• 제목/요약/키워드: gas cross-over

검색결과 95건 처리시간 0.021초

MCS-BEq 알고리즘에 의한 $SiH_4$ 기체의 전자수송특성 (Characteristics of Electron Transport in $SiH_4$ Gas used by MCS-BEq Algorithm)

  • 김상남;성낙진
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 학술대회 논문집 전문대학교육위원
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    • pp.159-162
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    • 2006
  • In this paper energy distribution function in $SiH_4$ has been analysed over the E/N range 0.5${\sim}$300Td and Pressure value 0.5, 1.0, 2.5 Torr by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, diffusion coefficient, electron ionization, mean energy and the electron energy distribution function. The electron energy distribution function has been analysed in $SiH_4$ at E/N=30, 50Td for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values.

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$SiH_4$ 가스의 에너지 분포함수 관한 연구 (Analysis of Energy Distribution Function in $SiH_4$ Gas)

  • 성낙진;김상남
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 학술대회 논문집 전문대학교육위원
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    • pp.76-79
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    • 2001
  • Energy distribution function in $SiH_4$ has been analysed over the E/N range $0.5{\sim}300Td$ and Pressure value 0.5, 1.0, 2.5 Torr by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, diffusion coefficient, electron ionization, mean energy and the electron energy distribution function. The electron energy distribution function has been analysed in $SiH_4$ at E/N=30, 50Td for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections.

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Theoretical Studies on Phenyl Group Rearrangement of Protonated Ketones

  • 김창곤;이진각;박형연;이익춘
    • Bulletin of the Korean Chemical Society
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    • 제18권6호
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    • pp.657-662
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    • 1997
  • Gas-phase phenyl group migration within the protonated ketones has been studied MO theoretically using the AM1 method. The initial state structure shows relatively strong resonance delocalization of positive charge into the nonmigrating (Y) ring, while the ring migration (Z-ring) is nearly complete in the transition state. These results are reflected in the large $p^+_Z$ (<0) and $p^+_$Y (>0) values and in the predominant contribution of resonance (r) over inductive (field, f) effect, r/f ranging from 1.3 ($p^+_r$) to 1.5 ($p^+_z$). The cross-interaction constant $p_{YZ}$ is vanishingly small ($p_{YZ}$=0.03) which is in contrast to the larger magnitudes for benzilic ($p_{YZ}$=-0.48) and azibenzil ($p_{YZ}$=-0.53) rearrangement processes. The relationship found between the extent of resonance contribution in the initial state and the magnitude of $p_{YZ}$ provides strong support for the proportionality between the magnitude of $p_{YZ}$ and the change in the intensity of interaction, ${\Delta}I^{\cdot}_{YZ}$, in the activation process.

Simulating the Lyman-Alpha Forest with Massive Neutrinos and Dark Radiation for Large-Volume Surveys

  • Rossi, Graziano
    • 천문학회보
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    • 제44권1호
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    • pp.57.1-57.1
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    • 2019
  • In support of current and upcoming large-volume cosmological surveys such as the SDSS-IV eBOSS, LSST, and DESI, we present an extensive suite of high-resolution cosmological hydrodynamical simulations spanning a large range of cosmological and astrophysical parameters. We follow the evolution of gas, dark matter, neutrinos, and dark radiation, and consider several combinations of box sizes and number of particles - enhancing the resolution up to $3{\times}33283=110$ billion particles in a (100 h-1 Mpc)3 box size. We also provide 100,000 skewers for a variety of redshift slices and combination of cosmological and astrophysical parameters, useful for interpreting upcoming high-quality $Lyman-{\alpha}$ forest data. These novel simulations represent an improvement over our previous runs, and can be useful for a broader variety of cosmological and astrophysical applications, ranging from the three-dimensional modeling of the $Lyman-{\alpha}$ forest to cross-correlations between different probes, for studying the expansion history of the Universe including massive neutrinos, and for particle-physics related topics.

