• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2003년도 생물공학의 동향(XII)
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• pp.164-168
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• 2003

유채유를 사용하여 바이오디젤 생산을 위한 1단 전이에스테르화 공정에 있어서 반응온도 $60^{\circ}C$, 유지에 대한 메탄올 몰비 1:10 이상, 1.0 % (w/w) 포타슘 하이드록시드의 조건에서 98.5% 이상의 전화율을 얻을 수 있었다.

• 한국연소학회지
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• 제14권1호
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• pp.19-24
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• 2009

A novel low NOx oil burner of 0.7 MW (for a 1 ton steam/hr industrial boiler) was designed and tested to investigate the combustion characteristics through in-flame measurement and flue gas analysis. Flame shape was observed by CCD camera and $CH^*/{C_2}^*$ radical distribution in the flame were observed, along with measurement of flue gas composition such as NOx and CO, for various heat inputs, excess airs and pressure of the fuel spary nozzles. The flame showed the two-zone structure: fuel-rich and fuel-lean zone, which was very favorable for the low-NOx combustion, and the NOx emission for haevy oil combustion was significantly reduced to < 150 ppm at 4 % $O_2$, compared with the NOx level of a conventional heavy oil burner.

• 한국지하수토양환경학회지:지하수토양환경
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• 제8권1호
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• pp.75-80
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• 2003

해수 중에는 연안 조간대의 저서생물의 생존에 필수적인 용존산소와 영양염이 풍부하게 내포되어 있기 때문에 해수의 토양침투는 저서생물의 생존과 밀접한 관련을 맺고 있다. 그러나 유출된 기름이 조간대에 표착하게 되면 해수의 침투가 차단되어 생물에게 많은 피해를 유발시킬 것이다. 또한 유출된 기름의 토양 침투에 관한 정보는 생태계 영향을 최소화하고 처리를 위한 대책수립의 단서로서 매우 중요하다. 본 연구에서는 유출된 기름의 침투 거동을 파악하고 침투된 기름의 해수 침투 차단을 검토하는 것을 목적으로 하여 연구를 수행하였다. 점도가 낮은 원유가 C중유보다 침투 깊이가 약 2배 깊었으며, 유출된 기름의 침투 깊이는 조간대에 표착된 기름의 양에 따라 영향을 받는 것을 알 수 있었다. 그리고 표착된 기름은 첫번째 조석에서 가장 급격한 침투거동을 보였으나, 두번째 조석변동부터는 급격한 침투 변화는 나타나지 않았다. 그리고 침투한 유분의 수직적 분포로부터 기름은 토양 표층 2cm에 집중적으로 분포하는 것을 알 수 있었다. 한편 해수의 침투량은 표착유의 양에 비례적으로 감소하였으며, C중유가 원유보다 약 1.7배 정도의 해수의 토양 침투량을 감소시키는 것을 알 수 있었다. 따라서, 침투한 기름의 처리는 가능한 빠른 시간내에 수행되어야 해수의 침투를 회복시켜 연안 조간대 생태계의 피해를 최소화 시킬 수 있다고 판단된다.

• 공업화학
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• 제30권3호
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• pp.297-302
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• 2019

열분해 연료유(pyrolysis fuel oil)의 열처리 시 발생되는 구조변화를 파악하기 위하여 열처리 온도에 따라 발생되는 휘발유분(volatile matters) 및 중질유분을 분리하였다. 열처리 온도가 증가함에 따라 중질유분의 수율은 낮아지며, 탄화수율은 높아지는 것을 확인하였다. 휘발유분의 $^1H-NMR$ 구조분석 결과, 원료에 포함되어 있던 1~2환 방향족 성분들은 $340^{\circ}C$ 이전의 온도에서 대부분 제거되었으며, $320^{\circ}C$부터는 크래킹 반응에 의하여 방향족 화합물로부터 지방족 탄화수소 곁사슬이 분해됨에 따라 새로운 휘발유분을 생성하는 것을 확인하였다. 한편 중질유분의 원소분석 및 $^1H-NMR$ 구조분석 결과로부터, 열처리 온도가 증가할수록 C/H 몰비 및 방향족화도 값이 증가함을 알 수 있었다. 이러한 구조분석 결과를 통하여 PFO의 $280{\sim}360^{\circ}C$에서의 열처리에 따른 구조 변화는 비점 차이에 따른 휘발유분의 분리 및 크래킹 반응에 의한 지방족 곁사슬의 분해가 가장 큰 영향을 미치며, 일부 화학종 간 중합반응 또한 발생된 것을 확인하였다.

