• 제목/요약/키워드: gel characteristics

검색결과 1,359건 처리시간 0.028초

다층구조 Water Gel Barrier의 농도변화에 따른 폭발특성에 대한 실험적 연구 (Experimental Studies of the Explosion Characteristics by Varying Concentrations of a Multi Layered Water Gel Barrier)

  • 하대일;박달재
    • 한국안전학회지
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    • 제34권1호
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    • pp.40-44
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    • 2019
  • Experimental studies have been carried out to investigate characteristics of gas explosion using a multi layered water gel barrier in a vented explosion chamber. The chamber is consisted of 1600 mm in length, with a square cross-section of $100{\times}100mm^2$. The gel concentration of inner layer of MLWGB ranged from 10% to 90% with intervals of 10% by weight of gel. Displacement of the MLWGB was photographed with a measured using a high-speed video camera, and pressure development was measured using a data acquisition system. It was found that MLWGBs with 10 ~ 20% inner layer concentrations were ruptured during the explosions. As the concentrations of inner layer increased from 30% to 90%, the barriers were not ruptured. As the gel concentrations of the inner layer increased, the displacement increased toward the chamber exit and the pressure decreased for the ruptured barriers. It was found that the pressure attenuation obtained from the MLWGB was higher than that of the single water gel barrier. For the cases of non-ruptured barriers, the pressure inside the chamber less increased with increasing gel concentrations of the inner layer. It was also found that the displacement moved back into the chamber for non-ruptured MLWGBs, and it was sensitive to the gel concentrations.

실리카에어로겔의 상압합성 및 특성연구(I) (Syunthesis of Silica Aerogel at Ambient Pressure and Characterization (I))

  • 강신규;최세영
    • 한국세라믹학회지
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    • 제33권12호
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    • pp.1394-1402
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    • 1996
  • The Silica gel with the density of 0.2g/cm3 and porosity of 90% was synthesized. The silica wet gel was dried and heat-treated under the ambient pressure after modification of the wet gel surface by TMCS. Specific surface area total pore volume and mean pore radius of dried gel were all increased with increasing heat treatment temperature and confirmed about 1400m2/g, 4.5cc/g and 8 nm respectively after heat treatment above 25$0^{\circ}C$. But the pore size distribution of dried gel was in the range of 1-100nm and was almost indepen-dent of temperature. As the result of external shape pore characteristics and microstructure of gel using SEM similar properties were observed between the silica gel synthesized in this study and the silica aerogel through the super critical drying.

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Effects of Specific Interaction Altering Reagents on Hardnesses of Succinylated Soy Protein Gel

  • Bae, Dongho;Jung, Hosun;Choi, Yong-Hee
    • Journal of Applied Biological Chemistry
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    • 제42권3호
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    • pp.125-129
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    • 1999
  • The changes in gel characteristics of soy protein and succinylated soy protein due to various specific interaction-altering reagents which affect the formation and textural properties of gels, were studied. The reagents were added to 15% soy protein solutions prior to heat treatment. Succinylated soy protein formed harder gel without the addition of reagents. Hardly no gels were formed with urea, indicating that hydrogen bonds significantly contributed to the formation and hardness of the gel and the effects of urea on the hardness of succinylated soy protein gel were more significant. Disulfide bonds were important in the formation of hard gels whether they were succinylated or not, but the contributions of hydrophobic interactions to gel hardness were relatively insignificant. The hardness reducing effects of NaCl and NaSCN were more significant in succinylated soy protein gel. As such, electrostatic interactions were important for succinylated soy protein to form hard gel but not for unmodified soy protein.

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은행 분말을 첨가한 청포묵의 항산화활성 및 품질특성 (Antioxidant Activity and Quality Characteristics of Mung Bean Starch Gel Prepared with Ginkgo Nut Powder)