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실록산계 고분자 막을 통한 올레핀/질소 기체 투과 거동 (Permeation Behavior of Olefin/Nitrogen Gases through Siloxane based Polymeric Membranes)

  • 이수복;신효진;최승학;김정훈;박인준;노재성;강득주
    • 멤브레인
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    • 제13권4호
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    • pp.246-256
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    • 2003
  • 폴리올레핀 산업에서 발생되는 올레핀 함유 배 가스(off-gas)에서 올레핀만을 선택적으로 분리하기 위해, 폴리디메틸실록산(Polydimethylsiloxane)계열의 막 소재들에 대한 올레핀과 질소의 투과특성을 연구하였다. 막 소재로는 가교 형태의 폴리디메틸실록산(Polydimethylsiloxane, 이하 PDMS라 칭함)막, 폴리실록산이미드(Polysiloxaneimide, 이하 PSI라 칭함)막, 아크릴변성 Oligo-PDMS가 부가된 Oligo-PDMS막들을 대상으로 공급기체의 온도($-20{\sim}50^{\circ}C$)와 압력(1∼25 atm)을 변화시키면서 에틸렌($C_2H_4$), 프로필렌($C_3H_6$), 부틸렌($C_4H_8$), 질소($N_2$) 기체의 단일투과특성을 조사하였다. 실험결과, 사용되는 막소재의 특징에 따라 다양한 투과특성을 보였다. 세 가지 막소재중에서 PDMS막이 가장 넓은 사용압력범위에서 높은 에틸렌투과도 및 에틸렌/질소의 분리특성을 보였으며 이 막을 대상으로 여러 투과조건에서 투과특성을 연구하였다. 선택된 가교 PDMS막을 통한 올레핀, 질소 기체들의 투과도는 투과기체의 분자크기(확산도 선택성)보다, 투과기체의 응축온도(용해도 선택성)에 좌우되는 경향을 보였다. 공급기체의 온도가 감소하거나 압력이 증가할 때, 응축성 기체인 올레핀 기체의 투과도는 증가하고, 비응축성 기체인 질소는 감소하는 특징을 보였으며 이에 따라 올레핀/질소의 선택도가 크게 증가하는 특징을 보였다. 이러한 결과들은 고무상 고분자막에서 보여지는 응축성, 비응축성 기체들의 전형적인 투과특성을 보여준다.

Growth of superconducting $MgB_2$ fibers for wire applications

  • Kim J. H.;Yoon H. R.;Jo W.
    • 한국초전도ㆍ저온공학회논문지
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    • 제7권4호
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    • pp.1-3
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    • 2005
  • Superconducting $MgB_2$ fibers are in-situ grown by a diffusion method. The fibers are prepared by exposing B filaments to Mg vapor inside a folded Ta foil over a wide range of temperature and growth time. The materials are sealed inside a quartz tube by gas welding. The as - grown fibers are characterized by scanning electron microscopy and energy dispersive x - ray analysis. The fibers have a diameter of about $110{\mu}m$. Surface morphology of the fibers looks dependent on growth temperature and mixing ratio of Mg and B. Radial distribution of Mg ions into B is observed and analyzed over the cross - sectional area. Transport properties of the $MgB_2$ fibers are examined by a physical property measurement system. The $MgB_2$ fibers grown at $900^{\circ}C$ for 2 hours show a superconducting transition at 39.8K with ${\Delta}T_c<$ 2.0 K. Resistance at room temperature $MgB_2$ is 3.745 $\Omega$ and residual resistivity ratio (RRR) is estimated as 4.723.

SEM 단면 시료 제작을 위한 플라즈마 이온원의 구조 (Structure of a Plasma Ion Source for a Cross-Section SEM Sample)

  • 원종한;장동영;박만진
    • 한국생산제조학회지
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    • 제24권4호
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    • pp.400-406
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    • 2015
  • This study researched the structure of the source of an ion milling machine used to fabricate a scanning electron microscope (SEM) sample. An ion source is used to mill out samples of over 1 mm dimension using a broad ion beam to generate plasma between the anode and cathode using a permanent magnet. To mill the sample in the vacuum chamber, the ion source should be greater than 6 kV for a positive ion current over $200{\mu}A$. To discover the optimum operating conditions for the ion miller, the diameter of the extractor, anode shape, and strength of the permanent magnet were varied in the experiments. A silicon wafer was used as the sample. The sputter yield was measured on the milled surface, which was analyzed using the SEM. The wafer was milled by injecting 1 sccm of argon gas into the 0.5 mTorr vacuum chamber.

