• 공업화학
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• 제27권4호
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• pp.371-379
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• 2016

사용 후 발생되는 폐 LCD판넬용 유리의 재활용 방안을 마련하고자 별도의 전처리 없이 폐 LCD판넬을 습식분쇄함으로서 발포체 제조용 원료유리로 사용가능한 폐 붕규산유리의 회수 방법을 조사하였으며, 이렇게 회수된 폐 붕규산유리를 사용하여 발포체의 제조를 시도하였다. 입도 270 mesh 이하의 크기로 분쇄 조절된 폐 붕규산유리를 대상으로 폐 붕규산분말 100 g에 대해 발포제로서 탄소분을 0.3 중량 분율, 추가 발포조제로서 $Na_2CO_3$, $Na_2SO_4$, $CaCO_3$를 각각 1.5 중량 분율이 되도록 첨가한 원료 유리분말을 발포소성온도 $950^{\circ}C$에서 20 min간 발포를 진행함으로서 밀도가 $0.3g/cm^3$ 이하되는 발포체를 제조할 수 있었다. 또한 원료 유리에 추가적으로 $SiO_2$ 또는 $H_3BO_3$를 첨가함으로서 얻어지는 발포체에 효과적으로 개기공을 형성할 수 있었으며, 개기공의 형성은 흡음 등 새로운 기능을 가진 발포체의 제조 가능성을 보여주었다.

• 한국세라믹학회지
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• 제46권1호
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• pp.16-23
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• 2009

The porous pellets were prepared from porphyry by slurry foaming method. The effect of sintering temperatures on pore structure of porous porphyry pellets with different extension ratio ($E_R$) was investigated by specific surface area, water absorption and porosity, which changed with sintering temperatures. When the sintering temperatures increased from $975^{\circ}C$ to $1075^{\circ}C$, specific surface area and water absorption of the all samples decreased. In case of the sample with an equal sintering temperature, $E_R=3.0$ pellets had little influence on pore structure compared to the $E_R=2.0$ pellets. As a results, it was shown by SEM that facilitated formation of micro pores at $E_R=2.0$ pellets shrunk increasingly after sintering process. At $E_R=3.0$ and sintering temperature at $1025^{\circ}C$, optimum conditions of the porous porphyry porous pellets was found. Also, Escherichia coli removal efficiency of the silver-containing porphoyry porous pellets was measured for the feasibility as a antibacterial media. The antibacterial activity of prepared silver-containing sample was maintained above 90% for 40 days.

• 한국재료학회지
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• 제26권8호
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• pp.449-453
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• 2016

$HA(hydroxyapatite)/{\beta}-TCP$ (tricalcium phosphate) biomaterial (BCP; biphasic calcium phosphate) is widely used as bone cement or scaffolds material due to its superior biocompatibility. Furthermore, $NH_4HCO_3$ as a space holder (SH) has been used to evaluate feasibility assessment of porous structured BCP as bone scaffolds. In this study, using a spark plasma sintering (SPS) process at 393K and 1373K under 20MPa load, porous $HA/{\beta}-TCP$ biomaterials were successfully fabricated using $HA/{\beta}-TCP$ powders with 10~30 wt% SH, TiH2 as a foaming agent, and MgO powder as a binder. The effect of SH content on the pore size and distribution of the BCP biomaterial was observed by scanning electron microscopy (SEM) and a microfocus X-ray computer tomography system (SMX-225CT). The microstructure observations revealed that the volume fraction of the pores increased with increasing SH content and that rough pores were successfully fabricated by adding SH. Accordingly, the cell viabilities of BCP biomaterials were improved with increasing SH content. And, good biological properties were shown after assessment using Hanks balanced salt solution (HBSS).

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2009년도 하계학술발표대회 논문집
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• pp.645-649
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• 2009

