• Title/Summary/Keyword: four point method

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A facile synthesis of transfer-free graphene by Ni-C co-deposition

  • An, Sehoon;Lee, Geun-Hyuk;Jang, Seong Woo;Hwang, Sehoon;Yoon, Jung Hyeon;Lim, Sang-Ho;Han, Seunghee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.129-129
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    • 2016
  • Graphene, as a single layer of $sp^2$-bonded carbon atoms packed into a 2D honeycomb crystal lattice, has attracted much attention due to its outstanding properties. In order to synthesize high quality graphene, transition metals, such as nickel and copper, have been widely employed as catalysts, which needs transfer to desired substrates for various applications. However, the transfer steps are not only complicated but also inevitably induce defects, impurities, wrinkles, and cracks of graphene. Furthermore, the direct synthesis of graphene on dielectric surfaces has still been a premature field for practical applications. Therefore, cost effective and concise methods for transfer-free graphene are essentially required for commercialization. Here, we report a facile transfer-free graphene synthesis method through nickel and carbon co-deposited layer. In order to fabricate 100 nm thick NiC layer on the top of $SiO_2/Si$ substrates, DC reactive magnetron sputtering was performed at a gas pressure of 2 mTorr with various Ar : $CH_4$ gas flow ratio and the 200 W DC input power was applied to a Ni target at room temperature. Then, the sample was annealed under 200 sccm Ar flow and pressure of 1 Torr at $1000^{\circ}C$ for 4 min employing a rapid thermal annealing (RTA) equipment. During the RTA process, the carbon atoms diffused through the NiC layer and deposited on both sides of the NiC layer to form graphene upon cooling. The remained NiC layer was removed by using a 0.5 M $FeCl_3$ aqueous solution, and graphene was then directly obtained on $SiO_2/Si$ without any transfer process. In order to confirm the quality of resulted graphene layer, Raman spectroscopy was implemented. Raman mapping revealed that the resulted graphene was at high quality with low degree of $sp^3$-type structural defects. Additionally, sheet resistance and transmittance of the produced graphene were analyzed by a four-point probe method and UV-vis spectroscopy, respectively. This facile non-transfer process would consequently facilitate the future graphene research and industrial applications.

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Distribution of Wildbirds According to Habitat Environment in Gap Stream (갑천의 서식지 환경에 따른 야생조류 분포에 관한 연구)

  • Lee, Joon-Woo;Lee, Do-Han;Paik, In-Hwan
    • Korean Journal of Agricultural Science
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    • v.30 no.1
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    • pp.41-58
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    • 2003
  • This study was conducted to investigate bird community and to suggest a proper way how to manage protect bird community in Gap stream. The survey was carried out over four sections by the line transect method and point counts method from September 2001 to August 2002. Natural stream region as Gasuwon Bridge - Mannyeon Bridge are observed birds were 11 orders 29 families 67 species, Artificial stream region as Mannyeon Bridge - Daedeok Bridge are observed birds were 6 orders 10 families 30 species, Daedeok Bridge - Wonchon Bridge are 8 orders 12 families 28 species, Wonchon Bridge - Gap Stream Bridge are 8 orders 18 families 40 species. All the observed birds in artificial stream region are 8 orders 19 families 47 species. Number of species in natural stream region was higher than artificial stream region owe to a various habitat environment such as forest, cultivated land, streamside forest, sandy plain, gravelly field, reedy field etc. and can not add with the interface and the usage of the human. Number of species in artificial stream region was lower than natural stream region owe to a simple habitat environment and the water ecosystem is severed with embankment block and grass plot with the land ecosystem. The furtherance of various habitat environment which considers the ecosystem like the natural stream as the water ecosystem is joined together with the land ecosystem is desired to attract various wildbirds in Gap stream. The design is desired with the maintenance of the stream to consider the stream corridor which plays ecological important role as connect the fragment habitats.