• Carbon letters
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• 제25권
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• pp.78-83
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• 2018

Pyrolyzed fuel oil (PFO) and coal tar was blended in the feedstock to produce pitch via thermal reaction. The blended feedstock and produced pitch were characterized to investigate the effect of the blending ratio. In the feedstock analysis, coal tar exhibited a distinct distribution in its boiling point related to the number of aromatic rings and showed higher Conradson carbon residue and aromaticity values of 26.6% and 0.67%, respectively, compared with PFO. The pitch yield changed with the blending ratio, while the softening point of the produced pitch was determined by the PFO ratio in the blends. On the other hand, the carbon yield increased with increasing coal tar ratio in the blends. This phenomenon indicated that the formation of aliphatic bridges in PFO may occur during the thermal reaction, resulting in an increased softening point. In addition, it was confirmed that the molecular weight distribution of the produced pitch was associated with the predominant feedstock in the blend.

• 한국응용과학기술학회지
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• 제32권1호
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• pp.136-147
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• 2015

신재생에너지 공급 의무화제도(Renewable Portfolio Standard(RPS))가 시행됨에 따라, 발전 사업자들은 의무공급량 이행을 위해 발전용 바이오중유를 사용하고 있다. 본 연구에서는 발전용 바이오중유의 원료물질별 물성과 원료 조성에 따른 발전용 바이오중유의 품질특성을 알아보았다. 발전용 바이오중유와 원료유지의 연료특성은 전산가, 동점도, 금속분 등 고시 상 품질기준 항목을 분석하였으며, 적외선 분광광도계와 고성능 액체크로마토그래피를 이용하여 조성분포를 분석하였다. 팜유계열의 저가의 고산가 유지는 유리지방산 함량이 높아 전산가가 높고, 금속분에 의한 회분함량이 높았으며, 바이오디젤 공정부산물은 점도가 높았다. 동점도, 전산가, 금속분과 같은 발전용 바이오중유의 연료특성은 원료물질 의 조성 및 혼합비와 관련이 깊다.

• 한국해양학회지
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• 제26권4호
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• pp.350-357
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• 1991

조간대에 서식하는 고둥류인 좁쌀무늬총알고동, 총알고동, 대수리 등 3종에 대한 유류오염과 유처리제를 이용한 정화작업의 영향을 조사하기 위한 실험을 실시하였다. 라뷰안 원유, 듀바이 원유, 벙커 C유를 실험 생물에 각각 직접 접촉시켰으며, 또한 1 시간 노출시킨 후에 농축형 유처리제로 세척하였다. 원유에 접촉시킨 고동류는 96시간 내에 모두 처사하였으며, 라뷰안 원유가 듀바이 원유보다 높은 독성을 보였다. 벙커 C 유에는 총알고동류가 대수리보다 민감한 반응을 보였으며, 원유 접촉시보다는 서서히 독성효과가 나타났다. 높은 농도의 유처리제를 이용한 전화작업은 고동류에게 치명적 인 영향을 주었으며, 낮은 농도에서도 총알고동류에게 유해한 영향을 주었다. 대수리 는 분산된 유류에 노출될 경우 250 ppm 이하의 농도에서는 도피행동을 보였다. 유류오 염과 유처리제를 이용한 정화작업은 고동류의 흡착기능을 저해하여 물리적인 힘에 의 해 서식지 이탈을 유발시킬 수 있을 것으로 보인다.

• Tribology and Lubricants
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• 제22권5호
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• pp.260-268
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• 2006

The dielectric constants of used gasoline engine oils were obtained at a few temperatures and a frequency. Through analyzing the characteristics of dielectric constant, the related correlation between the changes in dielectric constants of oil and the degree of oil deterioration is going to be found. The dielectric constant was calculated using cross capacitances measured by a sensor tube. As results of the measurement of the fresh engine oil's dielectric constant, it was found that the value of dielectric constant was set down below $60^{\circ}C$ regardless changing frequency. Further, above 6 kHz, the dielectric constant was set down even if temperature was above $100^{\circ}C$ Therefore, for the measurement of used oils, it was selected the frequency of 6 kHz,,and the temperature of $80^{\circ}C$ preventing a certain ionic-conduction effects on the measured dielectric constant and the evaporation of a certain fluid mixed with engine oil. Specially, the effects of the mixing fluid like coolant, water and fuel on the fresh engine oil's dielectric constant were studied. It was found that the oil mixed with coolant showed the highest value, next water, and the lowest fuel. As results of the measurement of the used engine oil's dielectric constant, it was found that the possible changed rate of the used engine oil's dielectric constant based on the warning limit for engine oil in service was below 4% for gasoline engine oil.

