• Bulletin of the Korean Chemical Society
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• 제34권8호
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• pp.2399-2402
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• 2013

The catalytic pyrolysis of cellulose was carried out over SAPO-11 for the first time. Pyrolyzer-gas chromatography/mass spectroscopy was used for the in-situ analysis of the pyrolysis products. The acid sites of SAPO-11 converted most levoglucosan produced from the non-catalytic pyrolysis of cellulose to furans. In particular, the selectivity toward light furans, such as furfural, furan and 2-methyl furan, was high. When the catalyst/cellulose ratio was increased from 1/1 to 3/1 and 5/1, the increase in the quantity of acid sites led to the promotion of deoxygenation and the resultant increase of the contents of light furan compounds. Because furans can be used as basic feedstock materials, the augmentation of the economical value of bio-oil through the catalytic upgrading over SAPO-11 is considerable.

• Bulletin of the Korean Chemical Society
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• 제25권11호
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• pp.1635-1640
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• 2004

The cyclophanes 1a-d containing two benzo[b]furan rings connected by various bridges have been prepared and their binding behaviors with N-benzylphenethylammonium cation 2 were examined by NMR titration method. The successive alkylation reactions of 4-hydroxyl groups and then 2-hydroxyl groups of 2,4-dihydroxybenzophenonse gave macrocycles 5a-c. Photoirradiation of the macrocycles 5a-c with 350 nm mercury lamp followed by dehydration afforded the cyclophanes 1a-c. Hydrolysis of two ester groups pendant on a bridge of 1b produced the carboxyl group-containing cyclophane 1d. The cyclophane 1a having a p-xylene bridge showed 1 : 1 binding with 2 with the binding constant of $36{\pm}6M^{-1}$ in 3 : 1 $CDCl_3$/methanol-$d_4$ solvent, while 1b and 1c which have neutral flexible bridges exhibited no appreciable binding with 2. The disodium salt of 1d showed much higher binding affinity for 2 forming 1 : 1 and 1 : 2 complexes.

• 태양에너지
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• 제15권3호
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• pp.105-117
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• 1995

본 연구소에서는 Furan foundry sand 유동층내에 Spiral coil tube를 설치하여 유동입자, 유동층내 온도, 유동율, 전열 관의 Pitch와 직경 비(p/Do) 및 전열 관의 Pitch와 유동입자의 크기의 비(p/dp) 등이 전열 관 표면 열 전달계수(ho)에 미치는 영향을 실험적으로 연구하고, 또한 최대 $Nu_{max}$수를 여러 변수들의 관계로 나타내었다. 전열 관 표면 열 전달계수는 유동층내 온도가 높아 질 수록, 유동율이 커질수록 증가한다. 그러나 유동입자의 크기가 커지면 열 전달계수는 감소한다. 전열 관의 Pitch와 직경 비(p/Do)와의 관계에서 p/Do=4.75일 때 가장 높은 열 전달계수를 얻었으며, 유동층내 온도가 상승하고, Re 수가 증가할 수록 p/Do=1.58일 때보다 p/Do=4.75일때가 Nu수의 증가율은 다소 감소하는 경향을 보였다. 또한 p/dp의 비가 클 경우 낮은 온도($75^{\circ}C$)에서, p/dp의 비가 작을 경우는 높은 온도($550^{\circ}C$)에서 열 전달 효과가 큰 것으로 나타났다. 본 실험범위에서 최대 $Nu_{max}$ 수와 Re 수, Prg 수, p/dp 및 p/Do의 관계를 무차원 식으로 다음과 같이 나타낼 수 있었다. $$Nu_{max}=1.01\;Re^{0.48}Prg^{0.4}(p/dp)^{0.28}(p/Do)^{0.05}$$.

• 식품기술
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• 제20권3호
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• pp.80-88
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• 2007

• 한국진공학회:학술대회논문집
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• 한국진공학회 1995년도 제9회 학술발표회 논문개요집
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• pp.108-109
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• 1995

• 한국주조공학회지
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• 제20권2호
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• pp.70-79
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• 2000

• Bulletin of the Korean Chemical Society
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• 제18권7호
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• pp.781-783
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• 1997

• Bulletin of the Korean Chemical Society
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• 제18권3호
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• pp.247-249
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• 1997

• Bulletin of the Korean Chemical Society
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• 제18권4호
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• pp.357-360
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• 1997

• 한국환경과학회지
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• 제18권7호
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• pp.803-810
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• 2009

Concentrations of dioxins, furans and dioxin-like polychlorinated biphenyls (DL-PCBs) were determined in crucian carp collected from eight locations mainly along the Nakdong River during 2004. Total dioxin concentrations which include concentrations of dioxins, furans and DL-PCBs ranged from 0.053 to 0.614 pg WHO-TEQ $g^{-1}$ wet wt. with a mean of $0.342{\pm}0.213$ pg WHO-TEQ $g^{-1}$ wet wt. The proportions of dioxins, furans and DL-PCBs to total dioxin TEQ were 4%, 12% and 84%, respectively. The results suggest that concentrations of dioxin-like polychlorinated biphenyls should be determined when total dioxin TEQ accumulated in freshwater fish is investigated.