• Journal of Energy Engineering
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• v.23 no.3
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• pp.235-240
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• 2014

In this study, the torrefaction of food waste was conducted to characterize its product, to find out effect of the operating temperature and to assess the feasibility of being used as fuel. The operating temperature was varid from $180^{\circ}C{\sim}270^{\circ}C$ and heat was provided by using nitrogen gas or waste oil heat carrier. The solid yield and moisture content were reduced were reduced as temperature increased. The moisture content reduction and thermochemical conversion were observed at higher than $240^{\circ}C$. At low operating temperature, heat transfer efficiency was higher with wast oil heat carrier. As temperature increases, there was not difference in heat transfer efficiency of two different heating methods. The lower heating value product was increased from 660 to 6,400 Kcal/kg with nitrogen gas and 6,890 Kcal/kg with waste oil heat carrier. The elemental analysis indicates that, as temperature increases, the carbon content of product increases and oxygen content decreases. From the analysis of O/C and H/C, the torrefaction product was close to low grade coal. The characteristics of fuel converted from the food subsequent thermochemical treatment.

• Korean Journal of Materials Research
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• v.28 no.3
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• pp.189-194
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• 2018

Porous graphites were synthesized by removing the template in HF after cabothermal conversion for 3 h at $900^{\circ}C$, accompanied by intercalations of pyrolyzed fuel oil (PFO) in the interlayer of Co or Ni loaded magadiite. The X-ray powder diffraction pattern of the porous graphites exhibited 00l reflections corresponding to a basal spacing of 0.7 nm. The particle morphology of the porous graphites was composed of carbon plates intergrown to form spherical nodules resembling rosettes like a magadiite template. TEM shows that the cross section of the porous graphites is composed of layers with very regular spaces. In particular, crystallization of the porous graphite was dependent on the content of Co or Ni loaded in the interlayer. The porous graphite had a surface area of $328-477m^2/g$. This indicates that metals such as Co and Ni act as catalysts that accelerate graphite formation.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.115-116
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• 2006

보다 깨끗한 환경에서 살고 싶어 하는 인류의 욕구가 육상의 대기 배출물뿐만 아니라 선박까지도 보다 깨끗한 배기를 요구하기에 이르렀다. 이러한 요구에 부응하여 IMO(국제해사기구)뿐만 아니라 EU(유럽연합)과 미국 등에서 규제를 이미 시작하였거나 시작할 예정이다. 또한 많은 선급에서도 약 10년 전부터 자발적인 규칙을 도입해오고 있다. 그리고 스웨덴은 인센티브제를 오래 전부터 적용해오고 있다. 이러한 규제, 선급 규칙 및 인센티브제는 질소산화물, 황산화물 및 입자상물질 배출에 제한을 가하는데, 황산화물 및 입자상물질 배출 제한은 간접적으로 연료유에 함유되어 있는 황 함량 규제를 통하여 하고 있거나 하려고 한다. 여기에 이러한 규제, 선급 규칙 및 인센티브제에서 가하고 있거나 가할 예정인 선박 디젤기관 연료유의 황 함량 규제에 대하여 간략하게 소개한다.

• Applied Chemistry for Engineering
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• v.33 no.5
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• pp.496-501
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• 2022

In this study, an anode material for lithium secondary batteries was manufactured using petroleum-based residual oil, which is a petroleum refining by-product. Among petroleum-based residual oils, pyrolysis fuel oil (PFO), fluidized catalyst cracking-decant oil (FCC-DO), and vacuum residue (VR) were used as carbon precursors. The physicochemical characteristics of petroleum-based residual oil were confirmed through Matrix-assisted laser desorption/ionization Time-of-Flight (MALDI-TOF) and elemental analysis (EA), and the structural characteristics of anode materials manufactured from residual oil were evaluated using X-ray crystallography (XRD) and Raman spectroscopic techniques. VR was found to contain a wide range of molecular weight distributions and large amounts of impurities compared to PFO and FCC-DO, and PFO and FCC-DO exhibited almost similar physicochemical characteristics. From the XRD analysis results, carbonized PFO and FCC-DO showed similar d₀₀₂ values. However, it was confirmed that FCC-DO had a more developed layered structure than PFO in Lc (Length of a and c axes in the crystal system) and La values. In addition, FCC-DO showed the best cycle characteristics in electrochemical characteristics evaluation. According to the physicochemical and electrochemical results of the petroleum-based residual oil, FCC-DO is a better carbon precursor for a lithium secondary battery than PFO and VR.

• Korean Chemical Engineering Research
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• v.46 no.5
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• pp.845-851
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• 2008

Oxidative desulfurizaton of model sulfur compounds and Industrial diesel fuel(LCO; Light Cycle Oil) over Ti-grafted SBA-15 catalyst was studied in a batch reactor with tert-Butyl Hydroperoxide(TBHP) as oxidant. Effects of Ti loading, TBHP/Sulfur mole ratio, reaction temperature on ODS activity and kinetic parameters were investigated. Ti-grafted SBA-15 catalyst showed higher sulfur removal activity in the oxidative desulfurization reaction of refractory sulfur compounds(DBT and 4, 6-DMDBT) and LCO, suggesting that Ti-grafted SBA-15 catalyst could be a good candidate for ODS catalyst.

