• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.93-94
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• 2023

Through the industrial revolution that began in the 18th century, the amount of carbon dioxide in the atmosphere increased rapidly as humans used fossil energy such as coal and oil as fuel for steam engines and factory machines. The amount of carbon dioxide emitted while producing cement, the main material of concrete used in construction, is large enough to account for 5-8% of the world's carbon dioxide emissions. In this study, Non cement-based matrix were used to reduce carbon dioxide emissions from cement production. Red mud is an industrial by-product generated in the manufacturing process of aluminum hydroxide using bauxite, and more than 120 million tons are produced worldwide. In addition, red mud is a porous material that can be physically adsorbed, and causes a photocatalytic reaction of TiO₂ to remove harmful substances such as nitrogen oxide formaldehyde in the air and chemically adsorbs ammonia and hydrogen sulfide. Therefore, this study aims to examine the physical properties of the matrix by mixing red mud, an industrial by-product with good adsorption performance, into the Non cement-based matrix.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.4
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• pp.152-158
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• 2019

Measure the type and content of VOCs for A-company epoxy coating and B-company floor coating(Type A, B), which are used as flooring materials for parking lots. Than the VOCs used gas detectors to measure gas emissions, assuming the worst environment to reduce errors in external environments in the formaldehyde, toluene and xylene harmful to workers and tenants. As a result, A-company epoxy coating has the largest amount of VOCs, and compared to A-company epoxy coating, B-company floor coating of A type represented about 79% less and B type about 96% less. In addition, A-company epoxy coating was also the highest in gas emission measurement for formaldehyde, toluene and xylene using gas detector after 1 hour and 8 hours in closed environment conditions. B-company floor coating A type was less than A-company epoxy coating, which was about 42.3% less measured. And type B satisfied all TWA even in closed environment conditions.

• Journal of the Korean Wood Science and Technology
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• v.40 no.3
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• pp.164-176
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• 2012

In the present study, rapeseed flour (RSF), which is a by-product from the production of edible oil and biodiesel extracted from rapeseed, was used to develop alternative adhesives for the production of plywood panels. To examine the effects of the enzyme on the adhesive properties and formaldehyde emission of the RSF-based adhesive resins, three enzymes, such as cellulase (CEL), pectinase (PEC) and protease (ALC), were used either separately or together. As a crosslinking agent, PF prepolymers, which were prepared with 1.5, 1.8 and 2.1 mole formaldehyde and 1 mol phenol (1.8-, 2.1- and 2.4-PF), were added into the RSF hydrolyzates. The adhesive resins formulated with CEL- or CEL-PEC-RSF hydrolyzates and 1.8-F/P PF prepolymers exhibited excellent adhesive strengths and formaldehyde emission. The tensile shear strength and formaldehyde emission of the plywood panels bonded with the formulate resins were satisfied with the minimum requirement of the KS standard for ordinary plywood panels (0.6 N/$mm^2$). In addition, formaldehyde emissions of the plywood panels approached to that of E0 specified in the KS standard (0.5 mg/${\ell}$), and even had much better than those of commercial UF glue mixes. Overall, the use of RSF-based adhesive resins for the production of plywood panels might provide durable adhesive properties and an environmentally friendly substitute for petroleum-based adhesive resins. However, further researches - the increase of solid content of RSF-based adhesives for reducing press time and the microscopic observation of plywood specimen for identifying the relationship between tensile shear strength and the penetration of adhesives into wood structure - are required to commercialize the RSF-based adhesives.

