• Title/Summary/Keyword: gas-slurry

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Study on Effect of gas superficial velocity on particle behavior in three phased Slurry Bubble Column Reactor (3상 Slurry Bubble Column Reactor에서 기체유속에 따른 고체입자의 거동에 대한 연구)

  • Yang, Jung-Hoon;Yang, Jung-Il;Lee, Ho-Tae;Kim, Hak-Joo;Chun, Dong-Hyun;Jung, Heon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.876-879
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    • 2009
  • Fischer-Tropsch 합성 반응과 같은 slurry bubble column reactor에서는 반응 속도를 증진시키기 위해서는 서로 다른 상간의 접촉 면적을 최대화함으로써 물질 전달을 원활하게 유지하여야 한다. 특히 Fischer-Tropsch 합성 반응에서는 반응물인 기체가 촉매로서 기능하는 고체 표면으로의 external mass transfer가 효과적으로 이루어져야 하기 때문에 반응기 내의 기체의 거동뿐만 아니라 고체인 촉매의 분포에 대한 연구가 활발하게 이루어지고 있다. 따라서 본 연구에서는 반응기 내에 기체의 superficial velocity를 변화시키면서 기체의 hold up 뿐만 아니라 고체 입자의 분포특성에 대하여 관찰하였다. Superficial velocity가 증가함에따라 gas hold up의 경우, 일정하게 증가하다가 6 cm/sec 이상에서 그 증가폭이 감소하였다. 즉 6 cm/sec이상에서 turbulent flow regime을 형성하였다. 또한 고체입자의 분포 역시 기체의 superficial velocity가 증가함에따라 보다 균일하게 되는 것을 확인할 수 있었다.

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Performance Evaluation and Characteristic Study of the Single Anaerobic Digestion from Piggery Slurry (돈분 슬러리를 이용한 단상 혐기소화공정의 특성연구 및 성능평가)

  • Park, Woo-Kyun;Jun, Hang-Bae;Park, Noh-Back;Kwon, Soon-Ik;Shin, Joung-Du;Hong, Seung-Gil
    • Korean Journal of Environmental Agriculture
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    • v.30 no.1
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    • pp.31-36
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    • 2011
  • BACKGROUND: Disposal of slurry animal manure produced by an anaerobic slurry-type barn method is not easy since the animal slurry contain high moisture content which makes solid-liquid separation a difficult process. However, recently, the interest about anaerobic digestion process as an environment-friendly waste disposal method has gained a wide interest because it can treat highly organic matter contained by the piggery slurry, decrease the odor after treatment, and enable the effective recovery of the methane gas which is a valuable energy resource. The objectives of this study were to identify the solubilization characteristics and to improve the anaerobic digestion efficiency of piggery slurry through full-scale anaerobic digestion experiments. METHODS AND RESULTS: In a full-scale continuous anaerobic digestion operation, the adaptability of single anaerobic digestion and its digestion efficiency were also evaluated in the farm field. The actual pH range and alkalinity concentration of piggery slurry used during the operation were comparatively higher than the concentrations of pH and alkalinity in the digestion tank which were stable at 7.5~8.0, 4,008 mg/L (as$CaCO_3$), respectively. The removal efficiency of organic matter (TCOD) by anaerobic digestion was 75~90% and methane gas production amount was at 0.33 L/L/day, a little higher than that of ordinary animal manure. CONCLUSION(s): Our findings showed higher recovery of highly purified methane and greater efficiency of anaerobic tank digestion since its methane gas content was at 65~70%.

CMP properties of $SnO_2$ thin film (가스센서 $SnO_2$ 박막의 광역평탄화 특성)

  • Choi, Gwon-Woo;Lee, Woo-Sun;Park, Jeng-Min;Choi, Seok-Jo;Park, Do-Sung;Kim, Nam-Oh
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1600-1604
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    • 2004
  • As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing (CMP) process was required for the global planarization of inter-metal dielectric(IMD) layer with free-defect. The effect of alternative commerical slurries pads, and post-CMP cleaning alternatives are discuess, with removal rate, scratch dentisty, surface roughness, dishing, erosion and particulate density used as performance metrics. we investigated the performance of $SnO_2$-CMP process using commonly used silica slurry, ceria slurry, tungsten slurry. This study shows removal rate and nonuniformity of $SnO_2$ thin film used to gas sensor by using Ceria, Silica, W-Slurry after CMP process. This study also shows the relation between partical size and CMP with partical size analysis of used slurry.