• Elastomers and Composites
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• v.42 no.4
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• pp.232-237
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• 2007

We examined the properties of compound and made compound of the optimum state using the properties of each material to evaluate suitability of FKM, VMQ, EPDM, NBR with gasket for fuel cell which is in general use with the material of gasket. It could be found from the compound made with setting the optimum state that NBR is worse than FKM in the chemical property of matter for a long term, and VMQ is worse than FKM in the elution of a metal ion, and EPDM is worse than FKM in the permeability of gas. As a result of leak evaluation of gasket for fuel cell with using FKM, it appeared leak in short time when contracting pressure is getting lower and sealing pressure is getting higher. And as a result of the life prediction with using Arrhenius model, we could predict that it is possible to continuously drive for 60,000 hours.

• Journal of Energy Engineering
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• v.17 no.1
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• pp.8-14
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• 2008

The effects of calcium type catalysts addition on the thermal decomposition of low density polyethylene (LDPE) and ethylene vinyl acetate (EVA) resin have been studied in a thermal analyze. (TGA, DSC) and a small batch reactor. The calcium type catalysts tested were calcinated dolomite, lime, and calcinated oyster shell. As the results of TGA experiments, pyrolysis starting temperature for LDPE varied in the range of $330{\sim}360^{\circ}C$ according to heating rate, but EVA resin had the 1st pyrolysis temperature range of $300{\sim}400^{\circ}C$ and the 2nd pyrolysis temperature range of $425{\sim}525^{\circ}C$. The calcinated dolomite enhanced the pyrolysis rate in LDPE pyrolysis reaction, while the calcium type catalysts reduced the pyrolysis rate in EVA pyrolysis reaction. In the DSC experiments, addition of calcium type catalysts reduced the melting point, but did not affect to the heat of fusin. Calcinated dolomite reduced 20% of the heat of pyrolysis reaction. In the batch system experiments, the mixing of calcinated dolomite and lime enhanced the yield of fuel oil, but did not affect to the distribution of carbon numbers.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.465-469
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• 2013

In this study, we investigated the feasibility of torrefied OPF (oil palm fronds) as the fuel. The torrefaction was performed at 200, 250, 300 and $350^{\circ}C$ during 1 and 2 hours, respectively. As raising the torrefaction temperature and increasing the processing time, the GHV (gross heating value) of torrefied OPFs was increased. Moreover, we found that the torrefaction temperature is more important factor than the processing time. However, the proper torrefaction temperature was asked because the higher torrefaction temperature leaded to the lower torrefied OPF yield. TGA (thermo-gravimetric analysis) data released that the torrefaction at $250^{\circ}C$ could significantly decompose the hemicellulose and the almost cellulose was decomposed at $300^{\circ}C$. In addition, the grindability of biomass was improved after torrefaction, so that it can reduce energy consumption in comminution.

• Elastomers and Composites
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• v.41 no.2
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• pp.88-96
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• 2006

The self-sealing rubber material for a fuel cell which has self-sealing ability, in case of fuel leakage, was studied. Cure characteristics, density, swelling, and surface morphology of foamed natural rubber were investigated with carbon black and with processing oil within the range of $10{\sim}30phr$. The rheological properties indicated that the value of $ts_2$ and the value of $Tc_{90}$ were increased with increasing a content of processing oil, while carbon black did not show a similar trend. A difference in density by foaming was decreased to one fifth scale compared to the initial value. According to the swelling test of foamed natural rubber in fuel C, isooctane and toluene, all the self-sealing action was finished in two minutes. From the SEM image for the surface of rubber compounding, a foaming by sodium bicarbonate was found to be unequal and consecutive foaming cell.

• Journal of the Korea Safety Management & Science
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• v.19 no.3
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• pp.1-9
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• 2017

In the industrial field, various type of fuel have been used for product processing facilities. Recent for 10 years, the usage of natural gas (NG) was gradually increased. Because it has many merits; clean fuel, no transportation, storage facility and so on. There are common safety concept that strict explosion protection approaches are needed for facilities where explosive materials such as flammable liquid, vapor and gases exist. But some has an optimistic point of view that the lighter than air gases such as NG disperse rapidly, hence do not form explosion environment upon release into the atmosphere, many parts has a conventional safety point of view that those gases are also inflammable gases, hence can form explosion environment although the extent is limited and present. In this paper, the heating equipments (Hot Oil Heater) was reviewed and some risk management measures were proposed. These measures include hazardous area classification and explosion-proof provisions of electric apparatus, an early gas leak detection and isolation, ventilation system reliability, emergency response plan and training and so on. This study calculates Hazardous Area Classification using the hypothetical volume in the KS C IEC code.