• Journal of the Korean Society of Hazard Mitigation
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• v.7 no.3
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• pp.19-31
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• 2007

Humidity and strain were estimated for understanding the relation between humidity change by self-desiccation and shrinkage in high-performance concrete with low water binder ratio and containing fly ash and blast furnace slag. Internal humidity change and shrinkage strain were about 10%, 10%, 7%, 11%, 11% and $320{\times}10^{-6}$, $270{\times}10^{-6}$, $231{\times}10^{-6}$, $371{\times}10^{-6}$, $350{\times}10^{-6}$ respectively on OPC30, O30F10, O30F20, O30G40, O30G50 and from the results, fly ash made humidity change and strain decrease but slag increase comparing with ordinary portland cement. Considering only relation internal humidity and shrinkage by self-desiccation, humidity change and shrinkage represented the strong linear relation regardless of mineral admixture. For specifying the relation on internal humidity change and autogenous shrinkage strain, shrinkage model was established which is driven by capillary pressure in pore water and surface energy in hydrates on the assumption of a single network and extended meniscus in pore system of concrete. This model and experimental results had a similar tendency so it would be concluded that the internal humidity change by self-desiccation in HPC originated in small pores less than 20nm, therefore controlling plan on autogenous shrinkage might be focused on surface tension of water and degree of saturation in small pore.

• Journal of the Korea Concrete Institute
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• v.16 no.6 s.84
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• pp.777-783
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• 2004

In this study, for improving of concrete properties, those are used ground granulated blast slag(GGBS) and fly ash(FA). There are some advantage to add the GGBS and FA in plain concrete. The objective of this study is to find the characteristics of fresh and hardened antiwashout underwater concrete which is followed by blended ratio of GGBS and FA. Experimental parameters were chosen that W/C was 50%, S/a was 40% and as the blended ratio of GGBS was set at 0, 10, 20, 30, 40, 50, 60% and FA was set at 0, 10, 15, 20, 25, 30, 35% in order to prove the properties of antiwashout underwater concrete can be changed by blended ratio of GGBS md FA. It was measured pH, suspension and slump flow of fresh antiwashout underwater concrete and compressive strength of hardened antiwashout underwater concrete in age of 7 days, 28 days and 56 days. The experimental results of fresh concrete show that pH, suspension and slump flow were all satisfied with KSCE (Korea Society of Civil Engineering) standard value and mix design standard value. To synthetically consider, the optimum blended ratio is about 30% of GGBS and FA.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.1
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• pp.131-138
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• 2010

This research intends to analyze the basic characteristics of cements(hereinafter "CC") with affordable price and particle distribution effective as hydration heat face which are discharged at the outlet of smashing process of ordinary portland cement(hereinafter "OPC") manufacturing process such as fluidity, rigidity, temporary insulation temperature increase amount etc to review the potential of developing "CC" to 3 ingredients low heat cement that substitutes fly ash and blast furnace slag(hereinafter "BS"). As a result of experiment, fluidity tended to decrease with increase in CC substitution rate, and increase with increase in FA+BS substitution rate. Air amount tended to slightly decrease with increase in CC substitution rate, and decrease with increase in FA+BS substitution rate. Condensation characteristics were such that condensation time was delayed with increase in CC and FA+BS substitution rate. As for the temperature rising amount by temporary insulation, peak temperature decreased with increase in CC substitution rate and increase in FA+BS substitution rate in general, and thereafter, temperature tended to decrease slowly. Compressive strength decreased with increase in CC and FA+BS substitution rate, and as aging goes on, long term strength was equivalent to plain or higher. By and large, when FA+BS was substituted to CC, fluidity and air amount tended to decrease, but hydration heat face showed good reduction effects, suggesting possibility of development to 3 ingredients low heat cement.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.1
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• pp.64-71
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• 2015