  • 주신윤;최해연
    • 한국식생활문화학회지
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    • 제29권1호
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    • pp.84-90
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    • 2014
  • This study investigated the effects of ginkgo nut powder on the antioxidant activity and quality characteristics of mung bean starch gel. Mung bean starch gels were prepared with different amounts of ginkgo nut powder (0, 1, 3, 5, and 7%). The antioxidant activity of ginkgo nut powder and mung bean starch gel was estimated through measuring DPPH free radical scavenging activity and total phenolic acid content. For analyzing quality characteristics several factors were considered: syneresis, pH, color, texture profile analysis, and sensory evaluations. In the results, syneresis in the treated group was higher than the control group. The pH, b values, total phenolic acid content, and DPPH free radical scavenging activity of mung bean starch gels also significantly increased with increasing ginkgo nut powder. In contrast, the L values and a values of mung bean starch gels significantly decreased with increasing ginkgo nut powder. In the texture profile analysis, the mung bean starch gels with 5% and 7% ginkgo nut powder showed significantly lower degrees of hardness, chewiness, and gumminess. On the other hand, cohesiveness was highest in the mung bean starch gels with 5% and 7% ginkgo nut powder. The consumer acceptability score for the mung bean starch gel prepared with 5% and 7% ginkgo nut powder ranked significantly higher than the other groups in flavor and taste. Overall, these results suggest that ginkgo nut powder is a good ingredient for increasing the consumer acceptability and functionality of mung bean starch gel.

수분에 의존하는 단백질의 특성이 어묵의 조직에 미치는 영향 (Moisture-dependent Gelation Characteristics of Nonfish Protein Affect the Surimi Gel Texture)

  • Chung, Kang-Hyun;Lee, Chong-Min
    • 한국식품조리과학회지
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    • 제12권4호
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    • pp.571-576
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    • 1996
  • The moisture-dependent gelation characteristics of five different proteins are evaluated to understand the modification of gel strength when they are added in surimi gel. Compressive force and penetration force of protein gels gradually decreased with increase of moisture level, with showing markedly decrease at certain point of moisture level called critical moisture level. The critical moisture level for gelation of SPI-1, SPI-2, EW, WPC and LA were 79.4%, 81.6%, 91.4%, 87,8% and 84.7%, respectively. Beyond this critical level of water, protein gel matrix begins to lose its water binding and structural integrity. The mnisture that was not re tained by a protein was available to diluting the protein matrix and eventually weakened the overall gel strength. EW and MPI showed higher water retention than those of SPI, WPC and LA. The compressive force of SPI, WPC and LA-incorporated surimi gel at the varying moisture levels strongly correlated with the amount if water retained at corresponding moisture level within those protein (r=0.99).

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Silicon Alkoxide계 가수분해에서 Alkoxy Group과 촉매의 첨가에 대한 영향 (The Effects on Alkoxy Group and Catalyst in Hydrolysis of Silicon Alkoxide System)

  • 김세훈;오근호;;강원호
    • 한국세라믹학회지
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    • 제24권6호
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    • pp.561-571
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    • 1987
  • In case of glass ceramics and powder preparation from the metalakoxide solutions, metalakoxide solutions with a various species of alkoxy groups have unique characteristics. Therefore, in this study, the mixing ability of homogeneous sol, gel morphology and physical properties of gels were investigated by the changes in terms of the different four alkoxy groups, CH3-, C2H5-, i-C3H7-n-C4H9-, along with the catalyst for the purpose of the observation about the homogenous transition range from sol to gel. As a result, when the fixed condition was mol ratio of H2O/Si(OR)4=2.0 and variables were batch composition and addition amount of catalyst, the characteristics of Tetra-normal-Butoxysilane and Tetra-iso-propoxysilane systems had very narrow sol-gel conversion region than Tetramethoxysilane and Tetraethoxysilane system. And silicon-alkoxide, systems having narrow sol-gel conversion region were enlarged by addition of catalyst. In viewpoint of the weight loss of gel produced by hydrolysis of silicon alkoxide systems with different four alkoxy groups, the amounts of weight loss of gel containing large molecular alkoxy groups were much more than those of small molecular alkoxy group.

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겔 캐스팅 공정을 위한 알루미나 슬러리에서의 첨가제 함량 변화에 따른 겔화특성 평가 (Evaluation of Gelation Characteristics with The Variation of Additive Contents in The Alumina Slurry for Gel Casting Process)

  • 정준기;오창용;하태권
    • 소성∙가공
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    • 제31권5호
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    • pp.290-295
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    • 2022
  • Recently, the use of high-tech ceramic parts in functional electronic parts, automobile parts and semiconductor equipment parts is increasing. These ceramics materials are required to have high reproducibility, reliability, large size and complex shapes. The researchers initiated the work to develop a new shaping method called gel casting, which allows high performance ceramic materials with a complex shape to be produced. The manufacturing process parameters of gel casting include uniform mixing of the initiator, bubble removal, and slip injection. In this study, we analyzed the dispersion and gelation characteristics according to the change in the additive content of the alumina slurry in the gel casting process. The alumina slurry for gel casting was prepared by mixing a solvent, a monomer and a dispersant through a ball mill. Alumina powder and a gelation initiator were added to the mixed solution, and ball milling was performed for 24 hours. A viscosity of 6,435 cps and a stable zeta potential value were obtained under the conditions of alumina powder content of 55 vol% and dispersant 2.0 wt%. After curing for 12 hours by adding aps 0.1wt%, TEMED 0.2wt%, and Monomer 3, 5wt%, it was possible to separate from the molding cup, confirming that the gelation was completed.