• Journal of the Korean Wood Science and Technology
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• v.36 no.3
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• pp.30-38
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• 2008

Petroleum-based resin adhesives have extensively been used for the production of wood panels. However, with the increase of manufacturing cost and the environmental issue, such as the emission of volatile organic compounds, of the adhesive resins, it is necessary to be developed new adhesive systems. In this study, the potential of okara, which is a residue wasted from the production of tofu, for the development of bio-based adhesives was investigated. At first, the physical and chemical properties of okara were examined. After okara was hydrolyzed in acidic and/or alkaline solutions, okara-based adhesive resins were formulated with the mixtures of the okara hydrolyzates and phenol formaldehyde (PF) prepolymer. The adhesive resins were used for the fabrication of plywood panels, and then the adhesive strength and formaldehyde emission of the plywood panels were measured to examine the applicability of the resin adhesives for the production of plywood panels. The solids content and pH of the okara used in this study were around 20% and weak acidic state, respectively. In the analysis of its chemical composition, the content of carbohydrate was the highest, and followed by protein. The shear strengths of plywood fabricated with okara-based resin adhesives exceeded a minimum requirement of KS standard for ordinary plywood, but its wood failure did not reach the minimum requirement. In addition, the formaldehyde emissions of all plywood panels were higher than that of E1 specified in the KS standard. Based on these results, okara has the potential to be used as a raw material of environmentally friendly adhesive resin systems for the production of wood panels, but further researches - biological hydrolysis of okara and various formulations of PF prepolymer - are required to improve the adhesive strength and formaldehyde emission of okara-based resin adhesives.

• Environmental Engineering Research
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• v.12 no.2
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• pp.72-80
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• 2007

Experiments were conducted to identify the emissions from the car air freshener and to identify the formation of ultra-fine particles and secondary gaseous compounds during the ozone-initiated oxidations with emitted VOCs. The identified primary constituents emitted from the car air freshener in this study were $\alpha$-pinene, $\beta$-pinene, $\rho$-cymene and limonene. Formation of ultra-fine particles (4.4-160 nm) was observed when ozone was injected into the chamber containing emitted monoterpenes from the air freshener. Particle number concentrations, particle mass concentrations, and surface concentrations were measured in time dependent experiments to describe the particle formation and growth within the chamber. The irritating secondary gaseous products formed during the ozone-initiated reactions include formaldehyde, acetaldehyde, acrolein, acetone, and propionaldehyde. Ozone concentration (50 and 100 ppb) and temperature (30 and $40^{\circ}C$) significantly affect the formation of particles and gaseous products during the ozone-initiated reactions. The results obtained in this study provided an insight on the potential exposure of particles and irritating secondary products formed during the ozone-initiated reaction to passengers in confined spaces.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.22 no.5
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• pp.304-313
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• 2010

During recent years, various studies have demonstrated that indoor chemical pollution causes health problem and also negatively affect the performance of work by occupants. Building materials have been concerned as indoor chemical sources. Some of guidelines and certification system has been developed and resulted as dramatic decrease of harmful indoor chemicals such as formaldehyde and volatile organic compounds. Also, Home furniture and electrical devices has been concerned as one the primary influence the indoor chemical concentration in residential spaces. It is found that various kinds of electric home appliances have a significant source of chemical emission in indoor environments. In this study, the methodologies of detecting harmful chemicals from various kinds of products has been developed with large chamber measurement system and suggest some of the evaluation method for the chemicals from the home appliances as TV sets.

• Journal of ILASS-Korea
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• v.20 no.4
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• pp.207-216
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• 2015

Recently, the researches for air pollutant control technologies have been performing in Korea, while considering an one of the latest main topics as problems on air pollutant control. However, it is difficult to investigate emission amount of air pollutant by passenger cars, because of lack of the domestic information about mobile source; the number of research institutes are less in the whole. Especially, the informations on registered numbers and emissions of motorcycles are less. Thus, in this study, the analysis that is based on experimental results was conducted for finding out source profiling and emission characteristics on motorcycles exhaust. For these experiments, the domestic motorcycles were chosen and evaluated by EURO III standard. From the result, controlled pollutants (CO, HC, NOx) were met to EURO III, but low displacement motorcycles showed a higher incomplete combustion reaction than that of 250 cc motorcycles. Additionally, uncontrolled pollutants (BTEX and 1,3-butadiene) were decreased with increasing a displacement of motorcycles. However, the emission trend of aldehydes was not followed that of those; the formaldehyde ratio increased upto approximately 33%, with increasing a displacement of motorcycles. In the future, it would be used to support the CAPSS as basic data of Korea.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.24 no.6
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• pp.467-475
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• 2012

