• 제목/요약/키워드: functional compounds

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뷰티케어용 세라믹소재기술 동향 (Trend of Ceramic Materials Technology for Beauty-care)

  • 장정호
    • 세라미스트
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    • 제21권3호
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    • pp.302-308
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    • 2018
  • This work reported the trends of bioceramic materials for beauty-care applications with the several represent examples - tone-up, sun-care and anti-pollution cosmetics. The development of cosmetic techniques was discussed and reviewed with various ceramic hybrid materials. Moreover, we also reported the preparation and application of functional cosmetics with silicified liposome particles as a good make-up material for controlled release with natural compounds. The homogeneous loading and highly controlled-release formulation with porous and silicified ceramic liposome ceramic materials were discussed.

Novel Asymmetric Synthesis of Unsaturated 1,2-Amino Alcohols

  • Kim, Ji-Duck;Jung, Young-Hoon
    • 대한약학회:학술대회논문집
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    • 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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    • pp.231.2-232
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    • 2002
  • The synthesis of chiral 1,2-amino alcohols has been an area of intense study in the synthetic and industrial fields, because of their important roles in organic synthesis as fundamental building blocks and their occurrence in a number of natural products. drugs. and chiral auxiliaries or ligands. General methods for the synthesis of these compounds can be divided into two large categories: functional group transformations and the C-C or the C-N bond formations. (omitted)

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Selective Tandem Synthesis of Oximes from Benzylic Alcohols Catalyzed with 2, 3-Dichloro-5, 6-dicyanobenzoquinone

  • Aghapour, Ghasem;Mohamadian, Samaneh
    • Bulletin of the Korean Chemical Society
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    • 제33권4호
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    • pp.1209-1212
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    • 2012
  • In spite of many reports in the literature concerning with oxidation of benzylic alcohols to carbonyl compounds with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) in stoichiometric amounts or even more, we surprisingly found that benzylic alcohols are directly oxidized to oximes using a catalytic amount of DDQ in the presence of hydroxylamine hydrochloride under solvent-free conditions. The present tandem catalytic method can be efficiently used for preparation of oximes in the presence of some other functional groups with excellent chemoselectivity.

Vinylation of $\beta$-Acetoxyvinyl Mercurials with Olefins by Palladium (Ⅱ) Salt

  • Kim, Jin-Il;Lee, Jong-Tae
    • Bulletin of the Korean Chemical Society
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    • 제7권2호
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    • pp.142-145
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    • 1986
  • Vinylation of highly hindered ${\beta}$-acetoxyvinyl mercurials with olefins in acetonitrile at room temperature in the presence of cupric chloride, as a reoxidant for the palladium, and a catalytic amount of $LiPdCl_3$ gave the corresponding conjugated dienes in moderate to good yields. The (E) or (Z) geometry in vinyl mercurials was retained in the vinylated products. The reaction was tolerant of a wide variety of functional groups ($CO_2$R, CN, OR, OAc) on either the vinyl mercurial or olefin compounds.

Synthesis of 11-Deoxydaunomycinone and Novel 10-Fluoroanthracyclinone Derivatives

  • Rho, Young S.;최영희;김규일;신홍식;유동진;정채준;김선하
    • Bulletin of the Korean Chemical Society
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    • 제20권5호
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    • pp.551-555
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    • 1999
  • 11-Deoxydaunomycinone 15 and 10-fluoroanthracyclinone derivatives 9, 10 were obtained. Naphthalenone 4 prepared from 2-(2,4-pentadienyl)-1,3-dioxane 2 with methyl vinyl ketone and hydrolysis with HClO4 was condensed with phthalidesulfone 5 through Michael type reaction, and was converted to 7 by epoxidation. Epoxide 7 was transformed to trione 12 using reduction-oxidation or hydrofluorination process, and then to 15 by introducing several functional groups. Compound 8 obtained in the course of the reaction of epoxide 7 and HF/ Pyr was used for the synthesis of compounds 9, 10.

Synthesis of POSS-Functionalized Imidazole

  • Choi, Kyung-Min;Jang, Hee-Jae;Shin, Dong-Soo
    • 대한화학회지
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    • 제63권1호
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    • pp.51-55
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    • 2019
  • The synthesis of N-substituted POSS-imidazole in one pot typically prepared using the condensation method from diketone and aminopropylisobutyl-POSS. A wide variety of functional groups and substitution patterns were tolerated under the present procedure. The resulting compounds can be used as valuable products allowing for the elaboration to OLED, DSSC building block.

까마중-에탄올 추출물의 기능적 특성과 항산화 효과 (Functional Properties and Antioxidant Effects of Solanum nigrum-Ethanol Extract)

  • 정갑섭;이남걸
    • 한국환경과학회지
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    • 제18권11호
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    • pp.1207-1214
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    • 2009
  • Functional properties of Solanium nigrum-ethanol extract were investigated, nitrite scavenging ability(NSA) and antioxidant activities based on thiobarbituric acid(TBA) value were measured. The contents of potassium in fruit and root, calcium in leaf were the highest mineral components in each parts of Solanium nigrum. Total aromatics contents(TAC) was order of fruit>root>leaf, total flavonoid contents(TFC) in leaf was 6 and 10 times, total phenolic compounds contents(TPC) in leaf was 15 and 30 times of those in fruit and root, respectively, and TFC was high with TPC increase. NSA of leaf-ethanol extract was 61.9% on pH 1.2, 53.5% on pH 3.0, 54.8% on pH 4.0 and 14.3% on pH 6.0, where as NSA of root and fruit-ethanol were considerably low to 3.5~7.9% over pH 1.2~6.0. TBA value of soybean oil with the dosage of leaf-extract showed few differences from control within 3 days, but it fairly decreased with considerable antioxidant effect to 47.6% of the control in 8 days.