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Free Vibration Analysis of a Degenerated Timoshenko Beam Including the Effect of Shear Deformation and Rotatory Inertia (전단변형(剪斷變形)과 회전관성(回轉慣性)을 고려(考慮)한 Timoshenko 보의 자유진동(自由振動) 해석(解析))

  • Byun, Dong Kyun;Shin, Young Shik;Jang, Jong Tak
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.3 no.4
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    • pp.109-122
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    • 1983
  • An accurate thick beam element (TB4) which includes the effects of the shear deformation and rotatory inertia has been degenerated from the three dimensional continuum by employing the Timoshenko beam assumptions. The proposed TB4 element has four nodes and two degrees of freedom at each node, totally eight degrees of freedom. The transverse deflection W and plane rotation ${\theta}$ with the cubic interpolation functions are selected as nodal variables. The element characteristics are formulated by discretizing the beam equations of motion, using the Galerkin weighted residual method, and are numerically integrated by the reduced shear integration technique, using the three-point Gauss quadrature with the various shear coefficients. Several numerical examples are analyzed to demonstrate the accuracy and the monotonic convergence behavior of the proposed TB4 beam element. The result indicates that the TB4 element shows the more excellent performance and the monotonic convergence behavior than the other existing Timoshenko beam type elements for the whole range of the beam aspect ratios, in both static and free vibration analyses.

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Validation of Korean Nomenclature of NOC;Focused on 260 Outcomes (간호결과분류체계(Nursing Outcomes Classifications)의 한글 명명화에 대한 타당성 연구;260개 간호결과명을 중심으로)

  • Yoo, Hyung-Sook;Jang, In-Sun;Jeon, Mi-Soon;Kim, Hee-Girl;Nam, Hye-Kyung;Park, Yeon-Sook;Kim, Ok-Hyeon;Park, Hye-Ja;Hwang, Yun-Young;Lee, Jeong-Hee;Lee, Mi-Ja;Choi, Enn-Hee;Lee, In-Soon;Lee, Soon-Hee;Yom, Young-Hee;Chi, Sung-Ai
    • Journal of Korean Academy of Nursing Administration
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    • v.8 no.2
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    • pp.221-238
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    • 2002
  • Purpose: The purpose of this study was to develop and test the validity of the standardized Korean nomenclature of 260 Nursing Outcomes Classification(NOC) developed by Johnson and Mass at University of Iowa in 2000. Method: The four phases of the study were: (1) translation of the NOC into Korean by the Research Team, (2) nine nursing professors and nurses with various clinical backgrounds reviewed each nomenclature taking into consideration of definitions and outcome indicators. The modified Delphi method was used to determine the most appropriate nomenclature for each term, (3) 307 Clinical expert nurses more than three years field experiences were given a questionnaire to rate each Korean nomenclature using a 5 point Likert scale ranging from very inappropriate to very appropriate, and (4) final accordance of Korean Nomenclature. Result: The team determined that 260 Korean nomenclature was appropriately named. because the mean validity score of 260 outcomes was 3.90 and each of 260 Korean nomenclature had a score more than 3.00. Conclusion: Korean nomenclature of NOC can be used as a standardized language of nursing result in a computerized nursing information system.

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Fluxless Bonding Method between Sn and In Bumps Using Ag Capping Layer (Ag층을 이용한 Sn과 In의 무 플럭스 접합)

  • Lee Seung-Hyun;Kim Young-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.2 s.31
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    • pp.23-28
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    • 2004
  • We utilized Ag capping layer for fluxless bonding. To investigate the effect of Ag capping layer, two sets of sample were used. One set was bare In and Sn solders. The other set was In and Sn solders with Ag capping layer. In ($10{\mu}m$) and Sn ($10{\mu}m$) solders were deposited on Cu/Ti/Si substrate using thermal-evaporation, and Ag ($0.1{\mu}m$) capping layers were deposited on In and Sn solders. Solder joints were made by joining two In and Sn deposited specimens at $130^{\circ}C$ for 30 s under 0.8, 1.6, 3.2 MPa using thermal compression bonder. The contact resistance was measured using four-point probe method. The shear strength of the solder joints was measured by the shear test of cross-bar sample in the direction. The microstructure of the solder joints was characterized with SEM and EDS. In and Sn solders without Ag capping layers were only bonded at $130^{\circ}C$ under high bonding pressure. Also the shear strength of the In-Sn solder joints under was lower than that of the Ag/In-Ag/Sn solder joints. The resistance of the solder joints was $2-4\;m{\Omega}$ The solder joints consisted of In-rich phase and Sn-rich phase and the intermixed compounds were found at the interface. As bonding pressure increased, the intermixed compounds formed more.