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CMP properties of $SnO_2$ thin film ($SnO_2$ 박막의 CMP 특성)

  • Choi, Gwon-Woo;Lee, Woo-Sun;Ko, Pil-Ju;Kim, Tae-Wan;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.93-96
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    • 2004
  • As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing (CMP) process was required for the global planarization of inter-metal dielectric(IMD) layer with free-defect. The effect of alternative commerical slurries pads, and post-CMP cleaning alternatives are discuess, with removal rate, scratch dentisty, surface roughness, dishing, erosion and particulate density used as performance metrics. we investigated the performance of $SnO_2$-CMP process using commonly used silica slurry, ceria slurry, tungsten slurry. This study shows removal rate and nonuniformity of $SnO_2$ thin film used to gas sensor by using Ceria, Silica, W-Slurry after CMP process. This study also shows the relation between partical size and CMP with partical size analysis of used slurry.

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CMP properties of $SnO_2$ thin film ($SnO_2$ 박막의 CMP 특성)

  • Lee, Woo-Sun;Choi, Gwon-Woo;Ko, Pil-Ju;Hong, Kwang-Jun;Seo, Young-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.184-187
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    • 2003
  • As the integrated circuit device shrinks to the smaller dimension, the chemical mechanical polishing (CMP) process was required for the global planarization of inter-metal dielectric(IMD) lyaer with free-defect. The effect of alternative commerical slurries pads, and post-CMP cleaning alternatives are discuess, with removal rate, scratch dentisty, surface roughness, dishing, erosion and particulate density used as performance metrics. we investigated the performance of $SnO_2-CMP$ process using commonly used silica slurry, ceria slurry, tungsten slurry. This study shows removal rate and nonuniformity of $SnO_2$ thin film used to gas sensor by using Ceria, Silica, W-Slurry after CMP process. This study also shows the relation between partical size and CMP with partical size analysis or used slurry.

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Rapid and Simultaneous Determination of Volatile Fatty Acids and Indoles in Pig Slurry and Dog Excrement by Solid-Phase Micro-Extraction Method with Gas Chromatography

  • Kim, Hyun-Jung;Yu, Mee-Seon;Yang, Sung-Bong
    • Journal of Environmental Science International
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    • v.23 no.10
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    • pp.1693-1701
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    • 2014
  • A rapid and simple method for the quantitative determination of volatile fatty acids (VFAs; propionic acid, n-butyric acid, i-valeric acid and n-valeric acid) and indoles (phenol, p-cresol, 4-ethyl phenol, indole and skatole) in pig slurry and dog excrement using solid-phase micro-extraction (SPME) coupled to gas chromatography was evaluated. $50/30{\mu}m$ DVB/CAR/PDMS (Divinylbenzene/Carboxen/Polydimethylsiloxane) fiber was used to extract the target compounds in aqueous media. Sample amount and adsorption time was standardized for the routine analysis. Detection limits were from 0.11 to $0.15{\mu}gL$ for VFAs and from 0.12 to $0.28{\mu}gL$ for indoles and the correlations observed ($R^2$) were 0.975~1.000. This method was applied to the pig slurry, fertilizer, compost and dog excrement. In nearly all cases, the indoles were detected in concentrations of higher than their limits of detection (DOLs). But the VFAs in swine manure were below their DOLs.

Effects of Consumable on STI-CMP Process (STI-CMP 공정에서 Consumable의 영향)

  • 김상용;박성우;정소영;이우선;김창일;장의구;서용진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.185-188
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    • 2001
  • Chemical mechanical polishing(CMP) process is widely used for global planarization of inter-metal dielectric (IMD) layer and inter-layer dielectric (ILD) for deep sub-micron technology. However, as the IMD and ILD layer gets thinner, defects such as micro-scratch lead to severe circuit failure, which affect yield. In this paper, for the improvement of CMP Process, deionized water (DIW) pressure, purified $N_2$ (P$N_2$) gas, slurry filter and high spray bar were installed. Our experimental results show that DIW pressure and P$N_2$ gas factors were not related with removal rate, but edge hot-spot of patterned wafer had a serious relation. Also, the filter installation in CMP polisher could reduce defects after CMP process, it is shown that slurry filter plays an important role in determining consumable pad lifetime. The filter lifetime is dominated by the defects. However, the slurry filter is impossible to prevent defect-causing particles perfectly. Thus, we suggest that it is necessary to install the high spray bar of de-ionized water (DIW) with high pressure, to overcome the weak-point of slurry filter. Finally, we could expect the improvements of throughput, yield and stability in the ULSI fabrication process.

