• Title/Summary/Keyword: gas-slurry

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Design of Highly Reliable Thick Film Gas Sensor Using SnO2 Nanofibers (SnO2 나노섬유를 이용한 고신뢰성 후막 가스센서 설계)

  • Jung, Jin Wook;Park, Sang Jin;Jeong, In Bong;Kim, Bo-Young;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.25 no.4
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    • pp.271-274
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    • 2016
  • The reliability and reproducibility of gas sensors are very important for real applications. The influence of nanofiber length and sensing film thickness on the reliability and response of gas sensing characteristics was investigated. For this, the length of $SnO_2$ nanofibers was controlled by tuning ultrasonic treatment and the different thicknesses of sensing films were prepared by manipulating the amount of slurry deposition. The sensor prepared from long nanofibers (length: ${\sim}3.6{\mu}m$) showed the significant fluctuation of gas sensing characteristics when the film becomes thinner than $18{\mu}m$, while that prepared from short nanofibers (length: ${\sim}0.9{\mu}m$) showed reproducible sensor response and resistance regardless of film thickness. Moreover, the shortening of nanofibers enhanced the gas response ~2 times, which can be explained by the increase of chemiresistive fiber-to-fiber contacts. The reproducibility, gas response, and selectivity of $SnO_2$ nanofiber gas sensor could be controlled by tuning nanofiber length, film thickness, and catalyst loading.

Characteristics of Large Green and Sintered Alumina Ceramics by Filter Pressing (필터 프레싱으로 제조한 대형 알루미나 세라믹스 성형체 및 소결체의 특성)

  • Lee, Hyun-Kwuon;Cho, Kyeong-Sik;Jang, Min-Hyeok;Jang, Chul-Woo;Kim, Sang-Mo;Kim, Mi-Young
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.306-312
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    • 2009
  • The size of various alumina ceramics used in semiconductor and display industry is also required to increase with increase in wafer and panel size. In this research, large alumina ceramics was fabricated by filter pressing of alumina slurry using commercial powder and thereafter sintering at $1600^{\circ}C$ in gas furnace. The characteristics of large alumina ceramics thereby were compared to those of small alumina ceramics prepared by pressure forming such as uniaxial pressing and CIP. Careful control of properties of alumina slurry and filter pressing made the fabrication of large alumina ceramics possible, and its characteristics were equivalent to those of small alumina ceramics. The large alumina ceramics, prepared by sintering the green body of 63% relative density at $1600^{\circ}C$, exhibited both dense microstructure corresponding to 98.5% of relative density and 99.8% of high purity as in starting powder.

Characteristics and Modeling Analysis of Entrained Flow Gasifiers (분류층 가스화기 특징 및 공정모사 분석)

  • Yoo, Jeongseok;Kim, Youseok;Paek, Minsu
    • New & Renewable Energy
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    • v.9 no.3
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    • pp.20-28
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    • 2013
  • The gasification process has developed to convert coal into the more useful energy and material since decades. Despite the numberous design of ones, entrained flow gasifier of the major companies has had an advantage on the market. Because it has a merit of full-scale and high performance plant. In this paper, the gasification technologies of GE energy, Phillips, Siemens and Shell have been reviewed to compare their characteristics and a high performance gasification process was suggested. And the simulation model of gasifiers using Aspen Plus offered the quantitative comparison data for difference designs. The simulation results revealed the poor performance of the slurry feed than dry design. The corresponding cold gas efficiency of 77% is much lower than the 80.3% for the dry feed cases. The exergy analysis of the difference syngas quenching system showed that chemical quenching is superior to another. The results of analysis recommend the two stage gasifier with dry multi-feeder as the energy effective design.

Effect of Dietary Protein Levels on Composition of Odorous Compounds and Bacterial Ecology in Pig Manure