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Assessment of Cerebral Collateral Circulation Using $^{99m}Tc$-Hexamethyleneamine Oxime (HMPAO) SPECT During Internal Carotid Artery Balloon Test Occlusion (내경동맥 풍선 시험 결찰술(BTO)시 $^{99m}Tc$-HMPAO 뇌 SPECT를 이용한 대뇌 측부 순환의 평가)

  • Ryu, Young-Hoon;Yun, Mi-Jin;Chung, Tae-Sub;Lee, Jong-Doo;Park, Chang-Yun
    • The Korean Journal of Nuclear Medicine
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    • v.29 no.1
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    • pp.22-30
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    • 1995
  • To predict preoperatively the safety of permanent occlusion of an internal carotid artery with $^{99m}Tc$-HMPAO brain single photon emission computed tomography(SPECT) from an objective point of view, Twenty-four patients underwent balloon test occlusion (BTO) of the internal carotid arteries because of neck and skull base tumors. The authors assessed the uptake of both middle cerebral artery territories before and during BTO with $^{99m}Tc$-HMPAO brain SPECT using semiquantitative analysis method and compared the results with other factors(neurologic examination, arterial stump pressure and electroenceph-alogram). Nineteen patients had not experienced neurological deteriorating or any problem during BTO. Their comparative uptakes of the middle cerebral artery territories were 95 to 101% of the pre-BTO state. The remaining five patients showed severe neurologic symptoms such as transient hemiplegia and unconsciousness. Their comparative uptake of the middle cerebral artery territories were 77 to 85% of the pre-BTO state, and were well matched with other factors. $^{99m}Tc$-HMPAO brain SPECT before and during BTO seems to be a simple and objective method for prediction of permanent neurologic deficits when the comparative uptake of middle cerebral artery territories during BTO is lower than 85% of that before BTO.

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Data Qualification of Optical Emission Spectroscopy Spectra in Resist/Nitride/Oxide Etch: Coupon vs. Whole Wafer Etching

  • Kang, Dong-Hyun;Pak, Soo-Kyung;Park, George O.;Hong, Sang-Jeen
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.433-433
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    • 2012
  • As the requirement in patterning geometry continuously shrinks down, the termination of etch process at the exact time became crucial for the success in nano patterning technology. By virtue of real-time optical emission spectroscopy (OES), etch end point detection (EPD) technique continuously develops; however, it also faced with difficulty in low open ratio etching, typically in self aligned contact (SAC) and one cylinder contact (OCS), because of very small amount of optical emission from by-product gas species in the bulk plasma glow discharge. In developing etching process, one may observe that coupon test is being performed. It consumes costs and time for preparing the patterned sample wafers every test in priority, so the coupon wafer test instead of the whole patterned wafer is beneficial for testing and developing etch process condition. We also can observe that etch open area is varied with the number of coupons on a dummy wafer. However, this can be a misleading in OES study. If the coupon wafer test are monitored using OES, we can conjecture the endpoint by experienced method, but considering by data, the materials for residual area by being etched open area are needed to consider. In this research, we compare and analysis the OES data for coupon wafer test results for monitoring about the conditions that the areas except the patterns on the coupon wafers for real-time process monitoring. In this research, we compared two cases, first one is etching the coupon wafers attached on the carrier wafer that is covered by the photoresist, and other case is etching the coupon wafers on the chuck. For comparing the emission intensity, we chose the four chemical species (SiF2, N2, CO, CN), and for comparing the etched profile, measured by scanning electron microscope (SEM). In addition, we adopted the Dynamic Time Warping (DTW) algorithm for analyzing the chose OES data patterns, and analysis the covariance and coefficient for statistical method. After the result, coupon wafers are over-etched for without carrier wafer groups, while with carrier wafer groups are under-etched. And the CN emission intensity has significant difference compare with OES raw data. Based on these results, it necessary to reasonable analysis of the OES data to adopt the pre-data processing and algorithms, and the result will influence the reliability for relation of coupon wafer test and whole wafer test.