• Tribology and Lubricants
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• 제22권5호
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• pp.290-300
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• 2006

The dielectric constants of used diesel engine oils were obtained at a few temperatures and a frequency. Through analyzing the characteristics of dielectric constant, the related correlation between the changes in dielectric constants of oil and the degree of oil deterioration is going to be found. The dielectric constant was calculated using cross capacitances measured by a sensor tube. As results of the measurement of the fresh engine oil's dielectric constant, it was found that the value of dielectric constant was set down below $60^{\circ}C$ regardless changing frequency. Further, above 6 kHz, the dielectric constant was set down even if temperature was above $100^{\circ}C$. Therefore, for the measurement of used oils, it was selected the frequency of 6 kHz, and the temperature of $80^{\circ}C$ preventing a certain ionic-conduction effects on the measured dielectric constant and the evaporation of a certain fluid mixed with engine oil. Specially, the effects of the mixing fluid like coolant, water and fuel on the fresh engine oil's dielectric constant were studied. It was found that the oil mixed with coolant showed the highest value, next water, and the lowest fuel. As results of the measurement of the used engine oil's dielectric constant, it was found that the possible changed rate of the used engine oil's dielectric constant based on the warning limit for engine oil in service was below 10% for diesel engine oil.

• Journal of Biosystems Engineering
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• 제26권3호
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• pp.209-220
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• 2001

This study was carried out to investigate the usability of the used frying oil, which was extracted from soybean, as one of the alternative fuel of a small diesel engine. For the experiment, NO. 2 diesel oil [D], used frying oil [UF], and their volumetric blends were applied and analysis of the properties and compositions of the experimental fuels were conducted. A four cycle diesel engine with single cylinder, water cooling system, maximum output 8.1 ㎾/2,200 rpm was selected and a direct injection chamber and a precombustion chamber were attached alternately. The results obtained were as follows: 1. Engine power (BHP) were increased from 4.13~4.27㎾ to 9.08~9.15㎾ for diesel oil, from 4.05~4.19㎾ to 8.44~8.92㎾ for UF, and from 4.01~4.48㎾ to 8.69~9.16㎾ for blend fuel, as the engine speed increased from 1,000 rpm to 2,200 rpm. The BHP in case of the direct combustion chamber were fluctuated higher than those of the pre-combustion chamber. 2. With the engine speed increased, torque of the engine were increased from 39.50~40.80 N.m to 42.89 N.m, then decreased to 39.44~39.77 N.m for diesel oil, and increased from 38.73~40.04 N.m to 40.12~40.82 N.m then decreased as 36.53~38.76 N.m for UF. Torque of the blend fuels were increased from 38.75~41.76 N.m to 40.47~42.89 N.m then decreased to 37.73~39.78 N.m. There is no significant difference of torque between the type of combustion chambers. 3. The specific fuel consumption of the UF was increased about 20 percent depending on the engine speed variations. And in case of direct injection chamber, about 12 percent lower fuel consumption was observed than that of precombustion chamber. 4. NOx emission of the UF was higher than that of diesel oil at above 1,800rpm of the engine speed. In case of the direct injection chamber, NOx emission was revealed higher about 59 percent than that of the precombustion chamber, depending on the range of the engine speeds. 5. Smoke emission was decreased in case of UF compared with diesel oil on direct injection chamber. When using precombustion chamber smoke emission was a little higher than that of the direct injection chamber were showed at the engine speed range. 6. At all the engine speed range, exhaust gas temperatures were decreased 2~3$^{\circ}C$ for UF used engine compared with those of the diesel oil. The exhaust gas temperature of the direct injection chamber was higher than that of the precombustion chamber by 72$^{\circ}C$. 7. Unburnt materials remained in the cylinder in case of the pre-combustion chamber was smaller and softer than that of the direct combustion chamber. 8. The feasibility of the blend fuel B-1 and B-2 were verified as a direct combustion chamber was attached to the diesel engine, with respect to the power performance of the engine.