  • Cho, Sungback;Hwang, Okhwa;Park, Sungkwon
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.9
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    • pp.1362-1370
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    • 2015
  • This study was performed to investigate the effect of different levels of dietary crude protein (CP) on composition of odorous compounds and bacterial communities in pig manure. A total of 48 male pigs (average initial body weight 45 kg) fed diets containing three levels of dietary CP (20%, 17.5%, and 15%) and their slurry samples were collected from the pits under the floor every week for one month. Changes in composition of odorous compounds and bacterial communities were analyzed by gas chromatography and 454 FLX titanium pyrosequencing systems, respectively. Levels of phenols, indoles, short chain fatty acid and branched chain fatty acid were lowest (p<0.05) in CP 15% group among three CP levels. Relative abundance of Bacteroidetes phylum and bacterial genera including Leuconostoc, Bacillus, Atopostipes, Peptonphilus, Ruminococcaceae_uc, Bacteroides, and Pseudomonas was lower (p<0.05) in CP 15% than in CP 20% group. There was a positive correlation (p<0.05) between odorous compounds and bacterial genera: phenol, indole, iso-butyric acid, and iso-valeric acid with Atopostipes, p-cresol and skatole with Bacteroides, acetic acid and butyric acid with AM982595_g of Porphyromonadaceae family, and propionic acid with Tissierella. Taken together, administration of 15% CP showed less production of odorous compounds than 20% CP group and this result might be associated with the changes in bacterial communities especially whose roles in protein metabolism.

Piggery Slurry Composting Using Batch Operating Autothermal Thermophilic Aerobic Digestion System

  • Ahn, Hee K.;Choi, Hong L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.2
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    • pp.273-279
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    • 2006
  • The performance of an autothermal thermophilic aerobic digestion (ATAD) system was studied to determine if nitrogen loss, as ammonia, was affected by an exhaust gas condenser. The system was run with and without a condenser while treating $8m^3$ of piggery slurry for 8 days. The system with a condenser (SWC) maintained the reactor temperatures above $40^{\circ}C$ for 2 days during the 8 days run, while the system without a condenser (SWOC) remained above $40^{\circ}C$ for 6 days. The SWC maintained the reactor temperatures mostly at mesophilic conditions while the SWOC at thermophilc conditions. Differences in operation conditions for the two runs were mainly caused by differences in atmospheric temperatures. Soluble chemical oxygen demand (SCOD) and volatile solids (VS) removal efficiencies of the SWC (SCOD: 62%, VS: 41%) were higher than those of the SWOC (SCOD: 40%, VS: 20%). The total Kjeldal nitrogen (TKN) removal efficiency of the SWC (7%) was less than that of the SWOC (25%). The concentration of total volatile fatty acids (VFA) in the SWC was observed to be lower than the threshold value of 0.23 g total VFA/L after 6 days, while the SWOC progressed below the threshold value after 3 days. No offensive odor emissions were observed in either run, which suggest that the use of the ATAD system may be a good odor removal strategy.

Status of Anaerobic Digestion Facility for Pig-slurry in Korea (국내 가축분뇨 혐기소화시설 현황 및 운영실태 분석)

  • Jeong, Kwang-Hwa;Kim, Jung-Gon;Han, Duk-Woo;Kwag, Jung-Hun
    • Journal of Animal Environmental Science
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    • v.20 no.1
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    • pp.27-34
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    • 2014
  • This study was conducted to survey and inspect the currently operating anaerobic digestion facilities for animal manure. Recently, the number of anaerobic digestion facility for livestock manure is on the rise thanks to growing interest in developing alternative energy. A anaerobic digestion system has been constructed in large scale farms or animal manure public resource center. Currently, most animal manure anaerobic digestion facilities in operation are producing biogas from the pig slurry which contains 97% water. Methane gas can be used to operate a engine generator which then produces electricity. Anaerobic digestate, a by-product of digestion, is mostly utilized as a liquid fertilizer after curing processing. Only in a few cases, it can be discharged after wastewater treatment process. The problem of anaerobic digestate treatment is the imbalance of C/N ratio. The content of N was too high to keep it into normal process.

Fabrication of Porous Reaction Bonded Silicon Carbide with Multi-Layered Pore Structures (다층 기공구조를 갖는 다공성 반응소결 탄화규소 다공체 제조)

  • Cho, Gyoung-Sun;Kim, Gyu-Mi;Park, Sang-Whan
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.534-539
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    • 2009
  • Reaction Bonded Silicon Carbide(RBSC) has been used for engineering ceramics due to low-temperature fabrication and near-net shape products with excellent structural properties such as thermal shock resistance, corrosion resistance and mechanical strength. Recently, attempts have been made to develop hot gas filter with gradient pore structure by RBSC to overcome weakness of commercial clay-bonded SiC filter such as low fracture toughness and low reliability. In this study a fabrication process of porous RBSC with multi-layer pore structure with gradient pore size was developed. The support layer of the RBSC with multi-layer pore structure was fabricated by conventional Si infiltration process. The intermediate and filter layers consisted of phenolic resin and fine SiC powder were prepared by dip-coating of the support RBSC in slurry of SiC and phenol resin. The temperature of $1550^{\circ}C$ to make Si left in RBSC support layer infiltrate into dip-coated layer to produce SiC by reacting with pyro-carbon from phenol resin.

