• Journal of Environmental Science International
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• v.28 no.10
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• pp.851-861
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• 2019

In this study, we performed a sediment elution experiment to evaluate water quality in terms of phosphorus, as influenced by the dissolved oxygen consumed by sediments. Three separate model column treatments, namely, raw, calcined, and sonicated oyster shell powders, were used in this experiment. Essential phosphorus fractions were examined to verify their roles in nutrient release from sediment based on correlation analyses. When treated with calcined or sonicated oyster shell powder, the sediment-water interface became "less anaerobic," thereby producing conditions conducive to partial oxidation and activities of aerobic bacteria. Sediment Oxygen Demand (SOD) was found to be closely correlated with the growth of algae, which confirmed an intermittent input of organic biomass at the sediment surface. SOD was positively correlated with exchangeable and loosely adsorbed phosphorus and organic phosphorus, owing to the accumulation of unbound algal biomass-derived phosphates in sediment, whereas it was negatively correlated with ferric iron-bound phosphorus or calcium fluorapatite-bound phosphorus, which were present in the form of "insoluble" complexes, thereby facilitating the free migration of sulfate-reducing bacteria or limiting the release from complexes, depending on applied local conditions. PCR-denaturing gradient gel electrophoresis revealed that iron-reducing bacteria were the dominant species in control and non-calcined oyster shell columns, whereas certain sulfur-oxidizing bacteria were identified in the column treated with calcined oyster powder.

• Structural Engineering and Mechanics
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• v.34 no.4
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• pp.491-505
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• 2010

A computational analysis of the nonlinear free vibration of corrugated annular plates with shallow sinusoidal corrugations under uniformly static ambient temperature is examined. The governing equations based on Hamilton's principle and nonlinear bending theory of thin shallow shell are established for a corrugated plate with a concentric rigid mass at the center and rotational springs at the outer edges. A simple harmonic function in time is assumed and the time variable is eliminated from partial differential governing equations using the Kantorovich averaging procedure. The resulting ordinary equations, which form a nonlinear two-point boundary value problem in spatial variable, are then solved numerically by shooting method, and the temperature-dependent characteristic relations of frequency vs. amplitude for nonlinear vibration of heated corrugated annular plates are obtained. Several numerical results are presented in both tabular and graphical forms, which demonstrate the accuracy of present method and illustrate the amplitude frequency dependence for the plate under such parameters as ambient temperature, plate geometry, rigid mass and elastic constrain.

• Structural Engineering and Mechanics
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• v.28 no.6
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• pp.749-765
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• 2008

Free axisymmetric vibrations of layered cylindrical shells of variable thickness are studied using spline function approximation techniques. Three different types of thickness variations are considered namely linear, exponential and sinusoidal. The equations of axisymmetric motion of layered cylindrical shells, on the longitudinal and transverse displacement components are obtained using Love's first approximation theory. A system of coupled differential equations on displacement functions are obtained by assuming the displacements in a separable form. Then the displacements are approximated using Bickley-spline approximation. The vibrations of two-layered cylindrical shells, made up of several types of layered materials and different boundary conditions are considered. Parametric studies have been made on the variation of frequency parameter with respect to the relative layer thickness, length ratio and type of thickness variation parameter.

• Bulletin of the Korean Chemical Society
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• v.12 no.1
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• pp.61-67
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• 1991

Conformational free energy calculations using an empirical potential function and the hydration shell model (a program CONBIO) were carried out on the neutral L-ascorbic acid (AA) in the unhydrated and hydrated states. The conformational energy was minimized from starting conformations which included possible conformations of six torsion angles in the molecule. The conformational entropy of each low energy conformation in both states was computed using a harmonic approximation. From the analysis of conformational free energies for AA in both states, intramolecular hydrogen bonds (HBs) are proved to be an essential factor in stabilizing the overall conformations, and cause the conformations in both states to be quite different from those in crystal. In the case of hydrated AA, there is a competition between HBs and hydration, and the hydration around the two hydroxyl groups attached to the acyclic side chain forces the molecule to form less stable HBs. The hydration affects strongly the conformational energy surfaces of AA. Several feasible conformations obtained in this work indicate that there exists an ensemble of several conformations in aqueous solution. The calculated probable conformations for the rotation about the C5-C6 bond of the acyclic side chain are trans and gauche +, which are in good agreement with results of NMR experiment.

• Structural Engineering and Mechanics
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• v.68 no.5
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• pp.527-536
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• 2018

The free vibration frequency responses of the graded flat and curved (cylindrical, spherical, hyperbolic and elliptical) panel structures investigated in this research considering the rectangular and tilted planforms under unlike temperature loading. For the numerical implementation purpose, a micromechanical model is prepared with the help of Voigt's methodology via the power-law type of material model. Additionally, to incur the exact material strength, the temperature-dependent properties of each constituent of the graded structure included due to unlike thermal environment. The deformation kinematics of the rectangular/tilted graded shallow curved panel structural is modeled via higher-order type of polynomial functions. The final form of the eigenvalue equation of the heated structure obtained via Hamilton's principle and simultaneously solved numerically using finite element steps. To show the solution accuracy, a series of comparison the results are compared with the published data. Some new results are exemplified to exhibit the significance of power-law index, shallowness ratio, aspect ratio and thickness ratio on the combined thermal eigen characteristics of the regular and tilted graded panel structure.