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Inferring Regional Scale Surface Heat Flux around FK KoFlux Site: From One Point Tower Measurement to MM5 Mesoscale Model (FK KoFlux 관측지에서의 지역 규모 열 플럭스의 추정 : 타워 관측에서 MM5 중규모 모형까지)

  • Jinkyu Hong;Hee Choon Lee;Joon Kim;Baekjo Kim;Chonho Cho;Seongju Lee
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.5 no.2
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    • pp.138-149
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    • 2003
  • Korean regional network of tower flux sites, KoFlux, has been initiated to better understand $CO_2$, water and energy exchange between ecosystems and the atmosphere, and to contribute to regional, continental, and global observation networks such as FLUXNET and CEOP. Due to heterogeneous surface characteristics, most of KoFlux towers are located in non-ideal sites. In order to quantify carbon and energy exchange and to scale them up from plot scales to a region scale, applications of various methods combining measurement and modeling are needed. In an attempt to infer regional-scale flux, four methods (i.e., tower flux, convective boundary layer (CBL) budget method, MM5 mesoscale model, and NCAR/NCEP reanalysis data) were employed to estimate sensible heat flux representing different surface areas. Our preliminary results showed that (1) sensible heat flux from the tower in Haenam farmland revealed heterogeneous surface characteristics of the site; (2) sensible heat flux from CBL method was sensitive to the estimation of advection; and (3) MM5 mesoscale model produced regional fluxes that were comparable to tower fluxes. In view of the spatial heterogeneity of the site and inherent differences in spatial scale between the methods, however, the spatial representativeness of tower flux need to be quantified based on footprint climatology, geographic information system, and the patch scale analysis of satellite images of the study site.

A study on the Realtime Update of the Digital-Map by the General Survey Map (일반측량성과도에 의한 수치지도의 수시갱신방법 연구)

  • Lee, Sang-Gil;Kwon, Jay-Hyoun;Jeon, Jae-Han
    • Journal of Korean Society for Geospatial Information Science
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    • v.15 no.3
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    • pp.19-26
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    • 2007
  • The renewal update of the digital map constructed through NGIS has been conducted for the enhancement of usage, maintenance so that the latest data is guaranteed. The total update has been done every five years for five regions of the country using aerial photographs and satellite images. By launching the third phase of NGIS, the updating plan was changed from total to total or partial update including the real time update scheme. Furthermore, the update period was improved from five to two years and four years for a large and a small city, respectively. Therefore, it is necessary to develope a matching technique which combines various geographic information (such as drawing map, surveying drawing and map) with exact position on the digital map. In this study, we developed a matching algorithm based on central point and suggested a method which uses general surveying drawing for revision/update of the digital map. The general survey is conducted when a civilian development on lands are approved. Thus, the outcome from the survey, which is the general survey drawing, contains the latest various contents such as road, building, water pipe and manhole. A consistent and efficient method using the general survey drawing for near real time update of the digital map by applying the developed matching algorithm is presented.

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Optimization of Esterification of Jatropha Oil by Amberlyst-15 and Biodiesel Production (Amberlyst-15를 이용한 자트로파 오일의 에스테르화 반응 최적화 및 바이오디젤 생산)

  • Choi, Jong-Doo;Kim, Deog-Keun;Park, Ji-Yeon;Rhee, Young-Woo;Lee, Jin-Suk
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.194-199
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    • 2008
  • In this study, the effective method to esterify the free fatty acids in jatropha oil was examined. Compared to other plant oils, the acid value of jatropha oil was remarkably high, 11.5 mgKOH/g. So direct transesterification by a base catalyst was not suitable for the oil. After the free fatty acids were esterified with methanol, jatropha oil was transesterified. The activities of four solid acid catalysts were tested and Amberlyst-15 showed the best activity for the esterification. After constructing the experiment matrix based on RSM and analyzing the statistical data, the optimal esterification conditions were determined to be 6.79% of methanol and 17.14% of Amberlyst-15. After the pretreatment, jatropha biodiesel was produced by the transesterification using KOH in a pressurized batch reactor. Jatropha biodiesel produced could meet the major specifications of Korean biodiesel standards; 97.35% of FAME, 8.17 h of oxidation stability, 0.125% of total glycerol and $0^{\circ}C$ of CFPP.