• 한국환경과학회지
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• 제11권7호
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• pp.749-755
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• 2002

The effects of noble gas (such as helium, neon, argon, krypton, and xenon) on the sonolytic decomposition of water and 2-methyl-2-propanol(t-butanol) with 200 KHz high power ultrasound were investigated. The physical properties of the noble gas have an effect on the formation rate of products $(H_2O_2,\;H_2,\;O_2)$ and the decomposition rate on the sonolytic decomposition of water. The pyrolysis products, such as methane, ethane, ethylene, and acetylene are formed during the sonolytic decomposition of t-butanol. From the estimation of the ratio $[C_2H_4+C_2H_2] / [C_2H_6]$, the cavitation temperature would be varied by the used noble gas. In all cases for the sonolytic decomposition of water, t-butanol, and diethyl phthalate, the decomposition rates were xenon > krypton > argon > neon > helium with a significant difference and were closely correlated with the formation rate of OH radical and high temperature inside the cavitation bubble under each noble gas.

• 전기의세계
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• 제29권8호
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• pp.532-537
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• 1980

Effect of Argon and Sulfur hexafloride in the transformer oil are experimented under non-uniform A.C. electric field. The result has shown that the corona frequency and corona charge quantity in liquid dielectrics were varied with gas condition in the oil and affected by the additives. SF$_{6}$ that has the effects of pressure and electrical negative characteristic is the most effective. The corona is considered to be the breakdown of bubble produced by gas contained in the oil or by dissociated ion of the oil molecules.s.

• 한국세라믹학회지
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• 제25권1호
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• pp.78-82
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• 1988

Good quality LiNbO3 single crystals which can be applied to SAW devices, were grown by Czochralski method. It was observed that the gas-bubbles were concentrated in ring shape at the outer part of grown crystals, and this anomaly was illustrated by modeling the mechanism of gas-bubble entrapment according to the melt flow pattern in the crucible. And this mechanism was also encertained by observation of solid-liquid interface shape of grown crystals. The optimal condition for good quality crystals was known that the solid-liquid interface shape was slightly concave.

• 한국막학회:학술대회논문집
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• 한국막학회 1991년도 추계 총회 및 학술발표회
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• pp.4-8
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• 1991

The characterization of pore properties (mean pore size and pore size distribution) of the active layer in a UF membrane is important not only in order to obtain information about the factors affecting pore formation during membrane manufacturing but also to understand deeply the mechanism of solute and solvent transport through pores. Many methods of characterizing quantitatively the pore properties of UF membranes have been suggested in the literature: solvent and gas flow measurement, bubble point determination, electron microscopy, gas adsorption/desorption measurement, rejection measurement etc. But most of these methods involve time-consuming procedures and involve some wellknown problems and uncertainties.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.16-16
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• 2011

Plasmas in saline solutions receive considerable attention in recent years. How the operating parameters influence the plasma characteristics and how the electrode erosion occurs have been topics that require further study. In the first part of this talk, the effect of the frequency on the plasmas characteristics in saline solution driven by 50~1000 Hz AC power will be presented. Two distinct modes, namely bubble and jetting modes, are identified. The bubble mode occurs under low frequencies. In this mode, one mm-sized bubble is tightly attached to the electrode tip and oscillates with the applied voltage. With an increase in the frequency, it shows the jetting mode, in which many smaller bubbles are continuous formed and jetted away from the electrode surface. Multiple mechanisms that are potentially responsible to such a change in bubble dynamics have been proposed and the dominant mechanism is identified. From the Stark broadening of the hydrogen optical emission line, electron densities in both modes are estimated. It shows clearly that the driving frequency greatly influences the bubble dynamics, which in turn alters the plasma behavior. In the second part, the study of the erosion of a tungsten electrode immersed in saline solution under conditions suitable for bio-medical applications is presented. The electrode is immersed in 0.1 M saline solution and is positively or negatively biased using a DC power source up to 600 V. It is identified that when the electrode is positively biased, erosion by the surface electrolytic oxidation is the dominant mechanism with an applied voltage below 150 V. An increase in the applied voltage leads to the formation of the plasma and the damage by the plasma and the thermal effect becomes more prominent. The formation of the gas film at the electrode surface leads to the formation of the plasma and hinders the electrolytic erosion. In the negatively-biased electrode, no electrolytic oxidation is seen and the damage is mostly likely due to the plasma erosion and the thermal effect.

