• Title/Summary/Keyword: gas and water exchange

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A SURVEY OF THE DEVELOPMENT OF MEMBRANE SCIENCE AND TECHNOLOGY IN CHINA

  • Congjie, Gao
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.12-12
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    • 2004
  • A brief introduction was given in this paper for the research and development on membrane science and technology in China. Ion exchange membranes and electrodialysis, MF, UF, NF and RO membranes, gas separation (GS) membranes, pervaporation (PV), membranes, inorganic membranes (IM) and membrane reactors (MR) were involved.(omitted)

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Numerical Simulation of Water Transport in a Gas Diffusion Layer with Microchannels in PEMFC (마이크로채널이 적용된 고분자 전해질 연료전지 가스확산층의 물 이송에 대한 전산해석 연구)

  • Woo, Ahyoung;Cha, Dowon;Kim, Bosung;Kim, Yongchan
    • Journal of the Korean Electrochemical Society
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    • v.16 no.1
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    • pp.39-45
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    • 2013
  • The water management is one of the key issues in low operating temperature proton exchange membrane fuel cells (PEMFCs). The gas diffusion layer (GDL) allows the reactant gases flow to the reaction sites of the catalyst layer (CL). At high current density, generated water forms droplets because the normal operating temperature is $60{\sim}80^{\circ}C$. If liquid water is not evacuated properly, the pores in the GDL will be blocked and the performance will be reduced severely. In this study, the microchannel GDL was proposed to solve the flooding problem. The liquid water transport through 3-D constructed conventional GDL and microchannel GDL was analyzed varying air velocity, water velocity, and contact angle. The simulation results showed that the liquid water was evacuated rapidly through the microchannel GDL because of the lower flow resistance. Therefore, the microchannel GDL was efficient to remove liquid water in the GDL and gas channels.

Experimental Studies on the Performance of a Transcritical Cycle for Hot Water Heating Using Carbon Dioxide (이산화탄소를 이용한 온수급탕용 초월임계사이클의 성능에 대한 실험적 연구)

  • 김성구;김민수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.6
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    • pp.461-470
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    • 2003
  • The purpose of this study is to investigate the performance of a transcritical cycle for hot water heating using $CO_2$ as a working fluid. Some of the main parameters that affect the practical performance of the $CO_2$ system are discussed; the performance on the variation of refrigerant charge, changes in flow conditions of secondary fluids, and that with or without internal heat exchanger, The experimental results show that the optimum charge is approximately the same for various mass flow rates of the secondary fluid at gas cooler. The experimental results on the effect of secondary fluids are in general agreement with the experimental results of transcritical cycle in the open literature and show similar trend for conventional subcritical vapor compression cycles. The heat exchanger effectiveness increases with an increase of the heat exchange area of the internal heat exchanger regardless of the mass flow rate at the gas cooler.

Development of Relief Valves for the Domestic Gas-fired Hot Water Boilers (가정용 가스보일러 과압방지밸브의 개발 연구)

  • Kim Young Gyu;Kwon Jeong Rock;Kim Ji Yoon;Suh Joon Suk
    • Journal of the Korean Institute of Gas
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    • v.4 no.1 s.9
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    • pp.63-68
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    • 2000
  • We have developed a new relief valve which is a safety device for the domestic gas-fired hot water boilers. The relief valve has been designed to expand the inner diameter of the inlet, the outlet and the seat of the valve considering the relief capacity, and also to separate the spring from the room heating water. Therefore, we could minimize the adhesion and/or obstruction of the inlet and the corrosion phenomena of the spring which used to be the problem of the conventional relief valves. Test results of the developed relief valve showed that the performance of the opening pressure, reseating pressure, tightness, endurance were excellent, and the operating boiler with developed relief valve was evaluated as very good. The standardization and application of the relief valve can provide the advantage of component exchange and easy maintenance and repair.

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Study of Development of Selective Removal Adsorption Ion Exchange Resin Materials for Fabricated with Chemical-biological Cloth by QFD (QFD 기법을 이용한 특정 유해가스 노출제어 이온선택성 보호복 소재개발연구)

  • Song, Hwa Seon;Koo, Il Seob;Kim, In Sik
    • Journal of Korean Society for Quality Management
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    • v.43 no.3
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    • pp.359-372
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    • 2015
  • Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

Removal of Flooding in a PEM Fuel Cell at Cathode by Flexural Wave

  • Byun, Sun-Joon;Kwak, Dong-Kurl
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.104-114
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    • 2019
  • Energy is an essential driving force for modern society. In particular, electricity has become the standard source of power for almost every aspect of life. Electric power runs lights, televisions, cell phones, laptops, etc. However, it has become apparent that the current methods of producing this most valuable commodity combustion of fossil fuels are of limited supply and has become detrimental for the Earth's environment. It is also self-evident, given the fact that these resources are non-renewable, that these sources of energy will eventually run out. One of the most promising alternatives to the burning of fossil fuel in the production of electric power is the proton exchange membrane (PEM) fuel cell. The PEM fuel cell is environmentally friendly and achieves much higher efficiencies than a combustion engine. Water management is an important issue of PEM fuel cell operation. Water is the product of the electrochemical reactions inside fuel cell. If liquid water accumulation becomes excessive in a fuel cell, water columns will clog the gas flow channel. This condition is referred to as flooding. A number of researchers have examined the water removal methods in order to improve the performance. In this paper, a new water removal method that investigates the use of vibro-acoustic methods is presented. Piezo-actuators are devices to generate the flexural wave and are attached at end of a cathode bipolar plate. The "flexural wave" is used to impart energy to resting droplets and thus cause movement of the droplets in the direction of the traveling wave.