Liquid desiccant cooling technology can supply cooling by using waste heat and solar heat which are hard to use effectively. For compact and efficient design of a dehumidifier, it is important to sustain sufficient heat and mass transfer surface area for water vapor diffusion from air to liquid desiccant on heat exchanger. In this study, the plate type heat exchanger is adopted which has extended surface, and hydrophilic coating and porous layer coating are adopted to enhance surface wettedness. PP(polypropylene) plate is coated by porous layer and PET(polyethylene terephthalate) non-woven fabric is coated by hydrophilic polymer. These coated surfaces have porous structure, so that falling liquid film spreads widely on the coated surface foaming thin liquid film by capillary force. The temperature of liquid desiccant increases during dehumidification process by latent heat absorption, which leads to loss of dehumidification capacity. Liquid desiccant is cooled by cooling water flowing in plate heat exchanger. On the plate side, the liquid desiccant can be cooled by internal cooling. However the liquid desiccant on extended surface should be moved and cooled at heat exchanger surface. Optimal mixing and distribution of liquid desiccant between extended surface and plate heat exchanger surface is essential design parameter. The experiment has been conducted to verify effective surface treatment and distribution characteristics by measuring wall side flow rate and visualization test. It is observed that hydrophilic and porous layer coating have excellent wettedness, and the distribution can be regulated by adopting holes on extended surface.

• 한국재료학회지
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• 제25권4호
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• pp.165-170
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• 2015

Ceramics biomaterials are useful as implant materials in orthopedic surgery. In this study, porous HA(hydroxyapatite)/${\beta}$-TCP(tricalcium phosphate) composite biomaterials were successfully fabricated using HA/${\beta}$-TCP powders with 10-30 wt% $NH_4HCO_3$ as a space holder(SH) and $TiH_2$ as a foaming agent, and MgO powder as a binder. The HA/${\beta}$-TCP powders were consolidated by spark plasma sintering(SPS) process at $1000^{\circ}C$ under 20 MPa conditions. The effect of SH content on the pore size and distribution of the HA/${\beta}$-TCP composite was observed by scanning electron microscopy(SEM) and a microfocus X-ray computer tomography system(SMX-225CT). These microstructure observations revealed that the volume fraction of the pores increased with increasing SH content. The pore size of the HA/${\beta}$-TCP composites is about $400-500{\mu}m$. The relative density of the porous HA/${\beta}$-TCP composite increased with decreasing SH content. The porous HA/${\beta}$-TCP composite fabricated with 30%SH exhibited an elastic modulus similar to that of cortical bone; however, the compression strength of this composite is higher than that of cortical bone.

• 한국재료학회지
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• 제24권2호
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• pp.111-115
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• 2014

Titanium and its alloys are useful for implant materials. In this study, porous Ti-Nb-Zr biomaterials were successfully synthesized by powder metallurgy using a $NH_4HCO_3$ as space holder and $TiH_2$ as foaming agent. Consolidation of powder was accomplished by spark plasma sintering process(SPS) at $850^{\circ}C$ under 30 MPa condition. The effect of high energy milling time on pore size and distribution in Ti-Nb-Zr alloys with space holder($NH_4HCO_3$) was investigated by optical microscope(OM), scanning electron microscope(SEM) & energy dispersive spectroscopy(EDS) and X-ray diffraction(XRD). Microstructure observation revealed that, a lot of pores were uniformly distributed in the Ti-Nb-Zr alloys as size of about $30-100{\mu}m$ using mixed powder and milled powders. In addition, the pore ratio was found to be about 5-20% by image analysis, using an image analyzer(Image Pro Plus). Furthermore, the physical properties of specimens were improved with increasing milling time as results of hardness, relative density, compressive strength and Young's modulus. Particularly Young's modulus of the sintered alloy using 4h milled powder reached 52 GPa which is similar to bone elastic modulus.

• 한국수산과학회지
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• 제51권4호
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• pp.351-361
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• 2018

This study investigated the potential of collagenous protein fractions (CPFs) as functional foods. The specific CPFs studied were recovered from the roe of bastard halibut (BH), Paralichthys olivaceus; skipjack tuna (ST), Katsuwonus pelamis; and yellowfin tuna (YT), Thunnus albacares through the alkaline solubilization process at pH 11 and 12. The buffer capacity, water-holding capacity and solubility of CPFs with pH-shift treatment were significantly better at alkaline pH (10-12) than at acidic pH (2.0). At pH-shift treatment (pH 2 and 12), the foaming capacities of CPFs from ST and YT were improved compared to those of controls, but they were unstable compared to BH CPFs. The emulsifying activity index (EAI, $m^2/g$ protein) of CPFs (controls) was 16.0-21.1 for BH, 20.1-23.9 for ST and 9.3-13.7 for YT (P<0.05). CPFs adjusted to pH 12 showed improved EAI and YT CPFs showed significantly greater emulsifying ability than those from BH and ST. CPFs recovered from fish roe are not only protein sources but also have a wide range of food functionalities, confirming the high availability of fish sausage and surimi-based products as protein or reinforcing materials for functional foods and alternative raw materials.