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The Effects of Zeolite on Ammonia, Nitrous Oxide Emission, and Forage Yield from Pig Slurry Applied to the Forage Corn Cropping

  • Choi, Ah-Reum;Park, Sang-Hyun;Kim, Tae-Hwan
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.40 no.4
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    • pp.274-278
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    • 2020
  • Pig slurry (PS) is the most applicable recycling option as an alternative organic fertilizer. The application of pig slurry has the risk of air pollution via atmospheric ammonia (NH3) and nitrous oxide (N2O) emission. The zeolite has a porous structure that can accommodate a wide variety of cations, thus utilizing for the potential additive of deodorization and gas adsorption. This study aimed to investigate the possible roles of zeolite in mitigating NH3 and N2O emission from the pig slurry applied to the maize cropping. The experiment was composed of three treatments: 1) non-N fertilized control, 2) pig slurry (PS) and 3) pig slurry mixed with natural zeolite (PZ). Both of NH3 and N2O emission from applied pig slurry highly increased by more than 3-fold compared to non-N fertilized control. The NH3 emission from the pig slurry was dominant during early 14 days after application and 20.1% of reduction by zeolite application was estimated in this period. Total NH3 emission through whole period of measurement was 0.31, 1.33, and 1.14 kg ha-1. Nitrous oxide emission in the plot applied with pig slurry was also reduced by zeolite treatment by 16.3%. Significant increases in forage and ear yield, as well as nutrient values were obtained by pig slurry application, while no significant effects of zeolite were observed. These results indicate that the application of zeolite and pig slurry efficiently reduces the emission of ammonia and nitrous oxide without negative effects on maize crop production.

The Effect of Spray Characteristics on Flue Gas Desulfurization Yield in Spray Drying Sorber (반건식 세정기의 슬러리 분무 특성에 따른 산성가스 제거효율)

  • Yang, Hyun-Mo;Kim, Sang-Soo
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.79-84
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    • 2001
  • The effect of spray characteristics on desulfurization yield was evaluated by performing experiments with pilot spray drying sorber (SDS). Among the variables of operating conditions, the slurry-spraying conditions were chosen as major parameters; Stoichiometric ratio and Sauter mean diameter of slurry droplet were varied for the different gas temperatures and $SO_{2}$ concentrations in the inlet gas flow. From the experimental results, we proposed semi-empirical models of desulfurization yield for both Stoichiometric ratio and Sauter mean diameter of droplets. The optimal condition of spray can be determined based on these results, which might be applied to the design or scale-up of SDS systems.

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Fabrication Of Thin Electrolyte Layer For Solid Oxide Fuel Cell by Vacuum Slurry Dip-coating Process (진공 슬러리 담금 코팅 공정에 의한 고체 산화물 연료전지용 박막 전해질막 제조에 관한 연구)

  • Son, Hui-Jeong;Lim, Tak-Hyoung;Lee, Seung-Bok;Shin, Dong-Tyul;Song, Rak-Hyun;Kim, Sung-Hyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.2
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    • pp.204-211
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    • 2006
  • The electrolyte in the solid oxide fuel cell must be dense enough to avoid gas leakage and thin enough to reduce the ohmic resistance. In order to manufacture the thin and dense electrolyte layer, 8 mol% $Y_2O_3$ stabilized-$ZrO_2$ (8YSZ) electrolyte layers were coated on the porous tubular substrate by the novel vacuum slurry dip-coating process. The effects of the slurry concentration, presintering temperature, and vacuum pressure on the thickness and the gas permeability of the coated electrolyte layers have been examined in the vacuum slurry coating process. The vacuum-coated electrolyte layers showed very low gas permeabilities and had thin thicknesses. The single cell with the vacuum-coated electrolyte layer indicated a good performance of $495\;mW/cm^2$, 0.7 V at $700^{\circ}C$. The experimental results show that the vacuum dip-coating process is an effective method to fabricate dense thin film on the porous tubular substrate.