• Title/Summary/Keyword: foams

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The Preparation and Property of Carbon Foams from Carbon Black Embedded Pitch Using PU Template (카본블랙이 내첨된 핏치로부터 폴리우레탄 조공제를 이용한 탄소 폼의 제조 및 특성)

  • Lee, Sangmin;Kim, Ji-Hyun;Jeong, Euigyung;Lee, Young-Seak
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.268-273
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    • 2016
  • To improve mechanical strength of carbon foams, the carbon black (CB) added carbon foams were fabricated by impregnating different contents of carbon black (CB) and mesophase pitch using polyvinyl alcohol (PVA) solution into polyurethane foam and being followed by heat treatment. The cell wall-thicknesses of carbon foams were controlled by adding amounts of CB, and it was confirmed that the compressive strength of carbon foams was increased as increasing cell wall-thickness. The compressive strength had the highest value of $0.22{\pm}0.05MPa$ with the highest bulk density of $0.44g/cm^3$ when adding 5 wt% CB in carbon foam. However, the thermal conductivity was decreased by adding CB in carbon foam. The results indicated that the thermal conductivities of carbon foams were reduced by increased interlayer spacing ($d_{002}$) with the addition of CB in carbon foams.

A Morphological Study on the Titanium-Oxide Foams Processed Using Freeze-Casting (동결 주조법으로 제조된 티타늄 옥사이드 폼의 구조 연구)

  • Yoon, Hyunjung;Choe, Heeman;Choi, Hyelim
    • Journal of the Korean Ceramic Society
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    • v.49 no.5
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    • pp.427-431
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    • 2012
  • The $TiO_2$ foam synthesized using freeze-casting is a promising photocatalyst and photovoltaic electrode for a variety of energy applications, because the freeze-casting technique is easy to use, cheap, and suitable for mass-production. Despite its several advantages, little scientific information is available on the processing and morphology of the $TiO_2$ foams processed by freeze-casting. In particular, no systematic study has been performed on the microstructural evolution and morphological change of the rutile-phase $TiO_2$ foams during sintering. Therefore, in the present study, several $TiO_2$ foam samples were produced using the freeze-casting technique, which were then sintered at a relatively high temperature of $1200^{\circ}C$ for 1, 2, and 4 h to compare the morphological changes in the microstructure and to understand the effects of processing parameters of the rutile-phase $TiO_2$ foams. The foam ligament size increased near linearly with increasing sintering time whereas the average pore size decreased only slightly with increasing sintering time, with changes in particle morphology from sphere to rod and complete phase transformation from anatase to rutile.

Effect of Process Parameters of P/M and Induction Heating on the Cell Morphology and Mechanical Properties of 6061 Aluminum Alloy (P/M법과 유도가열 공정변수가 6061 알루미늄 합금의 미세기공과 기계적 성질에 미치는 영향)

  • 강충길;윤성원
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.6
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    • pp.222-229
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    • 2003
  • The purpose of this study is to evaluate the mechanical properties of 6061 Al foams, which were fabricated by P/M and multi-step induction heating method, and to build the database, which is needed for computer aided modeling or foam components design. Aluminium foams, consisting of solid aluminium and large quantities of porosities, is widely used in automotive, aerospace, naval as well as functional applications because of its high stiffness at very low density, high impact energy absorption, heat and fire resistance, and greater thermal stability than any organic material. In this study, 6061 Al foams were fabricated for variation of fraction of porosities (%) according to porosities (%)-final heating temperature ( $T_{a3}$) curves. Mechanical properties such as compressive strength, energy absorption capacity, and efficiency were investigated to evaluate the feasibility of foams as crash energy absorbing components. Moreover, effect of the surface skin thickness on plateau stress and strain sensitivity of the 6061 Al foams with low porosities (%) were studied.d.

An Experimental Study for the Effect of the Density of Polypropylene Foams on the Absorption of Impact Energy (폴리프로필렌 폼 밀도가 충격에너지 흡수에 미치는 영향에 대한 실험적 연구)

  • Lee, Yoon-Ki;Sung, Won-Suk;Lim, Dong-Jin;Sun, Shin-Kyu
    • Journal of the Korean Society of Safety
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    • v.23 no.6
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    • pp.21-27
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    • 2008
  • Polypropylene(PP) foams are widely used as protective materials such as automotive bumper and safety helmet, but whose dynamic behaviour are not well defined. In this paper, the compression tests by Split Hopkinson Pressure Bar were conducted to obtain the stress-strain curve and to investigate the effect of density on the absorption of impact energy in the PP foams. Three kinds of foams were chosen depending upon the density. The result of the experiment has revealed that the stiffness of the low-density PP foam is remarkably increased at high strain rate compared with that of the high-density PP foam. And it is also shown that the absorption of impact energy are greatly influenced by the density of PP foam. These results are expected to be utilized for the development of a protective structure with polymer foams.

Thermal Properties and Sound-Damping Characteristics of Polyurethane Nanocomposite Foams (폴리우레탄 나노복합 발포체의 열적 성질 및 흡음 특성)

  • Lee, Jun Mo;Ha, Chang Sik
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.3-8
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    • 2010
  • Thermal properties, flame retardant property, and sound-damping properties of polyurethane (PU) nanocomposite foams prepared with oligomeric 1,2-propanediol isobutyl polyhedral silsesquioxane (POSS) were investigated. It was found that the PU nanocomposite foams showed good sound-damping performances comparing to the PU foams without POSS.

