• Membrane and Water Treatment
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• v.11 no.2
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• pp.159-166
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• 2020

In this study, the performance and antifouling properties of polysulfone (PSf) and polyvinylidene fluoride/polyvinylpyrrolidone (PVDF/PVP) membranes in a membrane bioreactor (MBR) were investigated. The membranes were prepared via phase inversion method, and then characterized by a set of analyses including contact angle, porosity and water flux and applied in a lab-scale MBR system. Soluble microbial product (SMP), extracellular polymeric substance (EPS), FTIR, gel permission chromatography (GPC) and particle size distribution (PSD) analyses were also carried out for MBR system. The results showed that the MBR with PSf membrane had higher hydrophobic organic compounds which resulted in formation of larger flocs in MBR. However, in this MBR had high compressibility coefficient of cake layer was higher (n=0.91) compared to MBR with PVDF/PVP membrane (n=0.8); hence, the fouling was more profound. GPC analysis revealed that compounds with molecular weight lower than 2 kDa are more formed on PSf membrane more than PVDF/PVP membrane. The results of FTIR analysis confirmed the presence of polysaccharide and protein compounds on the cake layer of both membranes which was in good agreement with EPS analysis. In addition, the results showed that their concentration was higher for the cake on PSf membrane.

• Korean Chemical Engineering Research
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• v.45 no.5
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• pp.500-505
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• 2007

The objectives of this research were to (1) identify the membrane fouling potential due to different fractions of NOM (2) correlate the physicochemical properties of NOM and membranes with the adsorption of humic substances on membrane (4) find out the effect of membrane physical and chemical washing according to membrane material. The static adsorption test and adsorption test showed that hydrophobic organics adsorbed much more quickly than hydrophilic organics. In case of the effect of membrane properties on the adsorption of organic fractions, the adsorption rate ratio(a) of hydrophobic membrane (0.016, 0.077) was greater than that of hydrophilic membrane (0.010, 0.033) regardless of the kind of organic fractions. This suggests that the UF membrane fouling were occurred mainly by internal pore size decreasing due to adsorption of organic into pore surface for hydrophobic membrane, and by sieving of organics and forming a gel layer on the membrane surface for hydrophilic membrane. In conclusion, the decrease in the pore volume, which was caused by the organic adsorption into the internal pore, was greater with the hydrophobic membrane than with the hydrophilic membrane. In case of the effect of membrane properties on permeate flux, the rate of flux decline for the hydrophobic membrane was significantly greater than that for the hydrophilic membrane.

• Food Science and Preservation
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• v.6 no.4
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• pp.424-428
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• 1999

The performance of a 30K polysulfone membrane for clarification of depectinized peach juice was studied Ultrafiltration of peach juice could minimize to loss of flavor and many compounds and was expected to effectively remove precipitation and suspended solid. The results showed that permeate flux increased with the increase of operating pressure and temperature. The permeate flux declined continuously as the process time increased. The values of soluble solid and titratable acidity of permeate were decreased or were at the same level, the turbidity was largely decreased. Total resistance decreased with lower temperature and lower pressure.

• Clean Technology
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• v.8 no.3
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• pp.119-128
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• 2002

In the present study the membrane filtration characteristics of a commercially available synthetic water-based cutting oil through two kinds of ultrafiltration membranes (HF1-45-CM50 and HF1-43-CM100) with molecular weight cut-offs of 50,000 and 100,000, respectively, have been investigated in detail. Among these membranes, the hydrophilic one (HF1-45-CM50) was found to show a satisfactory result for both the permeate flux and the permeability of oil components, whereas the permeate flux obtained with the hydrophobic membrane (HF1-43-CM100) appears to be significantly low, indicating that synthetic cutting oil was easily wetted on the hydrophobic membrane surface and induced more membrane fouling. The effect of material characteristics of the membrane on the filtration characteristics was found to be much more significant compared with the mean pore size of the membrane. Backflushing by nitrogen gas was applied to reduce the formation of a gel layer and membrane fouling. With the hydrophilic membrane, the backflushing was found to increase the permeate flux, whereas the backflushing resulted in a decrease in flux for the hydrophobic membrane. The flux recovery was observed to be highest when the membranes fouled with waste synthetic cutting oil were immersed into a cleaning solution for more than 72 hours and then backflushed by nitrogen gas.