Characterizing Spatiotemporal Variations and Mass Balance of CO2 in a Stratified Reservoir using CE-QUAL-W2 (CE-QUAL-W2를 이용한 성층 저수지에서 CO2의 시공간적 분포 및 물질수지 분석)

  • Park, Hyungseok;Chung, Sewoong
    • Journal of Korean Society on Water Environment
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    • v.36 no.6
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    • pp.508-520
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    • 2020
  • Dam reservoirs have been reported to contribute significantly to global carbon emissions, but unlike natural lakes, there is considerable uncertainty in calculating carbon emissions due to the complex of emission pathways. In particular, the method of calculating carbon dioxide (CO2) net atmospheric flux (NAF) based on a simple gas exchange theory from sporadic data has limitations in explaining the spatiotemporal variations in the CO2 flux in stratified reservoirs. This study was aimed to analyze the spatial and temporal CO2 distribution and mass balance in Daecheong Reservoir, located in the mid-latitude monsoon climate zone, by applying a two-dimensional hydrodynamic and water quality model (CE-QUAL-W2). Simulation results showed that the Daecheong Reservoir is a heterotrophic system in which CO2 is supersaturated as a whole and releases CO2 to the atmosphere. Spatially, CO2 emissions were greater in the lacustrine zone than in the riverine and transition zones. In terms of time, CO2 emissions changed dynamically according to the temporal stratification structure of the reservoir and temporal variations of algae biomass. CO2 emissions were greater at night than during the day and were seasonally greatest in winter. The CO2 NAF calculated by the CE-QUAL-W2 model and the gas exchange theory showed a similar range, but there was a difference in the point of occurrence of the peak value. The findings provide useful information to improve the quantification of CO2 emissions from reservoirs. In order to reduce the uncertainty in the estimation of reservoir carbon emissions, more precise monitoring in time and space is required.

Prediction of Fuel Cell Performance and Water Content in the Membrane of a Proton Exchange Membrane Fuel Cell (고분자 전해질 연료전지의 전해질 막내의 함수율과 성능 예측)

  • Yang, Jang-Sik;Choi, Gyung-Min;Kim, Duck-Jool
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.6
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    • pp.151-159
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    • 2006
  • A one-dimensional numerical analysis is carried out to investigate the effects of inlet gas humidities, inlet gas pressures, and thicknesses of membrane on the performance of a proton exchange membrane fuel cell. It is found that the relative humidity of inlet gases at anode and cathode sides has a significant effect on the fuel cell performance. Especially, the desirable fuel cell performance occurs at low relative humidity of the cathode side and at high humidity of the anode side. In addition, an increase in the pressure ranging from 1 atm to 4 atm at the cathode side results in a significant improvement in the fuel cell performance due to the convection effect by a pressure gradient toward the anode side, and with decreasing the thickness of membrane, the fuel cell performance is enhanced reasonably.

OXYGEN CONCENTRATION IN THE CATHODE CHANNEL OF PEM FUEL CELL USING GAS CHROMATOGRAPH

  • Ha, T.H.;Kim, H.S.;Min, K.D.
    • International Journal of Automotive Technology
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    • v.8 no.1
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    • pp.119-126
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    • 2007
  • Because of the low temperature operation, proton exchange membrane (PEM) fuel cell has a water phase transition. Therefore, water management is an important operation issue in a PEM fuel cell because the liquid water in the fuel cell causes electrode flooding that can lower the cell performance under high current density conditions. In this study, in order to understand the reactant distributions in the cathode channels of the PEM fuel cell, an experimental technique that can measure the species concentrations of reactant gases by using gas chromatograph (GC) is applied for an operating PEM fuel cell. The oxygen distribution along the cathode flow channels of PEM fuel cell is mainly investigated with various operating conditions. Also, the relations between cathode flooding and oxygen concentrations and oxygen consumption pattern along the cathode channel configurations of the unit cell adopted for this study are discussed using GC measurement and visualization experiment of cathode flooding. It is found that the amount of oxygen consumption is very sensitive to various operating conditions of the fuel cell and was much affected by the flooding occurrence in cathode channels.

Characteristics of Evaporation Heat Transfer in a Small-Scale Cryogenic Heat Exchange System for the Utilization of LNG Cold Energy (LNG 냉열활용을 위한 초저온 열교환시스템의 축소모형에서 증발 열전달 특성)

  • Nam S. C.;Lee S. C.;Lee Y. W.;Sohn Y. S.
    • Journal of the Korean Institute of Gas
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    • v.2 no.4
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    • pp.25-33
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    • 1998
  • The characteristics of evaporation heat transfer for the utilization of LNG cold energy was investigated experimentally using liquified nitrogen and a solution of ethylene-glycol and water under horizontal two-phase conditions in the small-scale equipment of a cryogenic heat exchange system. The inner tubes in the double pipe heat exchanger with 8 mm and 15 mm inner diameter and 6 m length were adopted as a smooth test tubes and enhanced tubes by means of wire-coil inserts. Heat transfer coefficients and Nusselt number for the test tube were calculated from measurements of temperatures, flowrates and pressures. The correlations in a power-law relationship of the Nusselt number, the Reynolds number and Prandtl number for heat transfer were proposed which can be available for design of cryogenic heat exchangers. The correlations showed heat transfer coefficients for the wire-coil inserts were much higher than those for the smooth tubes, increased by more than 2.5 ${\~}$ 5.5 times depending upon the equivalent Reynolds number. Form and length of cryogenic double pipe heat exchanger were proposed for applicable to the utilization of LNG cold energy.

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