고흡수성(高吸水性) Polymer와 Cellulose의 흡수특성(吸水特性) 비교(比較) (The Comparison of Absorption Characteristics between High Absorbent Polymers and Cellulose)

  • 양인;안원영
    • Journal of the Korean Wood Science and Technology
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    • 제18권2호
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    • pp.36-48
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    • 1990
  • This experiment was carried out to improve the quality of high absorbent polymer which has excellent absorptivity and water retention compared to pulp and absorption sheet, through absorption characteristics-absorptive power, water retention, absorption rate, gel strength, pH, particle size, and moisture content. - of six polymers, namely, anionic polyacrylamide, cationic polyacrylamide, polyacrylic, acid polyvinyle alcohol 500, and 1500, and a-cellulose. and to examine the possibility of substitution of amide groups for carboxyl group and/or hydroxyl group which were commercial high absorbent polymer by comparing the absorption characteristics of the polymers. Polyacrylamide has high absorptive power and water retention, but has low gel strength and poor absorption rate. The rest of polymers were similiar to ${\alpha}$-cellulose in every respect. Thus, polyacrylamides could be replaced with polyacrylic acid and polyvinyl alcohol which are presently a high absorbent polymers. In comparing the absorption characteristics and the absorptive power of the polymers-anionic polyacrylamide, cationic polyacrylamide, polyacrylic acid, polyvinyle alcohol. a-cellulose-the absorptive power was in inverse proportion to the gel strength and absorption rates, affected by the particle size and pH change.

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Red muscle과 White muscle의 근원섬유단백질의 특성의 비교 (Comparison of Biochemical Characteristics of Myofibrillar Proteins from Red Muscle and White Muscle)

  • 양융;신완철;오두환;진홍승;김기태
    • 한국식품과학회지
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    • 제18권3호
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    • pp.173-180
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    • 1986
  • 근섬유의 생화학적 특성을 규명하기 위하여 red muscle과 white muscle로 부터 myofibril과 actomyosin을 각각 조제하고 그 생물활성 및 SDS-polyacrylamide gel전기 영동상을 비교하였다. 또한 동물의 중류에 따른 특성의 차이를 알아보기 위하여 소의 근육과 닭의 근육을 비교하였다. Myofibril의 SDS-polyacrylamide gel 전기 영동상으로 부터 red muscle은 white muscle보다 30K성분의 함량이 높다는 사실을 알았다. 소의 근육과 닭의 근육은 actomyosin ATPase활성의 이온강도의존성 및 ATPase activity-pH curve에서 차이를 보였다.

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젤형 염료 태양전지의 광전변환 특성에 관한 연구 (Study for Photovoltaic Characteristics of Gel Type Dye Sensitized Solar Cells)

  • 박병욱;곽동주;성열문
    • 조명전기설비학회논문지
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    • 제23권2호
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    • pp.168-174
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    • 2009
  • 본 연구에서는 Poly(VdF-HFP)를 사용한 Gel Polymer 전해질을 제작하여 기존의 액상전해질과 비교하였다. 제작된 젤 고분자 전해질의 성분은 FTIR 분석을 사용하여 화학적 구조를 고찰한 후, 성분조사를 통해 Gel Polymer 전해질임을 확인하였으며, SEM 관측을 통해 Polymer 상태의 Gel 전해질의 구조를 확인하였다. 본 실험에서 제작된 젤 고분자 전해질을 구성하는 DEC와 PC의 최적의 성분비는 5 : 5임을 확인할 수 있었다. 최적조건의 젤 고분자전해질을 이용하여 제작된 염료 태양전지(DSCs)의 효율은 $3{\sim}4[%]$정도의 측정값을 얻었으며, 이상의 결과로부터 기존의 액상 전해질을 대체할 수 있는 준 고체형 염료태양전지의 제작이 가능함이 확인되었다.