Recently, residents have been spending almost 90% of their time indoors, which presents a higher risk from inhalation of pollutants than when spending time outdoors. Therefore, controlling indoor air quality became important. It is reported that the lung diseases and mortality for occupants are increased when there is high density of ozone which is one of the pollutants among the indoor air. In addition, the reactions between ozone and building materials produce VOCs and formaldehyde. The studies to eliminate the ozone by building materials have been actively investigated. However, ozone removal and secondary pollutants from ozone reactions with building materials have not been reported in Korea. For this reason, the aim of this study is to introduce ozone removal by HVAC filters, various building materials, and eco-friendly building materials including the quantity of secondary pollutant emissions.

• Fire Science and Engineering
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• v.29 no.4
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• pp.49-56
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• 2015

Toxic gases from five types of interior building materials were investigated according to Naval Engineering Standard (NES) 713. The materials were plywood, indoor wall coverings (wood wall plate members and pine wood), reinforced Styrofoam insulation, laminate flooring, and PVC. Specimens were measured using an NES 713 toxicity test apparatus to analyze the hazardous substances in combustion gas from the materials. We used the US Department of Defense standard (MIL-DTL, Military Standard) to calculate the toxicity index of the combustion gas. Emissions of $CO_2$ from all specimens did not exceed the NES 713 limit of 100,000 ppm. The amount of CO gas emissions from reinforced Styrofoam insulation was 6,098 ppm. 25 ppm and 49 ppm of formaldehyde were released from the reinforced Styrofoam insulation and PVC flooring, respectively. These values were less than the limit of 400 ppm. The highest emissions were from $NO_X$ emitted by plywood and were above the limit of 250 ppm. The toxicity index of the specimens were calculated as 5.19 for plywood, 4.13 for PVC flooring, 2.35 for reinforced Styrofoam insulation, 2.34 for laminate flooring, and 1.22 for indoor wall coverings (pine wood). Our research helps us to understand the properties of these five interior materials by analyzing the combustion gas and explaining the toxicity of constituents and the toxicity index. Also, it would be useful for giving fundamentals to guide the safe use of interior materials for applications.

• Journal of the Korean Wood Science and Technology
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• v.38 no.4
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• pp.323-332
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• 2010

Petroleum-based adhesive resins have extensively been used for the production of wood panels. However, it is necessary to develop environmentally friendly adhesive resins due to the increase of manufacturing cost and the environmental issue, such as the emission of volatile organic compounds, of the pertroleum-based adhesive resins. This study was conducted to formulate environmentally friendly adhesive resins using by rapeseed flour (RSF), which is the by-product of bio-diesel produced from rapeseed, for replacing petroleum-based adhesives with them. To formulate RSF-based adhesive resins, RSF was hydrolyzed in de-ionized water, 1% and 3% sodium hydroxide solutions. As a crosslinking agent, PF prepolymers were prepared with 1.8, 2.1 and 2.4 mol formaldehyde and 1 mol phenol (1.8-, 2.1- and 2.4-PF), and then mixed with RSF hydrolyzates to complete the formulation of RSF-based adhesive resins. The RSF-based adhesive resins were applied to fabricate 3-ply plywood panels. The solid content of RSF-based adhesive resins were ranged from 26.08% to 36.12% depending on the hydrolysis condition of RSF and PF prepolymer type with a high viscosity. The tensile shear strength and wood failure of plywood fabricated with RSF-based adhesive resins exceeded a minimum requirement of KS standard for ordinary plywood regardless of the hydrolysis condition of RSF and PF prepolymer type. Formaldehyde emissions of the plywood panels fabricated with 1.8-PF and RSF hydrolyzates were lower than that of E0 specified in the KS standard. Based on the results, RSF might be used as a raw material of environmentally friendly adhesives for the production of plywood panels, but further researches - the increase of solid content of RSF-based adhesives for reducing press time and the microscopic observation of plywood specimen for identifying the relationship between tensile shear strength and the penetration of adhesives into wood structure - are required to commercialize the RSF-based adhesives.