Silica fume is generally adopted as admixture for Ultra High Strength Concrete (UHSC) owing to its remarkable contribution to the strength and durability but increases significantly the fabrication cost of UHSC. Accordingly, this study investigates the replacement of silica fume by blast furnace slag (BS) and fly ash (FA) in order to lower the fabrication cost of 80MPa-UHSC. To that goal, experiment is conducted on the mix proportions of mortar in terms of its binder combination, water-to-binder ratio (W/B) and unit binder content. Based on the experimental data, a mix design of concrete is derived and its properties are verified. The results reveal that a W/B of 21% and unit binder content of $720kg/m^3$ are appropriate to achieve 80MPa-UHSC using a binder composed of 60% of OPC, 30% of BS and 10% of FA. The properties of the corresponding UHSC are seen to be satisfactory with a slump flow of 715mm and compressive strength of 97MPa at 28days. The application of the binder combination derived in this study is analyzed to reduce the cost by 50% of binder compared to the mix using silica fume while realizing equivalent performance.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.1
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• pp.52-59
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• 2014

This study examines the compressive strength, elastic modulus and splitting tensile strength of geopolymer concrete in order to evaluate its mechanical characteristics according to the admixing of fly ash and blast furnace slag. Moreover, identical tests are also conducted considering the amount of powder, the mixing ratio of alkali activator and the mixing ratio of silica fume for further comparative analysis considering various variables. The comparison with the formulae specified in Korean and overseas codes reveal that a mixing ratio of 18% is adequate for the alkali activator and that a replacement ratio of 5% by silica fume is recommended for silica fume. The elastic modulus of the geopolymer concrete appears to increase slightly with the increase of the compressive strength per variable and age and to be smaller than the values predicted by the formulae specified in Korean and overseas codes. In addition, the examination of the stress-strain curves shows that the geopolymer concrete exhibits ductile behavior compared to the conventional OPC. In view of the splitting tensile strength, high strength is observed for a powder content of $400kg/m^3$ and a replacement ratio of 18% by silica fume. The resulting ratio of the compressive strength to the splitting tensile strength is seen to range between 8.7 and 10.2%.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.435-442
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• 2022

In this study, the density of KS L 5110 was compared with that of gas pycnometer and electronic densimeter for efficient density management of cement, blast furnace slag powder and fly ash. Correlation and usability according to the test method were reviewed, and based on the results of the experiment, the availability of alternative test methods was analyzed. As a result of the density test according to test methods, the density of cement, blast furnace slag powder and fly ash tended to decrease in the order of gas pycnometer, KS L 5110 and electronic densimeter. Because the volume range of the sample to be evaluated is different depending on test methods. The coefficient of determination R² was in the range of 0.71 to 0.93, and the correlation according to test methods showed a relatively good correlation. If correction is applied through correlation, it is analyzed that alternative test methods can be used. As a result of the usability review considering the test procedure, measurement time and coefficient of variation, the gas pycnometer had the simplest test procedure and good reliability. In addition, it is expected that the reproducibility between the testers is relatively high because the skill is not greatly required.

• Korean Journal of Materials Research
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• v.25 no.2
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• pp.75-80
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• 2015

The carbon dioxide($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical method to reducing $CO_2$ for building materials is the addition of slag and fly ash, like pozzolan material, while another method is reducing $CO_2$ production by carbon negative cement development. The MgO-based cement was from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements could improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as main starting materials, as well as silica fume, fly ash and blast furnace slag for the mineral admixture, were carried out for industrial waste material recycling. In order to increase the hydration activity, $MgCl_2$ was also added. To improve hydration activity, $MgCO_3$ and serpentinite were fired at $700^{\circ}C$ and autoclave treatment was conducted. In the case of $MgCO_3$ as starting material, hydration activity was the highest at firing temperature of $700^{\circ}C$. This $MgCO_3$ was completely transferred to MgO after firing. This occurred after the hydration reaction with water MgO was transferred completely to $Mg(OH)_2$ as a hydration product. In the case of using only $MgCO_3$, the compressive strength was 3.5MPa at 28 days. The addition of silica fume enhanced compressive strength to 5.5 MPa. In the composition of $MgCO_3$-serpentine, the addition of pozzolanic materials such as silica fume increased the compression strength. In particular, the addition of $MgCl_2$ compressive strength was increased to 80 MPa.

• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.5
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• pp.133-142
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• 2008

This paper studies the early-aged chloride binding capacity of various blended concretes including OPC(ordinary Portland cement), PFA(pulversied fly ash), GGBFS(ground granulated blast furnace slag) and SF(silica fume) cement paste. Cement pastes with 0.4 of a free water/binder ratio were cast with chloride admixed in mixing water, which ranged from 0.1 to 3.0% by weight of cement and different replacement ratios for the PFA, GGBFS and SF were used. The content of chloride in each paste was measured using water extraction method after 7 days curing. It was found that the chloride binding capacity strongly depends on binder type, replacement ratio and total chloride content. An increase in total chloride results in a decrease in the chloride binding, because of the restriction of the binding capacity of cement matrix. For the pastes containing maximum level of PFA(30%) and GGBFS(60%) replacement in this study, the chloride binding capacity was lower than those of OPC paste, and an increase in SF resulted in decreased chloride binding, which are ascribed to a latent hydration of pozzolanic materials and a fall in the pH of the pore solution, respectively. The chloride binding capacity at 7 days shows that the order of the resistance to chloride-induced corrosion is 30%PFA > 10%SF > 60%GGBFS > OPC, when chlorides are internally intruded in concrete. In addition, it is found that the binding behaviour of all binders are well described by both the Langmuir and Freundlich isotherms.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.2
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• pp.143-148
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• 2016

The aim of research is inducing the optimum proportion of fly ash(FA) and blast furnace slag(BS) for ternary cement. In this research, hence, the fundamental properties of mortar mixtures were evaluated depending on various proportion of FA and BS. The results of the experiment, within the scope of the study, obtained the following conclusions. Flow of the mixtures was increased with addition of binary supplementary cementitious material(SCM), and especially, portion of FA. The air content of the mixtures was increased with addition of binary SCMs, while it was decreased with increased FA content. In the case of unit mass, increased value was obtained due to the increased air content within 25 to 45% of binary SCM content, while it was increased within 65 to 100% of binary SCM up to only 20% of FA content and decreased more than 20% of FA because of the low density of FA. The setting time of the mixtures was delayed with addition of binary SCM and FA. In the case of compressive strength, at 91-day age, the highest value was obtained with 25 and 45% of binary SCM with the proportion of FA to BS of 40 to 60. Therefore, based on the compressive strength, it is considered that the binary SCM content of 25 and 45% with the proportion of FA to BS of 2 : 3 is the most favorable conditions in this research scope.

• Journal of the Korea Concrete Institute
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• v.28 no.5
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• pp.593-600
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• 2016

The paper presented investigates the effects of kaolinite on strength properties of alkali-activated multi-component cement. The binders of this study was blended of ground granulated blast furnace slag (GGBFS), fly ash (FA), silica fume (SF) and kaolinite (KA). In this study, the specimens of combination of 20%~70% GGBFS, 10%~60% FA, 10% SF (constant ratio) and 10%~50% KA binder were used for strength properties tests. The water/binder ratio was 0.5. The binders (GGBFS + FA + SF + KA) was activated by sodium hydroxide (NaOH) and sodium silicate ($Na_2SiO_3$) was 10% by total binder weight (10% NaOH + 10% $Na_2SiO_3$). The research carried out is on the compressive strength, water absorption, ultrasonic pulse velocity (UPV) and X-ray diffraction (XRD). The compressive strength decreased as the contents of KA increase. One of the major reason for this is the low reactivity of KA compared with other raw materials used as precursors such as GGBFS or FA. The presence of remaining KA indicates that the initially used quantity has not fully reacted during hydration. Moreover, the results have indicated that increased of KA contents decreased UPV under all experimental conditions. The drying shrinkage and water absorption increased as the content of KA increase. Test result clearly showed that the strength development of multi-component blended cement were significantly dependent on the content of KA and GGBFS.