Synthesis of Ultrafine TiC-5%Co Powder by Using Co Nitrate and TiO(OH)2 Slurry and Evaluation of Sintered Materials Prepared by Mixing WC-Co (Co 질산염과 TiO(OH)2 슬러리를 이용한 초미립 TiC-5%Co 제조 및 WC-Co 분말과의 혼합에 따른 소결체 특성)

  • Hong, Seong-Hyeon;Kim, Byoung-Kee
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.107-113
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    • 2008
  • Ultrafine TiC-5%Co powders were synthesized by spray drying of aqueous solution of TiO$(OH)_2$ slurry and cobalt nitrate, followed by calcination and carbothermal reaction. The oxide powders with carbon powder was reduced and carburized at $900^{\circ}C{\sim}1250^{\circ}C$ under hydrogen atmosphere. During reduction, CO gas was mainly evolved by reducing reaction of oxides. Ultrafine TiC-5%Co powders were easily formed by carbothermal reaction at $1250^{\circ}C$ due to using ultrafine powders as raw materials. The ultrafine WC-TiC-Co alloy prepared by sintering of mixed powder of ultrafine WC-13%Co powder and ultrafine TiC-5%Co powder has higher sintered density and mechanical properties than WC-TiC-Co alloy prepared by commercial WC, TiC and Co powders.

A Mechanism Study on Formation and Reduction of Residual Li of High Nickel Cathode for Lithium-ion Batteries (층상계 하이니켈 양극재의 잔류 리튬 생성 및 저감 메커니즘 연구)

  • MinWook, Pin;Beom Tak, Na;Tae Eun, Hong;Youngjin, Kim
    • Journal of Industrial Technology
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    • v.42 no.1
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    • pp.7-12
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    • 2022
  • High nickel layered oxide cathodes are gaining increasing attention for lithium-ion batteries due to their higher energy density and lower cost compared to LiCoO2. However, they suffer from the formation of residual lithium on the surface in the form of LiOH and Li2CO3 on exposure to ambient air. The residual lithium causes notorious issues, such as slurry gelation during electrode preparation and gas evolution during cell cycling. In this review, we investigate the residual lithium issues through its impact on cathode slurry instability based on deformed polyvinylidene fluoride (PVdF) as well as its formation and reduction mechanism in terms of inherently off-stoichiometric synthesis of high nickel cathodes. Additionally, new analysis method with anhydrous methanol was introduced to exclude Li+/H+ exchange effect during sample preparation with distilled water. We hope that this review would contribute to encouraging the academic efforts to consider practical aspects and mitigation in global high-energy-density lithium-ion battery manufacturers.

Fabrication and Characteristics of Anode-Supported Tubular Solid Oxide Fuel Cell (연료극 지지체식 원통형 고체산화물 연료전지의 제조 및 특성연구)

  • Kim, Eung-Yong;Song, Rak-Hyun;Shin, Dong-Ryul;Lim, Y.E.
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1547-1549
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    • 1999
  • As a preliminary experiment for the development of anode-supported tubular cell with proper porosity, we have investigated the anode substrate and the electrolyte-coated anode tube. The anode substrate was manufactured as a function of carbon content in the range of 20 to 50 vol.%. As the caron content increased, the porosity of the anode substrate increased slightly and the carbon content with proper porosity was obtained at 30 vol.%. The anode tube was fabricated by extrusion process and the electrolyte layer was coated on the anode tube by slurry dipping process. The anode-supported tube was cofired successfully. Their sintered property and microstructure were examined and the porosity of the anode tube was 35%. From the gas permeation test, the anode tube was found to be porous enough for gas supply. On the other hand, the anode-supported tube with electrolyte layer indicated a very low gas permeation rate. This means that the coated electrolyte was dense. Based upon these experimental results. we will fabricate and test the anode-supported tubular cell.

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