• Advances in nano research
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• v.10 no.2
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• pp.165-174
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• 2021

This paper based on Sanders theory aims to investigate the vibration of SWCNTs considering the clamped-simply supported, clamped-free, clamped-clamped and simply supported-simply supported end conditions. After developing the governing equation of the objective system, the Rayleigh-Ritz technique is implemented for the purpose of obtaining the frequency equation in the eigen form. In addition, the applicability of this model for the analysis of vibration of CNTs is examined with the effect of length and ratio of height-to-radius. A detailed description of different types of SWCNTs with different indices is provided in the theoretical methodology. The effect of extended length is stimulated with increasing the radii and the model is effective because it also predicts the effect of thickness on vibration of SWCNTs. For different boundary conditions, the present results are verified with earlier literature.

• Applied Chemistry for Engineering
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• v.28 no.4
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• pp.404-409
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• 2017

Natural polymer chitosan has been widely applied to medical fields due to its biochemical activities such as anticancer, antibacterial and lowering cholesterol in addition to biocompatibility and biodegradability. Currently, researches are being actively conducted to develop various drug-encapsulated chitosan nanoparticles for curing different diseases by applying chitosan to a drug delivery system. The free amine ($-NH_2$) group present in chitosan can bind to various hydrophobic groups by physical and chemical modification and the chitosan with hydrophobic groups can form shell-core nanoparticles by self-assembly when dispersed in water. In addition, an insoluble drug can increase the solubility against water when it was encapsulated in the core of chitosan nanoparticles. Also, the therapy effect can be maximized by minimizing side effects of drugs such as proteins, anticancer drugs and vaccines when they were encapsulated in the core of chitosan nanoparticles. Moreover, it is possible to control the particle size and release rate according to the hydrophobic group introduced to chitosan, so that it can be applied to a wide range of medical fields. The purpose of this review is to discuss the preparation and property of chitosan nanoparticles modified with various hydrophobic groups, and the application to drug delivery systems according to their property.

• Explosives and Blasting
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• v.35 no.3
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• pp.21-30
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• 2017

When explosives explode in water, the effect of post-explosion gas after explosion should be considered, unlike explosion in the air. During explosion in water, the propagation velocity of the explosion pressure is faster than when the explosion occurs in the air. The generated gas is diffused and trapped in the form of bubbles by water before the energy is dissipated. At this time, the bubble expands and contracts, creating a shock wave. In order to investigate this series of phenomena, a cylinder type steel water tank capable of observing the interior was fabricated and explosion experiments were conducted. In this study, a small amount of shell-free pentolite was exploded in water. Experiments were performed to observe the behavior of the generated gas bubble as well as to measure the shock wave generated. We designed the experimental method of underwater explosion and examined the results.

• Bulletin of the Society of Naval Architects of Korea
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• v.7 no.1
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• pp.1-12
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• 1970

The propeller induced pressure fluctuation around a ship's stern is one of the interesting problems from viewpoints of the noise and vibration. Most of the experimental works on the subject employ pressure transducer attached on hull surface near the propeller. In the technique, the measured pressure includes the hydrodynamic pressure transducer attached, if they exit. Hence, the separation of the additional pressure due to vibration from the measured pressure is essential for the determination of true values of the propeller induced pressure. In this paper, to contribute to the separation method, the author investigated the additional hydrodynamic pressure as below, based on the numerical calculation. (1) Hydrodynamic pressure on the body surface of two dimensional cylinders of some mathematical sections such as ellipse, rectangle, Lewis form of hypotrocoidal charactor and curvilinear-element section with chines oscillating vertically at high frequency in a free surface. (2) Hydrodynamic pressure on the surface of the shell plate in local vibration in an ideal fluid.

• Computers and Concrete
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• v.32 no.4
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• pp.393-398
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• 2023

This paper provides the free vibrations of chiral carbon nanotubes. The governing equations of Flügge theory is considered for vibration frequencies of chiral single walled carbon nanotubes. The solution of frequency equation is obtained from a novel model for better representation of stubby and short vibration characteristics of chiral tubes with clamped-clamped and clamped-simply supported end conditions. For the harmonic response of this tube, the model displacement function is adopted. The variational approach Rayleigh-Ritz method with kinetic and strain energies are used. The Lagragian function is differentiated with respect to unknown functions. The frequency equation is written in compact form to solve with MATLAB software. The frequencies of chiral SWCNTs for first ten aspect ratios as small level are investigated. The results shown as for decreasing the aspect rations, the frequencies are increases. The presented results of this model are verified with experimental and numerical results, which found as an excellent agreement.