• Title/Summary/Keyword: fuel composition

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Experimental Investigation of the Effect of Composition on the Performance and Characteristics of PEM Fuel Cell Catalyst Layers

  • Baik, Jung-Shik;Seong, Dong-Mug;Kim, Tae-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.157-160
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    • 2007
  • The catalyst layer of a proton exchange membrane (PEM) fuel cell is a mixture of polymer, carbon, and platinum. The characteristics of the catalyst layer play critical role in determining the performance of the PEM fuel cell. This research investigates the role of catalyst layer composition using a Central Composite Design (CCD) experiment with two factors which are Nafion content and carbon loading while the platinum catalyst surface area is held constant. For each catalyst layer composition, polarization curves are measured to evaluate cell performance at common operating conditions, Electrochemical Impedance Spectroscopy (EIS), and Cyclic Voltammetry (CV) are then applied to investigate the cause of the observed variations in performance. The results show that both Nafion and carbon content significantly affect MEA performance. The ohmic resistance and active catalyst area of the cell do not correlate with catalyst layer composition, and observed variations in the cell resistance and active catalyst area produced changes in performance that were not significant relative to compositions of catalyst layers.

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A SENSITIVITY STUDY ON NEUTRONIC PROPERTIES OF DUPIC FUEL

  • Park, Hangbok;Roh, Gyu-Hog
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.124-129
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    • 1998
  • A sensitivity study has been done to determine the composition of DUPIC fuel from the viewpoint of neutronics fuel design. The spent PWR fuel compositions were generated and fissile contents adjusted by blending fresh uranium after mixing two spent PWR fuel assemblies. The $^{239}$ Pu and $^{235}$ U enrichments of DUPIC fuel were adjusted by controlling the amount of fresh uranium feed and the ratio of slightly enriched and depleted uranium in the fled uranium. Based on the material balance calculation, it is recommended that DUPIC fuel composition be such that spent PWR fuel utilization is more than 90%.. A sensitivity study on the temperature reactivity coefficient of DUPIC fuel has shown that it is desirable to increase the $^{239}$ Pu and $^{235}$ U contents to reduce both the fuel and coolant temperature coefficients. On the other hand, refueling simulations of the DUPIC core have shown that the channel power peaking factor, which is a measure of the reactor trip margin, increases with the total fissile content. Considering these neutronic characteristics of the DUPIC fuel, il is recommended to have enrichments of 0.45 and 1.00 wt% for $^{239}$ Pu and $^{235}$ U, respectively.

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Study on the fuel rail temperature and pressure characteristics with LPG composition during hot restart condition of LPi engine with turbine type pump (터빈방식 펌프 LPi연료공급 시스템의 엔진 고온재시동 시 LPG 조성비에 따른 연료레일에서의 압력 및 온도특성에 관한 연구)

  • Lee, Kang-Ju;Kim, Ju-Won;Myung, Cha-Lee;Park, Sim-Soo
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3323-3328
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    • 2007
  • Conventional LPG pump for Liquified Petroleum injection(LPi) engine has been adopted vane type. But the BLDC type fuel pump for LPi system has complicated structure and its price is high. Therefore, as a alternative, this study has mainly focused on the development of turbine type LPG pump which has lower cost and simple structure than conventional BLDC type. To verify the possibility of substitute the performance tests were performed for each fuel pump. The comparative items were pressure settling time, variation of fuel outlet temperature and engine performance of hot restart ability. As a result, performances of turbine type LPG pump were equivalent or high comparing to the BLDC type all over the tests for different fuel composition.

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Effect of Gas Compositions on Fuel Economy and Exhaust Emissions of Natural Gas Vehicles (연료의 조성변화가 천연가스차량의 연비 및 배출가스 특성에 미치는 영향)

  • 이영재;김강출
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.8
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    • pp.123-131
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    • 1999
  • Natural gas is one of the most promising alternative fuels for automotive vehicles. However, natural gas varies in compositional between the originating fields and may be further modified due to processing and additional mixing. These variations are known to affect engine performance and emissions through changes in fuel metering and combustion characteristics. In the present study, the effect of gas compositions on vehicle performance such as fuel economy, driveability and exhaust emissions was examined. Analysis are made of using 3 types of NGVs which were made by automakers and 6 different fuels which are selected in consideration of the variation in fuel composition on the worldwide market. The results may be utilized to develop natural gas natural gas engine in automaekrs and/or to establish the fuel standard in the refueling stations.

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A Study on Performance of Initial Blowoff Flow for a Fuel Pump with Various Temperature and Composition Condition in LPG Engine (자동차용 LPG 펌프의 온도 및 연료조성에 따른 초기토출성능에 관한 연구)

  • Park, Cheol-Woong;Kim, Chang-Up;Choi, Kyo-Nam
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.12-17
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    • 2008
  • The In recent years, the need for more fuel-efficient and lower-emission vehicles has driven the technical development of alternative fuels such as LPG (Liquefied Petroleum Gas) which is able to meet the limits of better emission levels without many modifications to current engine design. LPG has a high vapor pressure and lower viscosity and surface tension than diesel and gasoline fuels. These different fuel characteristics make it difficult to directly apply the conventional gasoline or diesel fuel pump. In this study, experiments are performed to get initial performance and efficiency of the fuel pump under different condition of the temperature and composition of fuel. The characteristics of vane type fuel pump were investigated to access the applicability on LPLi engine.