• 한국산학기술학회논문지
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• 제16권5호
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• pp.2979-2984
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• 2015

본 연구에서는 발포제를 이용하여 형성된 기공을 확대하는 방식의 공정으로써, 선택적 하이브리드 구조의 폴리머 필름의 제작을 위한 새로운 발포기술을 제시하였다. 기존의 발포제만을 이용한 폐쇄형 기공보다 큰 기공을 형성하기 위해서 PP에 발포제와 구리분말(Copper powder)을 혼합하여 만든 필름 내부에 355nm파장의 UV 펄스레이저를 이용하여 LAMO(Laser Aided Micro pore Opening) 공정 방식을 통한 기공의 크기를 확장하는 실험을 진행하였다. 그 결과 발포공정만 수행된 기공의 크기보다 추가적인 LAMO 공정을 통해 형성된 기공의 크기가 훨씬 더 크게 관찰되었다. 본 실험의 결과를 통해 LAMO 공정에 의한 기공의 특성과의 상관관계를 파악할 수 있었으며, 기존의 UV laser를 이용하여 원하는 부위에 선택적으로 폐쇄형 기공을 형성하는 것 이상으로 기공의 크기를 제어하는 방안을 제시하고자 한다.

• 한국건설순환자원학회논문집
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• 제6권4호
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• pp.304-310
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• 2018

본 연구에서는 경량 기포 콘크리트의 부피 안정성을 확보하기 위해 소포를 저감시킬 수 있는 요소들을 레올로지 특성을 연계하여 분석하였다. 실험계획으로는 비빔시간, 물-결합재비, 증점제, 기포제, 폐지 첨가량에 대한 변화로 각 요인을 통해 실험하였다. 먼저 과도한 비빔과 기포제의 첨가량에 의해 발생한 다량은 기포는 슬러리 내에서 불안정한 상태로 존재하여 침하를 발생시킨다. 특히 기포제의 경우 계면활성제로써 물에 영향을 미치므로 배합 계획 시 물에 대한 질량비로 계획해야할 것으로 판단된다. 또한 레올로지 특성을 통해 경량 기포 콘크리트의 소성점도와 소포량이 반비례관계를 가진 것을 확인할 수 있었다. 따라서 본 연구의 결과는 경량 기포 콘크리트의 소포를 저감시킬 수 있는 요소들을 분석함으로써 경량 기포 콘크리트의 배합 조건에 대한 기초적인 자료를 제공될 것으로 판단된다.

• 한국산학기술학회논문지
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• 제18권3호
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• pp.49-55
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• 2017

대부분의 모터 케이스는 방수기능과동심도, 직각도 품질 등이 우수한딥드로잉 제품을 채택하고 있으며 그외 방수기능이 필요없는 블로우모터, 시트모터 등 실내에 장착되는 모터 케이스는 멀티포밍 제조방법을 채택하고 있다. 딥드로잉 공정은 드로잉 성형, 트리밍 및 피어싱 등 약 12공정을 소화할수 있는 고가의 트랜스퍼 프레스가 필요하다. 하지만 멀티포밍 공법은 멀티포밍기 1대 또는 멀티포밍기 1대와 프레스 1대의 구성으로 이루어지기 때문에 저렴한 투자로도 완제품 생산이 가능하다. 멀티포밍기는 대부분 수입이 되는 고가설비 이고 국내 중소기업이 개발한 굽힘/전단가공 일체형 멀티포밍기는 생산원가를 줄이는데 부족하여 굽힘/전단 분리형 멀티포밍기를 본 연구를 통해 개발하였다. 일체형 멀티포밍기는 비교적 얇고 작은소형 제품을 제한적인 작업 방법으로 사용된다. 크고 소재가 두꺼운 제품은 전단 하중이 높아 단발 크랭크 프레스를 이용하고 블랭킹 후 멀티포밍기로 이동 작업자가 수작업으로 소재를 공급한다. 멀티포밍기에서 벤딩 작업이 이루어지면 다시 프레스로 이송해 치수를 교정한다. 이러한 작업공정 분산은 생산성 저하, 품질이슈 및 과도한 인원 투입으로 원가경쟁력 저하를 가져왔다 이에 굽힘/전단가공 공정분리와 설비자동화를 통하여 안정되고 원가가 절감되는 생산체계를 갖추고자 하는게 본 연구의 목적이다.