Processing and Mechanical Properties of Ni-Cr and Ni-Cr-Al Foams by Pack-Cementation

  • Dunand, David;Choe, Hui-Man
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.19.1-19.1
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    • 2009
  • Open-cell Ni-Cr and Ni-Cr-Al(with gamma/gamma prime microstructure typical of Bi-base super alloys) foams are manufactured by pack-cementation at $1000{\boxplus}$degrees C, followed by homogenization at $1200{\boxplus}C$. The resulting alloyed foams retain the low relative densities (less than 3.5 wt.%). The oxidation behavior of Ni-Cr foams turns out to be identical to that of bulk Ni-Cr alloys, after taking into account the foam's higher surface area. The room-temperature compressive behavior of the Ni-Cr and Ni-Cr-Al is compared to model predictions. Additionally, the foam creep behavior, measured between 680 and $825{\boxplus}C$ in the stress range of 0.1-0.3 MPa, compared to two analytical models, namely strut compression and strut bending as high-temperature deformation modes.

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Tensile Properties of Plate Attached Open Cell Aluminium Foams (판이 부착된 개포형 발포 알루미늄의 인장특성)

  • Kang, Bok-Hyun;Bu, Sung-Duk;Kim, Ki-Young
    • Journal of Korea Foundry Society
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    • v.27 no.2
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    • pp.83-87
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    • 2007
  • Aluminum plates of the same materials as the foam were attached by the casting process inserting the foam as a core to investigate the tensile property of open cell foams. Tensile properties of the open cell 6063 aluminum alloy foam of $10{\sim}30$ PPI were measured before and after heat treatment. Densities of test specimens were between 0.14 and $0.29g/cm^3$. Tensile strength of the 6063 aluminum foam after heat treatment showed little change. C values were in the range of $0.41{\sim}0.87$ for as cast foams and $0.11{\sim}0.27$ for T6 heat treated foams in the eq. of ${\sigma}^* _{pl}/{\sigma}_{ys}=C({\rho}/{\rho}_s)^{1.5}$, and increased with increase in the cell size.

Pressure-Dependent Yield Criterion For Polymeric Foams (폴리머폼의 압력종속항복조건에 관한 연구)

  • 이희봉
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2000.04a
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    • pp.17-20
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    • 2000
  • Polymeric foams are excellent energy absorber and have found a wide range of applications especially in the automotive industry. The purpose of the present study is to develop experimental and theoretical methodology to characterize the pressure dependent yield behavior of polymeric foams. For the compression test in a triaxial stress sate a specially designed device was placed in a press machine to produce and control oil pressure. From the experiment results it was observed that the size of Mother circles is changed with mean normal stress in contrast to general metal. Then the Coulomb-Mohr criterion was applied to the data.

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Emulsion rheology and properties of polymerized high internal phase emulsions

  • Lee, Seong-Jae
    • Korea-Australia Rheology Journal
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    • v.18 no.4
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    • pp.183-189
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    • 2006
  • High internal phase emulsions are highly concentrated emulsion systems consisting of a large volume of dispersed phase above 0.74. The rheological properties of high internal phase water-in-oil emulsions were measured conducting steady shear, oscillatory shear and creep/recovery experiments. It was found that the yield stress is inversely proportional to the drop size with the exponent of values between 1 and 2. Since the oil phase contains monomeric species, microcellular foams can easily be prepared from high internal phase emulsions. In this study, the microcellular foams combining a couple of thickeners into the conventional formulation of styrene and water system were investigated to understand the effect of viscosity ratio on cell size. Cell size variation on thickener concentration could be explained by a dimensional analysis between the capillary number and the viscosity ratio. Compression properties of foam are important end use properties in many practical applications. Crush strength and Young's modulus of microcellular foams polymerized from high internal phase emulsions were measured and compared from compression tests. Of the foams tested in this study, the foam prepared from the organoclay having reactive group as an oil phase thickener showed outstanding compression properties.

Effects of Amine Catalysts on Structure of Polyurethane Foams

  • Furukawa, Mutsuhisa;Takamatsu, Katsuhiro
    • Elastomers and Composites
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    • v.34 no.4
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    • pp.285-291
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    • 1999
  • Effects of catalysts on network structure, hard segment length and distribution of polyurethane foams in the absence of catalysts were investigated. CFC free all MDI-based poly urethane foams were prepared from poly(ethylene adipate)glycol, 4,4'-diphenylmethane diisocyanate, and water. Amino catalysts used were 1,4-diazabicyclo[2,2,2]octane(DABCO), N, N,N',N'-tetramethyl--hexane-1,6-diamine(MR), bis(2-methylamino ethyl)ether(ET), 1,8-diazabicyclo-[5,4,0]-undecene-7(DBU). Dibutyltindilaurate(DBTL) as control was also used. Hard segment components of polyurethane foams were obtained by a selective degradation of polyester chains with 0.01N KOH-methanol solution. The PUFs with DBU catalyst contained more amount of isocyanurate components than other PUFs. On the other hand, the PUFs with ET, MR, DBTL catalysts contained more amount of allophanate and biuret component than the other PUFs.

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