• Economic and Environmental Geology
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• v.17 no.4
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• pp.289-298
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• 1984

Uraniferous black slates of the Okchon sequence occur in Koesan (northeast) through Miwon-Boun (middle) to the southwest off Taejon (southwest) within the Okchon fold belt. The Uraniferous balck slates in the southwest off Taejon are particularly well developed in Chubu (northeast) and Moksso-ri (middle) areas whereas they are less developed in Jinsan (southwest) area. The uraniferous beds range from less than a meter to 40 meters in thickness and range from less than 0.02% $U_3O_8$ (cut-off-grade) to 0.05% $U_3O_8$ in the southwestern district off Taejon. Electron microprobe analysis of uranium-minerals found in graphitic slate samples enables to estimate their major compositions semi-quantitatively so that uraninite, ferro-uranophane and chlopinite are tentatively identified. Uranium-minerals are closely associated with carbon and metal sulfides. Correlation analysis of trace element concentrations revealed that U and F.C., and U and Mo are lineary correlative respectively and their correlation coefficients are positively high whereas those of U and V, U and Mn, and U and Zr are negatively low, implying that uranium mineralization has been closely related with concentrations of carbon and molybdenum. Stable isotope analyses of pyrite sulfur range widely from +11.5% to -23.3% in ${\delta}^{34}S$ values whereas those of graphite carbon fall within a narrow range between -23.3% and -28.9% in ${\delta}^{13}C$ values. The wide range of ${\delta}^{34}S$ values suggests that the sulfur could be of meteoric origin rather than of igneous source. The narrow range of ${\delta}^{13}C$ values, which are close to those of coal, indicates that the graphite is organic carbon in origin. Therefore, it is concluded that the uranium mineralization in the Okchon sequence took place primarily in sedimentary environment rich in organic matter and sulfide ion, both of which served as the reducing agents to convert soluble uranyl complex to insoluble uranium dioxide.

• 보존과학연구
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• s.30
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• pp.103-124
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• 2009

Major and trace elements and cross section textures of the large-sized jar-coffins excavated in the Young San river area have been analyzed for categorization according to geochemical characteristics of the raw materials. As results, we have found out that the jar-coffins of the Oryang-dong and Ungok-dong have very similar characteristics, and those of Songwol-dong and Jangdeung show distinguishable characteristics from the others. In addition, similar characteristics have been detected in some U-shape jar-coffins from several sites such as Oryang-dong, Ungok-dong, Sinchon-ri, Mansu-ri and Yeon-ri posess on trace elements and cross section texture. These results indicate that there was active physical migration although the detail route of the physical migration is unclear at current stage.

• Ocean and Polar Research
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• v.32 no.3
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• pp.309-319
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• 2010

To assess community structure and diversity of archaea, a clone sequencing analysis based on an archaeal 16S rRNA gene was conducted at three sediment depths of the continental slope and Ulleung Basin in the East Sea. A total of 311 and 342 clones were sequenced at the slope and basin sites, respectively. Marine Group I, which is known as the ammonia oxidizers, appeared to predominate in the surface sediment of both sites (97.3% at slope, 88.5% at basin). In the anoxic subsurface sediment of the slope and basin, the predominant archaeal group differed noticeably. Marine Benthic Group B dominated in the subsurface sediment of the slope. Marine Benthic Group D and Miscellaneous Crenarchaeotal Group were the second largest archaeal group at 8-9 cm and 18-19 cm depth, respectively. Marine Benthic Group C of Crenarchaeota occupied the highest proportion by accounting for more than 60% of total clones in the subsurface sediments of the basin site. While archaeal groups that use metal oxide as an electron acceptor were relatively more abundant at the basin sites with manganese (Mn) oxide-enriched surface sediment, archaeal groups related to the sulfur cycle were more abundant in the sulfidogenic sediments of the slope. Overall results indicate that archaeal communities in the Ulleung Basin show clear spatial variation with depth and sites according to geochemical properties the sediment. Archaeal communities also seem to play a significant role in the biogeochemical carbon (C), nitrogen (N), sulfur (S), and metal cycles at each site.

