• Nuclear Engineering and Technology
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• 제56권3호
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• pp.933-940
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• 2024

A macroscopic cross section generation model was developed for the conceptual horizontal, compact high temperature gas reactor (HC-HTGR). Because there are many sources of spectral effects in the design and analysis of the core, conventional LWR methods have limitations for accurate simulation of the HC-HTGR using a neutron diffusion core neutronics simulator. Several super-cell model configurations were investigated to consider the spectral effect of neighboring cells. A new history variable was introduced for the existing library format to more accurately account for the history effect from neighboring nodes and reactivity control drums. The macroscopic cross section library was validated through comparison with cross sections generated using full core Monte Carlo models and single cell cross section for both 3D core steady-state problems and 2D and 3D depletion problems. Core calculations were then performed with the AGREE HTR neutronics and thermal-fluid core simulator using super-cell cross sections. With the new history variable, the super-cell cross sections were in good agreement with the full core cross sections even for problems with significant spectrum change during fuel shuffling and depletion.

• 한국항공우주학회지
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• 제40권11호
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• pp.940-947
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• 2012

연구대상으로 삼은 중형 전기추진 무인기는 무게 18.5 kg, 날개 길이 6.4 m급의 저속 장기체공형으로 태양전지, 연료전지, 배터리를 전력원으로 사용한다. 이륙시간에 따라 태양전지의 에너지 총량이 달라지므로 체공을 최대화하기 위한 최적의 이륙시간을 선정해야 한다. 이를 위해 전압매칭을 통해 각 전력원을 선정하여 모델링을 수행하였으며 단품 성능시험을 통해 검증 후 시뮬레이션을 수행하였다. 이륙시간이 오전 6시, 오전 2시일 때 각각 최대 37.5시간, 최소 27.6시간동안 전력공급이 가능하였다. 배터리 SOC의 사용범위를 25~80%로 제한하도록 연료전지의 작동을 제어할 경우 각각 0.31시간, 0.63시간동안 더 전력공급이 가능하며 각 전력원은 최적 운전점에서 작동함을 확인하였다.

• 한국수소및신에너지학회논문집
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• 제20권4호
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• pp.300-308
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• 2009

In a pursuit of the development of alternative mobile power sources with a high energy density, a planar and air-breathing PEMFCs with a new type of hydrogen cartridge which uses onsite $H_2$ generated from sodium borohydride ($NaBH_4$) hydrolysis have been investigated for use in advanced power systems. Two types of $H_2$ generation through $NaBH_4$ hydrolysis are available: (1) using organic acids such as sulphuric acid, malic acid, and sodium hydrogen carbonate in aqueous solution with solid $NaBH_4$ and (2) using solid selected catalysts such as Pt, Ru, CoB into the stabilized alkaline $NaBH_4$ solution. It might therefore be relevant at this stage to evaluate the relative competitiveness of the two methods mentioned above. The effects of flow rate of stabilized $NaBH_4$ solution, MEA (Membrane Electrode Assembly) improvement, and type and flow control of the catalytic acidic solution have been studied and the cell performances of the planar, air-breathing PEMFCs using $NaBH_4$ has been measured from aspects of power density, fuel efficiency, energy density, and fast response of cell. In our experiments, planar, air-breathing PEMFCs using $NaBH_4$ achieved to maximum power density of 128mW/$cm^2$ at 0.7V and energy efficiency of 46% and has many advantages such as low operating temperature, sustained operation at a high power density, compactness, the potential for low cost and volume, long stack life, fast star-up and suitability for discontinuous operation.

• Korean Chemical Engineering Research
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• 제59권1호
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• pp.6-10
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• 2021

PEMFC(Proton Exchange Membrane Fuel Cell) 고분자 막의 shorting 저항(Shorting Resistance, SR)은 고분자 막의 내구성에 관한 중요한 지표다. SR이 감소하면 shorting 전류(Shorting Current, SC)가 증가하여 내구성과 성능이 감소하고, SR이 약 0.1 kΩ·㎠ 이하가 되면 shorting이 발생하여 온도가 급상승하고 MEA(Membrane Electrode Assembly)를 연소시켜 스택 구동이 종료된다. Shorting 현상을 방지하기 위해서는 SR을 제어해야 하므로 SR에 영향을 주는 조건들에 대해서 연구하였다. SR 측정방법들에서도 차이가 있어서 DOE(Department of Energy)와 NEDO(New Energy and Industrial Technology Development Organization) 방법을 개선한 SR 측정법을 제시하였다. 상대습도와 온도, 셀 체결 압이 상승하면 SR이 감소함을 확인하였다. 고분자 막의 가속내구 평가과정에서 마지막 단계에서 SR이 0.1 kΩ·㎠ 이하로 급감해 수소투과전류밀도가 15 mA/㎠ 이상이 되었고, 이 MEA를 해체 후 SEM(Scanning Electron Microscope) 분석한 결과 고분자 막 내부에 백금이 많이 분포함을 보였다.

