• 대한건축학회논문집:구조계
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• 제34권3호
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• pp.37-42
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• 2018

The use of fly ash in construction materials is increasing worldwide due the various advantages of using it, such as to produce durable concrete, or to use less cement and thus lower carbon dioxide emissions. The quality of fly ash is often determined by loss on ignition value (LOI), where an upper limit of LOI is set in each country for quality control purpose. However, due to many reasons, production of high LOI fly ash is increasing that cannot be utilized in concrete, ending up in landfill. In this study, the effect of fly ash use in cementitious materials on nitrogen oxides adsorption is examined. In particular, the effect of using high LOI, and thus high carbon content fly ash on nitrogen oxides adsorption is investigated. The results suggest that the higher carbon content fly ash is related to higher nitrogen dioxide adsorption, although normal fly ash was also more effective in nitrogen dioxide adsorption than ordinary portland cement. Also, higher replacement rate of up to 40% of fly ash is beneficial for nitrogen dioxide adsorption. These results demonstrate that high carbon fly ash can be used as construction materials in an environmentally friendly way where strength requirement is low and where nitrogen oxides emissions are high.

• 플랜트 저널
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• 제11권1호
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• pp.50-57
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• 2015

연구에서는 국내 D 석탄 화력발전소에서 비회 이송량 35,800 kg/h의 용량으로 운전 중인 비회 이송설비를 대상으로 최대 비회 이송량을 예측하였다. 수평거리 550 m, 수직거리 40 m, 엘보우 9개소, 직경 0.254 m의 이송관으로 구성된 비회 이송관로와 트립(trip) 정압 1,163 mmH2O, 풍량 5,040 m3/h인 용적식 비회 이송 송풍기로 이루어진 비회 이송 시스템에서 최대 비회 이송량은 비회 이송량의 증가에 따른 비회 이송 시스템의 압력 손실과 용적식 비회 이송 송풍기의 트립 정압이 같아질 때이며, 이 조건 하에서 가능한 최대 비회 이송량은 52,600 kg/h로 예상되었다.

• 환경영향평가
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• 제8권4호
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• pp.25-35
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• 1999

Fly ash, by-product from coal fired power station, has long been regarded as a potential contamination source for heavy metals and inorganics due to their enriched concentrations and associations with particle surface. Feed coal and fly ash samples were collected from two power stations; Yongdong deliang with domestic anthracite coals and Boryong with imported bituminous coals. The coal and fly ash samples were analyzed for chemical composition and mineral components, using XRF and XRD. Batch leaching experiments were conducted by agitating samples with deionised water for 24 hours. Anthracite coals are generally higher in Al and Si contents than bituminous coals. This is due to the higher ash contents of the anthracite coal than bituminous coal. The chemistry of the two fly ash samples shows broadly similar compositions each other, except for the characteristically high contents of Cr in anthracite coal fly ash. Leaching experiments revealed that concentrations of metals gradually decreased with leachings in general. However, measurable amounts of metals were present in the effluent from weathered ash and the samples subjected to the leaching procedure. These metals are likely to indicate that the metals in fly ash were incorporated into glass fraction as well as associated with particle surface of samples. Dissolution of aluminosilicate glass would control releasing heavy metals from fly ash as weathering progresses during landfill with implication of possible groundwater contamination through fly ash landfill.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 봄 학술발표회 논문집(I)
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• pp.95-98
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• 1998

Fly ash is glassy dust collected from coal fired power plant. Recently, much research for fly ash conducted in Korea and fly ash is a valuable material especially when it used in high strength, high flowable, high durability concrete. But it varies with coal source, coal grinding and boiler conditions. Therefore, it is important that quality control of fly ash itself to get high quality concrete. In this study, over 20 samples of Poryong and Samchonpo fly ashs are tested and analyzed. The physical, chemical properties of fly ash and their relationships are investigated and it can be applied to quality control of concrete.