• Korean Journal of Ecology and Environment
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• v.48 no.3
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• pp.168-175
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• 2015

This study was conducted in autumn to determine phosphorus (P) fraction in sediments of Daechung Lake, to elucidate controlling factors for sedimentary P, and to compare with the other areas. For this study, sediment samples were collected at 6 sites only once on November 2014 using ponar grab and analyzed for solid-phase P (Loosely adsorbed, Fe-bound, Al-bound, detrital apatite, and refractory organic P) by sequential extraction. Total phosphorus (TP) was relatively high in front of Daechung Dam and Hoinam where fish farm was run until 1997. The dominant sedimentary P form was Al-bound P, followed by Fe-bound P, which could be released from sediment to water column during suboxic state. Based on principal component analysis, Al-bound P, Fe-bound, and TP were controlled by grain size of sediments. Loosely adsorbed, detrital apatite, and refractory organic P were relatively highly accumulated at the mouth of major tributaries where suspended sediments were delivered. Sedimentary P concentrations in Daechung Lake sediments were not higher than in other lake sediments. Therefore, based on these results, major controlling factors were grain size and input of suspended sediments from tributaries.

• Economic and Environmental Geology
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• v.37 no.3
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• pp.277-290
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• 2004

The trench exploration was carried out on the quartz veins of the Tanggung area of Java, Indonesia. The chemical values of quartz vein samples for hydrothermal alteration zones in this area are defined such as over values of Ag : 2∼190ppm(Celak); 2∼41 ppm(Cilangkap), Au : 21∼17,400 ppb(Celak); 24∼91,100 ppb(Cilangkap), Cu : 9∼3,340 ppm(Celak); 2∼l,600 ppm(Cilangkap), Pb : 60∼52,900 ppm(Celak); 16∼2,960 ppm(Cilangkap), Zn : 12∼13,950 ppm(Celak); 14∼1,520 ppm(Cilangkap), respectively. Two drilling areas, Mt. Subang area(Celak area) and Mt. Cilangkap area(Cilangkap area), have been chosen based on the factors such as, geologic settings associated with gold mineralizations, highly anomalous areas revealed by geochemical survey such as chemical analysis of ore and soil, trench exploration, statistical processing of the chemical analysis, and petrographic studies of igneous rocks related to its mineralization, and graphic presentation of anomalous areas.

• Economic and Environmental Geology
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• v.56 no.5
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• pp.501-514
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• 2023

Forest fires can generate numerous pollutants through the combustion of vegetation and cause serious environmental problems. The global warming and climate change will increase the frequency and scale of forest fires across the world. In Korea, many nuclear power plants (NPPs) are located in the East Coast where large-scale forest fires frequently occur. Therefore, understanding the sorption and transport characteristics of radionuclides in the forest fire areas is required against the severe accidents in NPPs. This article reviewed the physiochemical changes and contamination of groundwater and soil environments after forest fires, and discussed sorption and transport of radionuclides in the subsurface environment of burned forest area. We considered the geochemical factors of subsurface environment changed by forest fire. Moreover, we highlighted the need for studies on changes and contamination of subsurface environments caused by forest fires to understand more specific mechanisms.

• Journal of the Mineralogical Society of Korea
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• v.21 no.2
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• pp.139-159
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• 2008

Geochemical analysis of the various kinds of water including observation borehole groundwater was carried out for the assessment of the hydrological safety of the underground oil storage cavern and the potentiality of mineralogical and microbiological clogging was estimated. Most of water samples belonged to $Ca-HCO_3$ and $Ca-HCO_3-SO_4$ types. There was no distinct chemical difference in the various kinds of water. All kinds of water are undersaturated with the calcite which is the major clogging mineral. Most water samples have low Fe and Mn concentrations. However, they are saturated or oversaturated with the iron-oxide/hydroxide minerals and have high dissolved oxygen contents which suggests the possibility of clogging by the iron-oxide/hydroxide minerals as a long-term aspect. Several water samples from the ground observation borehole also show the high saturation indices far the clay minerals, which can fill up the fractures, indicating the possibility of clogging by the clay minerals. Statistical analysis shows the degree of mineral precipitation or dissolution is mainly controlled by pH, Eh and DO of water samples. According to the microbial analysis, the aerobic microbes and slime forming bacteria are dominant in most water samples and anaerobic microbes including sulfate reducing bacteria are very low or not detected. Although the slime forming bacteria which are known as a main microbial cause of the clogging is lower than $10^5\;CFUs/mL$ in all water samples, because the slime forming bacteria are dominant microbe in several observation boreholes, the clogging can be caused by it as a long-term aspect. In addition, the possibility of clogging can be increased if the microbial effect is combined with the mineralogical effect such as iron oxide/hydroxide minerals for the possibility of clogging. Therefore, the systematic and long-term program for the assessment of clogging is required for the safe operation of underground oil storage cavern.

