exploration targeting the extended economic REE ore body in Quy Chau as project area from 2011 to 2012.

• Journal of Soil and Groundwater Environment
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• v.12 no.4
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• pp.35-53
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• 2007

Geochemical and isotope studies on the groundwater system of the Youngcheon area were carried out. Most groundwaters belong to Ca-$HCO_3$ and Ca-$SO_4$ types and some groundwaters belong to Na-$HCO_3$ type. Geochemical characteristics of these groundwaters were mainly affected by their basement rocks around the boreholes. High $SO_4$ content of groundwater is the result of reaction with sulfate or sulfide minerals in the host rock. Ca was originated from the carbonate minerals in the sedimentary rock. After the groundwater was saturated with calcite, the Na-$HCO_3$ type groundwaters were evolved by the reaction with plagioclase for a relatively long residence time. This explanation was supported by low tritium contents of Na-$HCO_3$ type groundwaters. ${\delt}a^{18}O$ and ${\delta}D$ data indicate that the groundwaters are of meteoric water origin and there was no difference between the various types of waters. Grondwaters from the boreholes BH-1, BH-9 and BH-12 showed the geochemical and isotopic characteristics of deep groundwater. Most borehole groundwaters except them did not show the systematic geochemical variations with sampling depth indicating that the shallow and deep groundwaters were mixed with each other throughout the study area. The results of water quality analysis indicate that the study area is highly contaminated by the introduction of agricultural sewage.

• Journal of the Korean Geographical Society
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• v.49 no.2
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• pp.221-244
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• 2014

We suggested several implications by examining geochemical properties of sediments in Simjeok, Jangdo, and Hwaeomneup mountain wetlands which are natural preservation areas. Geochemical properties of wetland sediments show that all wetlands were included in the type of fens, but their distribution patterns were different from one another. We classified three sub-groups of sediments using the two step cluster analysis on the ratio of exchangeable cations. Wetland sediments can be grouped into Ca-dominated, Mg-dominated, and K-dominated types. Simjeok wetland have Ca-dominated sediments, while the sediments of Jangdo wetland indicate the Mg-dominated and Ca-dominated characteristics. Hwaeomneup wetland is composed of K-dominated sediment mainly. Different properties in the ratio are affected by various environmental factors such as geological, pedological, and vegetational settings. Because these geochemical properties will be affected by climate change and human impacts, these will be environmental indicator in mountain wetlands and be used in wetland management. This scheme can be used for classification of mountain wetlands. Therefore, we should work on geochemical properties of wetland sediments and classification schemes based on geochemical properties not only to widen understanding in geomorphic system or ecosystem of mountain wetlands but to conserve mountain wetlands properly.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.69-76
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• 2021

This study is to identify the mineralogical properties of caprock samples from drilling cores of the Pohang basin, which is the research area for the demonstration-scale CO2 storage project in Korea. The interaction of water-rock-gas that can occur due to CO2 injection was identified using geochemical modeling. Results of mineralogical studies, together with petrographic data of caprock and data on the physicochemical parameters of pore water were used for geochemical modeling. Modelling was carried out using the The Geochemist's Workbench 14.0.1 geochemical simulator. Two steps of modeling enabled prediction of immediate changes in the caprocks impacted by the first stage of CO2 injection and the assessment of long-term effects of sequestration. Results of minerlaogical analysis showed that the caprock samples are mainly composed of quartz, K-feldspar, plagioclase and a small amount of pyrite, calcite, kaolinite and montmollonite. After the injection of carbon dioxide, the porosity of the caprock increased due to the dissolution of calcite, and dawsonite and chalcedony were precipitated as a result of the dissolution of albite and k-feldspar. In the second step after the injection was completed, the precipitation of dawsonite and chalcedony occurred as a result of dissolution of calcite and albite, and the pH was increased due to this reaction. Results of these studies are expected to be used as data to quantitatively evaluate the efficiency of mineral trapping capture in long-term storage of carbon dioxide.

• Economic and Environmental Geology
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• v.35 no.6
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• pp.509-521
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• 2002

The purpose of this study is to find out geochemical characteristics of stream sediments which are good indicator of geochemical hazard valuation and water in primary channels of the Jangheung area. We separated three groups which were granitoid area, granite gneiss area and tuffeous area by petrological properties. Physical and chemical characteristics of stream water such as temperature, pH, and EC were measured in the field between 1999 and 2001 and stream sediments samples were collected from April to May in 1999. For the chemical analysis of stream sediments samples, XRF, ICP-AES and NAA were used. The contents of the major elements had a similar contents in three groups and those of rare earth elements in granite gneiss area were lower value than those of other two groups. Zn and Cu were higher value than the other toxic elements. Through the enrichment factor and enrichment index features of the elements, we knew that $Fe_2O_3$, MgO, $TiO_2$, MnO and Eu, Yb of the tuffeous area samples and Co, Cr, Zn were enriched.