• Journal of Mechanical Science and Technology
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• 제15권6호
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• pp.804-812
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• 2001

A triboelectrostatic separation system for removing unburned carbon from coal fly ash is designed and evaluated. Fly ash from a coal-fired power plant is used as an accepted additive in concrete where it adds strength, sulfate resistance and reduced cost, provided acceptable levels of unburned carbon are maintained. Unfortunately, unburned carbon in coal fly ash absorbs some of other additives and reduces the concrete strength. This paper describes to investigate dry triboelectrostatic process to separate unburned carbon from coal fly ash and utilize it into economically valuable products. The laboratory-scale triboelectrostatic separation system consists of a particle feeding system, a tribocharger, a separation chamber, and collection systems. Particles of unburned carbon and fly ash can be imparted positive and negative surface charges, respectively, with a copper tribocharger due to differences in the work function values of the particles and the tribocharger, and can be separated by passing them through an external electric field. Results showed that fly ash recovery was strongly dependent on the electric field strength and the particle size. 70wt% of fly ash containing 6.5wt% of carbon contents could be recovered at carbon contents below 3%. The triboelectrostatic separation system showed a potential to be an effective method for removing unburned carbon from coal fly ash.

• 한국세라믹학회지
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• 제20권2호
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• pp.135-146
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• 1983

This study is to investigate the properties of domestic fly ash for utilization as data in regard to fly ash which is by-product of domestic coal powder plants and the possibility of utilization as insulation material of domestic fly ash. Composition refractoriness size distribution density contents of hollow particles and crystalline phase were examined as the properties of domestic fly ash. As to the fired test pieces of fly ash by itself that varied contents of hollow particles with four kinds and of the fly ash-clay-saw dust system linear shrinkage bulk density app. porosity compressive strength thermal conductivity and structures were investigated for the possibility of utilization as an insulation material. The results are as follows : 1. The properties of the fly ash I) The constituent particle of the fly ash is spherical and it contains not a few hollow particles (floats by water 0.30-0.50 floats by $ZnCl_2$ aq.(SpG=1.71) 6.97-16.72%). ii) The chemical compositions of fly ash are $SiO_243.9-54.1%$ , $Al_2O_321.0-30.7%$ Ig loss is 7.4-24.1% and the principal of Ig loss is unburned carbon. iii) Fly ash was not suitable to use for mortar and concrete mixture because Ig. loss value is higher than 5% 2. Utilization as insulation material I) The test pieces of original fly ash floats by water floats by ZnCl2 aq(SpG=1.71) p, p t by ZnCl2 aq.(SpG=1.71) that were fired at 110$0^{\circ}C$ represented 0.11-0.18 kcal/mh$^{\circ}$ C as thermal conductivity value. ii) The test pieces which (76.5-85.5) wt% fly ash-(8.5, 9.5) wt% clay-(5.0-15.0) wt% saw dust system(68.0-72.0) wt% fly ash -(17.0-18.0)wt% clay-(10.0-15.0) wt% saw dust system and 59.5 wt% fly ash-25.5 wt% clay-15.0wt% saw dust system were fired at 110$0^{\circ}C$ the thermal conductivity was less than 0.1Kcal/mh$^{\circ}$ C. iii) In view of thermal conductivity and economic aspect insulation materials which added saw dust as blowing agent and clay as inorganic binder are better than that of fly ash as it is or separated hollow fly ash particles. iv) When the saw dust contents increased in the (59.5-90.0) wt% saw dust system and when amount of clay de-creased and firing temperature decreased under the condition of equal addition of saw dust app. porosity increased but bulk density compressive strength and thermal conductivity decreased.