• 한국재료학회지
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• 제28권11호
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• pp.633-639
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• 2018

In anion exchange membrane fuel cells, Pd nanoparticles are extensively studied as promising non-Pt catalysts due to their electronic structure similar to Pt. In this study, to fabricate Pd nanoparticles well dispersed on carbon support materials, we propose a synthetic strategy using mixed organic ligands with different chemical structures and functions. Simultaneously to control the Pd particle size and dispersion, a ligand mixture composed of oleylamine(OA) and trioctylphosphine(TOP) is utilized during thermal decomposition of Pd precursors. In the ligand mixture, OA serves mainly as a reducing agent rather than a stabilizer since TOP, which has a bulky structure, more strongly interacts with the Pd metal surface as a stabilizer compared to OA. The specific roles of OA and TOP in the Pd nanoparticle synthesis are studied according to the mixture composition, and the oxygen reduction reaction(ORR) activity and durability of highly-dispersed Pd nanocatalysts with different particles sizes are investigated. The results of this study confirm that the Pd nanocatalyst with large particles has high durability compared to the nanocatalyst with small Pd nanoparticles during the accelerated degradation tests although they initially indicated similar ORR performance.

• 한국미생물·생명공학회지
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• 제38권4호
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• pp.461-466
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• 2010

본 연구는 미생물연료전지를 이용하여 액비를 처리하고 동시에 유용한 전기에너지 발생이 가능한지를 실험한 것이다. 탄소섬유전극(graphite felt)와 스테인레스 스틸망을 다른 비율로 충진한 single-chamber 미생물연료전지를 이용하였으며 탄소섬유전극보다 스테인레스망을 더 많이 충진한 미생물연료전지를 대조구(CMFC)로 하여 탄소섬유전극이 더 많이 충진된 미생물연료전지(SMFC)와 서로 비교하였다. 농화 배양이 끝난 후, SMFC로부터 발생되는 전류는 $3.167{\pm}80\;mg/L$ 의 액비를 공급할 때 18 mA가 안정적으로 발생되었다. 이때 최대 전력밀도와 전류밀도는 각각 $680\;mW/m^3$와 $3,770\;mA/m^3$이었으며, CMFC의 전력밀도와 전류밀도보다는 높았다. 화학적산소요구량(COD)는 SMFC와 CMFC에서 $3.718{\pm}80\;mg/L$에서 $865{\pm}21$과 $930{\pm}14\;mg/L$로 감소하여 각각 72.7%와 70.6%가 감소되었다. SMFC와 CMFC로부터 부유물질(SS)은 99% 이상이 감소되는 것을 확인하였다. 또한 SMFC의 암모니아성질소, 질산성질소, 그리고 인산염인과 같은 영향물질 농도의 변화도 각각 65.4%, 57.5%, 그리고 73.7%이 감소되었으며 CMFC의 경우도 거의 유사한 제거율을 보였다. 이들 결과로부터 저가 재료가 충진한 미생물 연료전지를 이용함으로써 경제적 효과를 기대할 수 있음은 물론 가축분뇨로부터 적지만 전기 에너지가 발생하는 것을 확인할 수 있었다.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2007년도 추계학술대회 논문집
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• pp.319-322
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• 2007

In the development of paralleling techniques, Multi-Phase Interleaved(MPI) converter constitutes one of the most promising alternatives reported in the last years. This technique consists of a phase shifting of the control signals of several cells in parallel operating at the same switching frequency. As a result, the aggregated input and output current waveform exhibit lower ripple amplitude and smaller harmonics content than in synchronous or stochastic operation modes. Based on the inherent advantages of the MPI converter, in this paper, a control scheme, which can reduce current and voltage rifle, is proposed for PEMFC generation systems. The MPI boost converter is composed of several identical boost converters connected in parallel.

• Journal of Electrical Engineering and Technology
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• 제4권2호
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• pp.201-210
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• 2009

A loss minimizing controller is developed for a fuel cell electric vehicle (FCEV) permanent magnet synchronous motor (PMSM). The PMSM losses are modeled by some experimental equations. Applying Lagrangian to the loss function, a necessary condition for the optimality appears to be a fourth order polynomial, and the loss minimizing solutions are obtained by a simple numerical approach. On the other hand, the loss minimizing solutions are found by scanning the motor loss in the entire operating region. The two results agree well. The loss minimizing current sets for given torque and speed are made into a table, which is utilized as a look-up in the current control loop.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2011년도 전력전자학술대회
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• pp.520-521
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• 2011

인버터의 병렬운전은 인버터간의 특성, 선로임피던스 차이, 각 구성품들의 오차 등으로 인해 적정한 제어가 되지 않는 경우 인버터간의 순환전류가 발생하여 인버터의 무효전력 부담이 증가하여 전체 전력 시스템의 용량을 감소시키게 된다. 본 논문에서는 4병렬 인버터의 병렬제어 알고리즘으로서 전압지령치와 주파수지령치의 regulation 성능이 좋은 동기좌표계 droop 제어기법을 적용한 1.2MW급 연료전지용 EBOP를 제안한다.

• Journal of Magnetics
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• 제17권4호
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• pp.275-279
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• 2012

The linear actuator has the inherent drawback of air gap variation because its linear motion is usually guided by the springs, which destabilizes the dynamic performance. In order to design the linear actuator to be insensitive to air gap, this paper describes the robust design of the air compressor driving linear actuator using Taguchi method. The orthogonal arrays are constructed with selected control factors and noise factor for minimum experiment. The control factors are thickness of inner magnet, height of upper yoke, thickness of outer magnet and thickness of lower yoke while noise factor is airgap. The finite element analysis using commercial electromagnetic analysis program "MAXWELL" are performed instead of experiment. ANOVA are performed to investigate the effects of design factors. In result, the optimal robust linear actuator which is insensitive to air gap variation is designed.