시추공간 전기비저항 토모그래피를 이용한 $CO_2$ 주입 모니터링 (Monitoring $CO_2$ injection with cross-hole electrical resistivity tomography)

  • Christensen, N.B.;Sherlock, D.;Dodds, K.
    • 지구물리와물리탐사
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    • 제9권1호
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    • pp.44-49
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    • 2006
  • 이 연구에서는 $CO_2$ 주입 모니터링에서의 전기비저항 토모그래피(ERT)의 분해능에 대해 조사한다. $CO_2$ 주입체 양쪽의 케이싱 없는 시추공에서 단극자 및 양극자 전극 배열이 사용된다. 주입 전 및 주입에 따른 3단계 모델에 대한 반응이 계산되고, 잡음이 더해진 후의 이론 값들이 L1 과 L2 norm을 사용해 역산된다. 역산결과는 어느 정도 수준이상의 $CO_2$ 부피가 확실히 감지됨을 보여준다. 대부분의 경우에 L1 norm의 경우가 L2에 비해 우월함이 판명되었다. 역산 결과를 주입 전 모델의 역산결과로 정규화하면 전기비저항이 변화하는 부분의 훌륭한 영상을 보여주며, 비저항의 전체적인 변화를 통합해서 판단하면 전체 주입된 부피에 대한 타당한 측정이 이루어짐이 입증된다.

수소용 다이어프램 압축기의 오일 분배 홀 패턴에 따른 수치해석 (Numerical Analysis on a Hydrogen Diaphragm Compressor with Various Oil Distribution Holes Pattern for Hydrogen Compressor)

  • 박현우;신영일;김규보;송주헌;장영준;전충환
    • 한국수소및신에너지학회논문집
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    • 제20권2호
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    • pp.87-94
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    • 2009
  • There are several types of compressors which are appropriate for hydrogen gas station. Diaphragm type of compressor is the one of them and it satisfies the requirements for that purpose in terms of maintaining gas purity and making high pressure over 700 bar. The objective of this study is to find an optimal design of oil distribution hole configuration. The number of holes is changed maintaining total cross-sectional area of holes. Five cases(1 hole, 4, 8,16 and 24 holes) were studied through Fluid Structure Interaction(FSI) analysis method. Gas and oil pressure, the deflection and stress of the diaphragm were analysed during compression and suction process respectively. There is no specific difference among the cases during compression. An additional deflection due to the existence of hole was found during suction for all case. But the highest deflection and stress were found in the 1 hole case. It was seen that 60% decrease of stress in magnitude in 24 hole case compare to the 1 hole case.

The Flow Instability Over the Infinite Rotating Disk

  • Lee, Yun-Yong;Hwang, Young-Kyu;Lee, Kwang-Won
    • Journal of Mechanical Science and Technology
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    • 제17권9호
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    • pp.1388-1396
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    • 2003
  • The hydrodynamic instability of the three-dimensional boundary layer on a rotating disk introduces a periodic modulation of the mean flow in the form of stationary cross flow vortices. The instability labeled Type II by Faller occurs first at lower Reynolds number than that of well known Type I instability. Detailed numerical values of the amplification rates, neutral curves and other characteristics of the two instabilities have been calculated over a wide range of parameters. Presented are the neutral stability results concerning the two instability modes by solving the appropriate linear stability equations reformulated not only by considering whole convective terms but also by correcting some errors in the previous stability equations. The present stability results agree with the previously known ones within reasonable limit. Consequently, the flow is found to be always stable for a disturbance whose dimensionless wave number is greater than 0.75. Some spatial amplification contours have been computed for the stationary disturbance wave, whose azimuth angle $\varepsilon$= 11.29$^{\circ}$ to 15$^{\circ}$ and for the moving disturbance wave, whose azimuth angle $\varepsilon$ = 12.5$^{\circ}$ to 15$^{\circ}$. Also, some temporal amplification contours have been computed for the stationary disturbance wave, whose azimuth angle $\varepsilon$= 11.29$^{\circ}$ to 15$^{\circ}$ and for the moving disturbance wave, whose azimuth angle $\varepsilon$= 12$^{\circ}$ to 15$^{\circ}$. The flow instability was observed by using a white titanium tetrachloride gas over rotating disk system. When the numerical results are compared to the present experimental data, the numerical results agree quantitatively, indicating the existence of the selective frequency mechanism.