• Economic and Environmental Geology
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• v.44 no.1
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• pp.1-10
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• 2011

The geology of the Pacitan district which occupies Southern mountain zone in the southwestern margin of East Java, Indonesia, consists of a pile of clastics and pyroclastics grading upwards into a series of sediments of Middle Miocene age which are intruded by a number of quartz porphyries and subvolcanic dacitic to andesitic bodies in after that time. The geochemical exploration in the Pacitan district to find out anomalous areas related with metallic mineral dispersion from the concealed ore deposits had been carried out using traditional exploration techniques of geological mapping, stream sediment, panned concentrate and outcrop sampling. The anomalous zones of each element were detected in the following areas: Gempol for Cu; Jompong for Au; Kasihan for Cu-Pb-Zn. The strongest Cu-Pb-Zn anomalous values are overlapped at the Kasihan area. The geochemical survey of soil was conducted with the geological survey at the Kasihan area. The statistical values were calculated by the statistical analysis method. The patterns for Cu, Pb and Zn are similar to the normal distribution. The anomalous values of copper-lead-zinc and/or copper and zinc are overlapped at five zones surrounding quartz porphyry at the central part of the Kasihan area. The area was interpreted and chosen as an anomalous zone related with stockwork and skam mineralization, extending to approximately NNW-SSE direction.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.450-452
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• 2004

Using factor analysis and bivariate comparisons of major components in ground water, three geochemical processes were identified as controlling factors of ground water chemistry; 1) natural mineralization by water rock interactions, 2) effect of seawater which includes salinization by seawater near seashores and deposition of sea salt, and 3) nitrate contamination by N fertilization. Contribution of rainfall was also estimated from the measured composition of wet deposition. The geochemical processes were separated using total alkalinity as an indicator for natural mineralization, Cl for effect of seawater, and nitrate for N fertilization. Relatively high correlation of major components with nitrate suggests that nitrification of nitrogenous fertilizers significantly affects ground water chemistry. Total cations derived from nitrate sources have good linearity for nitrate in equivalent basis with a slope of 1.8, which is a mean of proton production coefficients in nitrification of two major compounds in nitrogenous fertilizers, ammonium and urea. Contribution of nitrate sources to base cations, Cl, and SO$_4$ in ground water was determined considering maximum contribution of natural mineralization to estimate a threshold of the effect of N fertilization for ground water chemistry, which shows W fertilization has a greatest effect than any other processes in ground water with nitrate concentration greater than 50 mg/L for Ca, Mg, Na and with concentration greater than 30 mg/L for Cl and SO$_4$.

• Journal of Korean Society for Atmospheric Environment
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• v.13 no.2
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• pp.171-174
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• 1997

To provide better insights into the factors and processes regulating the geochemical behavior of airborne lead (Pb), we have investigated several important aspects of its distribution characteristics using the data collected from the Kyung Hee University-Suwon Campus during 1989 through 1994. Although the Pb data in the area reflected the effects of many anthropogenic activities ongoing in the area, the data were quite useful to assess the geochemical facets affecting the temporal distributions of lead as well as particulate matter (PM). The analysis of these data indicated that the Pb patterns were characteristic of enriched Pb levels during odd-numbered years relative to even-numbered years, while those of PM were exhibiting pronouncingly different patterns. Despite many similarities and differences found between year-to-year distribution patterns, of Pb data, it was possible to discuss the facts associated with relatively high concentrations in the years 1991 and 1993 via normalization of Pb against PM data. According to this procedure, we were able to conclude that relative enrichment in Pb levels during 1991 was due to enhanced input of PM, while that of the year 1993 came from more chemically-oriented processes such as active adsorptive scavenging of Pb onto the PM surface. Based on our comparative analysis of the size-fractionated PM and Pb data sets, we propse that two distinctive mechanisms that are both of phyical (1991) and chemical nature (1993) exerted controls over the observed distribution patterns of airborne Pb in the atmosphere of Suwon.

• Ocean and Polar Research
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• v.32 no.3
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• pp.299-307
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• 2010

In conjunction with geochemical characteristics, rate of sulfate reduction was investigated at two sediment sites in the continental slope and rise (basin) of the Ulleung Basin in the East Sea. Geochemical sediment analysis revealed that the surface sediments of the basin site (D2) were enriched with manganese oxides (348 ${\mu}mol$ $cm^{-3}$) and iron oxides (133 ${\mu}mol$ $cm^{-3}$), whereas total reduced sulfur (TRS) in the solid phase was nearly depleted. Sulfate reduction rates (SRRs) ranged from 20.96 to 92.87 nmol $cm^{-3}$ $d^{-1}$ at the slope site (M1) and from 0.65 to 22.32 nmol $cm^{-3}$ $d^{-1}$ at the basin site (D2). Depth integrated SRR within the top 10 cm depth of the slope site (M1; 5.25 mmol $m^{-2}$ $d^{-1}$) was approximately 6 times higher than that at the basin site (D2; 0.94 mmol $m^{-2}$ $d^{-1}$) despite high organic content (>2.0% dry wt.) in the sediment of both sites. The results indicate that the spatial variations of sulfate reduction are affected by the distribution of manganese oxide and iron oxide-enriched surface sediment of the Ulleung Basin.

• Journal of the Korean Geophysical Society
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• v.5 no.1
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• pp.19-27
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• 2002

Geophysical surveys(self-potential, electromagnetic, electrical resistivity, and seismic refraction methods) were performed to delineate the flow channel of leachate from a AMD (acid mine drainage) by correlating the anomalies to geochemical characteristics at an abandoned mine (Jangpoong mine). The geophysical responses attempted to be correlated with water sample analysis data(pH, EC, heavy metals, ${SO_4}^{-2}$). Electrical dipole-dipole resistivity sections represent the low-resistivity zone trending northwest, which indicates the leachate flow by AMD along the contact of the mine waste rock dump and the bedrock. From the overall points of geophysical and geochemical anomalies, it is summarized that the flow channel of leachate by AMD can be successfully imaged with composite interpretations on the geophysical and geochemical studies.