• KSBB Journal
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• 제5권1호
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• pp.59-67
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• 1990

생성물의 분리 및 효소의 회수를 위하여 수평흐름 한외여과장치를 부착한 기포탑에서 섬유소의 연속적인 효소 가수분해 반응을 연구하였다. 기포탑을 효소 가수분해 반응 공정에 이용할 경우 기체유속의 범위는 1-3cm / sec로 기포의 합체현상이 발생하지 않는 dispersed bubble flow 영역이 적합하며 혼합도 거의 완전하게 이루어짐을 확인하였다. 효소 회수장치에 한계분자량이 $10^4$인 여과막을 사용하였을 경우 효소의 활성이 저하되지 않은 채 대부분이 회수되었고 glucose 및 cellobiose의 배제율은 0이었다. 따라서 수평흐름 한외 여과장치는 효소의 연속회수장치로 작합하였으며 반응생성물이 연속적인 분리로 섬유소의 당화율을 증가시켰다. 화분식 반응의 경우 반응시간이 8시간이내에서 실험치는 성능식에 잘 부합되었으나 반연속식 및 연속식 반응의 경우에는 이론값과 차이가 있었다. 이는 반응기 내에서의 효소의 변성에 기인된다. 반연속식 및 연속식 반응의 경우 희석율을 증가시킴에 따라 전환율은 증가하나 반응액중의 환원당의 농도는 낮아진다. 따라서 적정한 기질 공급속도 및 희석율은 효소의 회수비용, 생성물의 농축비용 및 기질의 공급비용등의 경제적 요소를 고려하여 판단하여야 한다. 이상의 결과로부터 수평흐름 한외여과장치를 효소 회수장치로 기포탑에 응용할 경우, 효소의 재사용이 가능할 뿐 아니라 당화율을 증가시킴으로서 연속반응기로 효과적이라고 판단되었다.

• Korean Chemical Engineering Research
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• 제47권4호
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• pp.459-464
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• 2009

가압 삼상슬러리 기포탑에서 탑의 직경변화에 따라 기체-액체 물질전달 특성을 고찰하였다. 기체 유속, 운전압력, 액체점도, 슬러리상에서 고체입자의 양 그리고 탑의 직경이 기체-액체 부피물질전달계수에 미치는 영향을 결정하였다. 운전변수들이 물질전달계수에 미치는 영향은 기포탑의 직경이 변화함에 따라 다르게 나타났다. 기체-액체 부피물질전달계수는 기체유속이나 운전압력이 증가함에 따라 증가하였으나, 기포탑의 직경, 액체의 점도 그리고 슬러리상에 고체입자의 농도가 증가함에 따라 감소하였다. 기체-액체 물질전달계수가 기체유속 증가에 따라 증가하는 경향과 액체의 점도가 증가함에 따라 감소하는 경향은 기포탑의 직경이 증가함에 따라 점차 감소하였다. 그러나, 운전압력과 슬러리상에 포함된 고체입자의 농도가 기체-액체 물질전달계수에 미치는 영향은 기포탑의 직경이 변화함에 따라 큰 영향을 받지 않았다. 본 연구의 실험범위에서 기체-액체 물질전달계수는 다음 식과 같은 실험변수의 상관식으로 나타낼 수 있었다. $k_La=0.02D^{-0.26}U_G^{0.28}P^{0.43}{\mu}_L^{-0.04}S_c^{-0.35}$.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2008년도 12th Asian Congress of Fluid Mechanics
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• pp.45.1-45.1
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• 2008

• Preventive Nutrition and Food Science
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• 제1권2호
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• pp.179-185
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• 1996

Extraction yields of thiosulfinates from garlic were studied by using gas-in-liquis-dispersion(GLD) system to maxmize the thiosulfinate extraction. Extracted thiosulfinates were spectrophotometically quantified using synthesized dially1 thiosulfinate. The conditions for maximum extraction were optimized by response surface methodology. The volatile components extracted by various methods, such as hexane extraction, simultaneous steam distillation and GLD system, were compared by using gas chromatography. The results indicated that the thiosulfinate yield was increased by incresaing temperature and nitrogen gas flow rate, while the effects of bubble sizes on thiosulfinate extraction were not significant at the ranges tested. Application of GLD system resulted in extraction of more volatile components than other extraction methods, Therfore, it was suggested that GLD system was one of the efficient extraction methods among the ever introduced ones, for thiosulfinate extraciton.

• 한국환경과학회지
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• 제1권2호
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• pp.105.1-113
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• 1992

The present study was performed to develop the removal system of the offensive gases, including hydrogen sulfide of acid gas, ammonia or amice of base gas, from the nightsoil treatment plant. In order to remove the offensive gases, the Fe-EDTA system liquid phase catalytic oxidation method with the bubble lift column reactor was employed. From the results obtained, it was confirmed that the offensive gases can be deodorized simultaneously and also hydrogen sulfide of acid gas, ammonia of base gas completely removed at pH 6.45. In addition, as input gases feed rate the efficiency of acid gas did not change but the efficiency of base gases decreased to approximately 90 % at pH 6, 0. From the result of particle size analyzer, it was found that the particle sizes including sulfur and other impurites grew up to $21{\mu}m$ over 72hour reaction time.