• 콘크리트학회논문집
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• 제16권6호
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• pp.751-757
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• 2004

화력 발전소에서 발생하는 석탄회(fly ash, bottom ash)를 안정적으로 재활용하기 위하여 알칼리 활성화된 석탄회 경화체 및 인공경량골재를 제조하였으며, 알칼리 활성화 석탄회 인공경량골재의 콘크리트 적용을 위한 실험적 연구를 수행하였다. 따라서, 알칼리 활성화된 석탄회 경화체의 최적 배합비, 알칼리 활성화 석탄회 경화체와 인공경량골재의 기본적 특성, 역학적 특성과 환경안전성, 알칼리 활성화 석탄회 인공경량골재를 사용한 콘크리트의 역학적 특성과 동결음해저항성을 파악하였다 실험결과 알칼리 활성화 석탄회 인공경량골재를 제조하기 위한 경화체의 최적 배합비는 시멘트 $10\%$, Water glass $15\%$, NaOH $10\%$, $MnO_2\;5\%$였으며, 혼합물을 $50^{\circ}C$ 항온습윤양생 24k후 상온 공기중 양생을하여, 7일 압축강도 36.4MPa를 얻을 수 있었다. 제조된 골재의 폴리머 함침 결과 $10\%$ 파쇄강도를 $150\%$ 향상시킬 수 있었으며, 콘크리트용 굵은 골재로의 활용 가능성을 파악할 수 있었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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• pp.211-216
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• 1994

This study dealt with the properties for fly ash of conbined heat power plant and application for concrete industry. For this purpose, fly ash sampled Ulsan conbined heat power plant and analyzed for physical and chemical properties. As analyzed results of fly ash, contents of $SiO_ and Al_O_ $in the fly ash of Ulsan were less than those of Thermo-electric power plant(Boryuing), but contents of CaO were tem times as much as those of Boryung, because of these differences, it is expected that pozzolanic activity of concrete using fly ash of Ulsan will be different from another fly ash. Concrete specimens were tested to evaluate concrete preformance when 10 to 50 percent of the portland cement by weight in the concrete mix was replaced with fly ash of conbined heat power plant. As test results, workability and consideration in the fresh concrete were increased and concrete strength was showed more than 400kg/$\textrm{cm}^2$ for the required age. This study would be provided valuable data for the practical utilization of fly ash(conbined heat power plant). In the future, properties of fly ash concrete including long term strength, elapsed time, pozzolanic activity, modulus of elasticity, sulfate resistance, shrinkage, freeze-thaw durability and so on will be studied.

• Computers and Concrete
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• 제8권5호
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• pp.583-595
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• 2011

This paper studied the cement efficiency factor (k factor) of high calcium Class F fly ash. This k factor represents a unit of fly ash with efficiency equivalent to k unit of cement. The high calcium Class F fly ash was used to replace cement in concrete. The modified Bolomey's law with linear relationship was used for the analysis of the result of compressive strength, cement to water ratio (c/w) and fly ash to water ratio (f/w) by using the multi-linear regression to determine the k factor and other constants in the equations. The results of analysis were compared with the results from other researcher and showed that the k factor of high calcium Class F fly ash depends on the fineness of fly ash, replacement level and curing age. While the amount of CaO content in Class F fly ash not evident. Furthermore, necessary criteria and variables for the determination of the k factor including the use of the k factor in concrete mix design containing fly ash were proposed.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문발표회
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• pp.67-71
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• 2003

This study is for the great quantity use of fly-ash. For the producing of high volume concrete from the use of fly-ash, the method of replacement between bonding agents and fine aggregate by fly-ash at the same time was used. It was used that the adiabatic temperature rise of concrete about the mass member which bad been produced by the method that was mentioned before, and the hydration heat of the core test pieces in concrete was measured. Also the core test pieces which were replaced with fly-ash was studied by the compressive streneth's comparison between standard care test pieces and core test pieces. In the case of mass test pieces, hydration heat and the tine to reach the highest temperature were decreased by an increase in replaced fly-ash's amounts of concrete. In addition, among the test pieces having the same amounts of concrete, the test pieces having more replaced amounts of fly-ash's fine aggregate showed higher hydration heat and the increased time to reach the highest temperature. Compressive strength was also increased by hydration heat's decrease according to fly-ash replacement. Replacement of fly-ash was more effective in high temperature environment.