• Economic and Environmental Geology
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• v.49 no.5
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• pp.335-347
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• 2016

The mineralogical and geochemical characteristics of diverse carbonate rocks can be investigated by using VNIRSWIR(visible near infrared-short wavelength infrared) spectroscopic analysis as a rapid, nondestructive, and inexpensive tool. Comparing whole rock analysis to VNIR-SWIR spectroscopic analysis, the analytical method was investigated to estimate CaO contents, mud impurity, and whiteness of carbonate rocks involved in high-grade limestones in the field. We classify typical carbonate rocks in the upper Pungchon Formation in high-grade limestone mine area such as the Gangweon, Chungmu and Baegun mine in the Jeongseon area. The results show that powdered specimen has much higher reflectance than cutted specimen between the same sample. Whiteness is highly correlated with reflectance(0.99) for powdered specimen. The absorption of mineral mixtures shifts in position as a result of the mass ratio of calcite and dolomite in the Chungmu mine by changing to 75:25, 50:50, and 25:75. The absorption peak position in carbonate mixtures is highly correlated with CaO contents(0.98~0.99). Based on color system, the carbonate rocks are grouped into (milky) white, light grey, light brown, grey, and dark grey. The absorption peak position shifts from 2340 nm to 2320 nm as CaO contents decrease from 55.86 wt.% to 29.71 wt.%. We confirmed that absorption peak position shifts depending on the amount of Ca, which is bonded to $CO{_3}^{-2}$, Mg, and Fe contents replacing Ca. This result suggests that CaO contents in carbonate rocks can be considered to quantitative analysis in the field by spectroscopic analysis.

• Journal of the Korean Society of Marine Environment & Safety
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• v.15 no.2
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• pp.157-164
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• 2009

The metals such as Al, Ag, Au, Cu, Cd, Co, Fe, Ni, Pb, Zn, etc are present at very low concentration in seawater and are classified as so-called trace metals. Whiles some of them are used in metabolism of living organism as a micronutrient, they may show toxic effects on organisms in case of a limited threshold concentration of them Plenty of studies on trace metals have been performed bemuse trace metals have a persistent influence and an adverse effect on marine environment and ecosystem. For long years, when the concentration of trace metals in natural waters such as seawater and fresh water are measured with high precision and accuracy, some systematic errors have been recognized to be present in measurements. Since 1975 in US and European countries, the measured concentration of trace metals in seawater have been found to be lower by factors of 10-1,000 than the previous data of trace metals measurements and the vertical profiles of the measurements have been shown to reflect well-known biological, physical and geochemical processes. These results are attributed to great advances in analytical instrumentation and methodology for trace metals measurements. Precautions against the contamination of samples are required to be taken in the process of sampling, storage, and analysis of samples. However, in Korea, erroneous data of trace metals with regard to ocean and marine environment related survey and investigations are reported The lock of exact understanding and information regarding precautions in sampling, storage and analysis of samples lead to the deterioration of data quality, especially in the analysis of trace metals. The major procedures to obtain the accurate data of trace metals in natural waters are introduced for applying to the study and assessment of marine environments.

• Journal of Conservation Science
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• v.29 no.4
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• pp.345-354
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• 2013

This study analyses geochemistrical, microscopic, mineralogical characteristics of coals which have been collected from in and out of the shipwreck No 1 of Mado island during underwater excavation in Taean. The result from mineralogical and geochemical analysis reveals that the specific gravity of the coals is $1.28g/cm^3$. Considering that coals contains 10% mineral of it and the specific gravity of the pure is $1.15g/cm^3$, it is believed that the collected coals would be lignite or biturminous coal. The X-ray diffraction analysis which displays the peak of $2{\theta}$ is 20~25C degree, proves that the collected coals would be categorised as low rank coal. The collected coals is composed of: 93%-94%(93.5%) of vitrinite maceral group, 5%-6%(5.5%) of exinite maceral group, and 1% of inertinite maceral group. In addition, the average of reflection rate is $R_{mean}$: 0.627 showing that it would be either high volatile bituminous C coal or sub-bituminous C coal. Such result confirms that the coal is sub-bituminous C or high volatile bituminous C coal in accordance with the U.S Bureau of Mine(USBM) classification system. The element analysis reveals that the coal is the coking coal which is grouped as the bituminous coal. Comparative analysis between the coals of Mado Shipwreck No 1 and domestic coals shows that the coals of Mado Shipwreck is similar to the bituminous coal used in the area of Janggi in Pohang city.