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The Effects of Combustion Products Dilution and Wall Temperature on the Ignition of Methane Fuel (메탄연료의 점화특성에 미치는 연소 생성물 희석 및 벽면온도의 영향)

  • Song, Keum-Mi;Oh, Chang-Bo
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.9-15
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    • 2012
  • The ignition characteristics in a confined axisymmetric coflow $CH_4$ jet were investigated numerically with the Fire Dynamics Simulator(FDS). The $CH_4$ fuel stream was diluted with main combustion product gases, such as $O_2$, $N_2$, CO, $CO_2$, and $H_2O$, and the mixed fuel stream was heated up to the sufficient temperature where a supplying fuel stream can be ignited. For the calculation of chemical reaction in the simulation, a 2-step global finite chemistry model was considered. Boundary condition for confined wall was optimized by investigating the effects of wall temperature on the ignition characteristics of fuel stream. In addition, the effects of composition of diluents in the fuel stream and fuel stream temperature on the ignition of fuel steam were investigated. The ignition characteristics of $CH_4$ stream with diluents were very sensitive to the wall temperature, composition of diluents in the fuel stream and fuel stream temperature.

Optimization of CANFLEX-RU Fuel Bundle for CANDU-6

  • Lee, Y. O.;C. J. Jeong;K. S. Sim;J. S. Jun;Park, G. S.;Kim, B. G.;Park, J. H.;H. C. Suk
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.10a
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    • pp.35-40
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    • 1995
  • Considering the higher discharge burnup, lower channel refuelling rate, lower linear element rating(LER), lower coolant void reactivity and axial power shape, CANFLEX-RU fuel bundle is optimized for CANDU-6 by grading the fissile composition in the ring-wise of the bundle and by applying fuel management scheme appropriately. The fissile composition of the fuel bundle is graded as the recovered uranium (0.9 w/o U-235) in the outer and intermediate elements, depleted Uranium (0.2 w/o U-235) in the center element, natural uranium (0.71 w/o U-235) in the inner elements. Enrichment is not required for these fuel. The fissile composition is optimized by lattice calculation and by time-averaged reactor simulation. CANFLEX-RU optimized for CANDU-6 resulted to be the 15% lower channel refuelling rate, acceptable axial power profile and power envelope, 70% higher discharge burnup, 15% lower LER and not increase coolant void reactivity compared with the 37-element natural uranium bundle for CANDU-6.

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Effect of Diesel Injection Characteristics on Biogas-Diesel Dual Fuel Engine Performance (디젤 분사 특성이 Biogas-디젤 혼소엔진 성능에 미치는 영향)

  • Lee, Sun-Youp;Kim, Young-Min;Lee, Jang-Hee
    • Journal of ILASS-Korea
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    • v.15 no.4
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    • pp.195-201
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    • 2010
  • Due to its carbon-neutral nature, biogas generated from anaerobic digestion or fermentation of biodegradable wastes is one of the important renewable energy sources to reduce global warming. It is mainly composed of methane and various inert gases such as $CO_2$ and $N_2$, and the actual composition of biogas significantly varies depending on the origin of anaerobic digestion process. Therefore, in order to effectively utilize this fuel as an energy source for electricity, it is important to develop power generation engines which can successfully apply biogas with significant composition variations. In this study, efforts have been made to develop a diesel-biogas duel fuel engine as a way to achieve such a stable power generation. The effects of diesel fuel injection quantity and pressure on stable combustion and engine performance were investigated, and an impact of diesel fuel atomization was discussed. The engine test results show that there exists a 2 stage combustion which consists of diesel pilot fuel burning and premixed biogas/air mixture burning in dual fuel engine operation and optimum diesel injection parameters were suggested for biogases with various compositions and heating values.

A Study on the Performance Characteristics of a Fuel Pump in LPG Engine (자동차용 LPG 펌프의 성능특성에 관한 연구)

  • Park, Cheol-Woong;Kim, Chang-Up;Choi, Kyo-Nam
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.29-34
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    • 2007
  • In recent years, the need for more fuel-efficient and lower-emission vehicles has driven the technical development of alternative fuels such as LPG(Liquefied Petroleum Gas) which is able to meet the limits of better emission levels without many modifications to current engine design. LPG has a hish vapor pressure and lower viscosity and surface tension than diesel and gasoline fuels. These different fuel characteristics make it difficult to directly apply the conventional gasoline or diesel fuel pump. In this study, experiments are performed to get performance and efficiency of the fuel pump under different condition of the temperature, rotating speeds, and composition of fuel. The characteristics of fuel pump were affected by cavitation occurred from the variation of temperature and composition.

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Estimation of Synthesis Gas Composition by Biomass Fuel Conditions using Thermodynamic Equilibrium Model (열역학적 평형모델을 이용한 바이오매스 연료조건에 따른 합성가스 조성의 예측)

  • Hong, Seong-Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.1
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    • pp.79-87
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    • 2015
  • A thermochemical equilibrium model was constructed for predicting composition of synthesis gas in biomass gasification. The model included estimation of equilibrium constants using Gibbs free energy. After constructing the model, the results were compared with the experimental values and predictions from a previous model. Gas compositions were reasonably well agreed with them and showed effects of operational and fuel condition. When the reaction temperature increased, the lower heating values decreased due to the decrease in CH4 concentrations. The methane concentrations were lower than those observed in experimental results. The model was used to predict the gas composition and heating values for the cases of mixed fuel of charcoal and un-dry woodchips. Although downdraft gasifiers require fuels less than 15% of moisture contents, the model results indicated that the mixed fuel with charcoal and woodchips which had over 25% of moisture contents could be used in the downdraft gasifiers. It might be explained by increase in energy density resulting from mixing charcoal. The results imply that the efforts and costs for drying biomass fuels could be reduced by mixing charcoal or fuels with higher calorific values.