• Journal of the Korea Concrete Institute
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• v.14 no.1
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• pp.100-109
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• 2002

Significant damage to concrete results from the intrusion of corrosive solutions, for example, dissolved chlorides corrode reinforcing steel and cause spatting. Effectively blocks the penetration of these solutions will eliminate or greatly reduce this damage and lead to increased durability. This study is to investigate the effects of pozzolanic admixtures, fly ash and silica fume, and a blast furnace slag on the chloride ion penetration of concretes. The main experimental variables wore the water-cementitious material ratios, the types and amount of admixtures, and the curing time. And it is tested for the porosity and pore size distributions of cement paste, chloride ion permeability based on electrical conductance, and 180-day ponding test for chloride intrusion. The results show that the resistance of concrete to the penetration of chloride ions increases as the w/c was decreased, and the increasing of curing time. Also, concrete with pozzolans exhibited higher resistance to chloride ion penetration than the plain concrete. The significant reduction in chloride ion permeability(charge passed) of concrete with pozzolans due to formation of a discontinuous macro-pore system which inhibits flow. It is shown that there is a relationship between chloride ion permeability and depth of chloride ion penetration of concrete, based on the pore structure (porosity and pore size distributions) of cement paste.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.4
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• pp.287-294
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• 2019

GGBFS(Ground Granulated Blast Furnace Slag) has been widely used in concrete for its excellent resistance chloride and chemical attack, however cracks due to hydration heat and dry shrinkage are reported. In many International Standards, GGBFS with low fineness of 3,000 grade is classified for wide commercialization and crack control. In this paper, the mechanical and durability performance of concrete were investigated through two mix proportions; One (BS) has 50% of w/b(water to binder) ratio and 60% replacement ratio with low-fineness GGBFS, and the other (TS) has 50% of w/b and 60% replacement ratio with 4000 grade and FA (Fly Ash). The strength difference between TS and BS concrete was not great from 3 day to 91 day of age, and BS showed excellent performance for chloride diffusion and carbonation resistance. Two mixtures also indicate a high durability index (more than 90.0) for freezing-thawing since they contain sufficient air content. Through improvement of strength in low fineness GGBFS concrete at early age, mass concrete with low hydration heat and high durability can be manufactured.

• Journal of the Korea Institute of Building Construction
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• v.16 no.1
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• pp.59-65
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• 2016

This study examined the compressive strength development and pH values of alpha-calcium sulfate hemihydrate(${\alpha}-CH$)-based binders developed for vegetation concrete with neutral pH between 6~7. Considering cost down and strength enhancement of the prepared binders, the ${\alpha}-CH$ was partially replaced by ground granulated blast furnace slag(GGBS), fly ash(FA), or ordinary Portland cement(OPC) by 25% and 50%. The compressive strength of mortars using 100% ${\alpha}-CH$ was 50% lower than that of 100% OPC mortars. With the increase of the replacement level of GGBS or FA, the compressive strength of ${\alpha}-CH$-based mortars tended to decrease, whereas the pH values were maintained to be 6.5~7.5. The main hydration products of ${\alpha}-CH$-based binders with GGBS or FA were a gypsum($CaSO_4$), whereas portlandite($Ca(OH)_2$) was not observed in such binders. Meanwhile, the pH values of ${\alpha}-CH$-based binders with OPC exceeded 11.5 due to the formation of $Ca(OH)_2$ phase as a hydration product. From the thermogravimetric analysis, the amount of $Ca(OH)_2$ in ${\alpha}-CH$-based binders with OPC was evaluated to be approximately 10% of the cement content.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.4
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• pp.136-143
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• 2016

There are various method for evaluating the durability life of concrete structures due to salt damage. The best way is to perform a corrosion test for a rebar embedded in concrete specimen was exposure to marine environment. However, this method has the disadvantage that it takes a long period of time. Also, accelerated corrosion test which was complemented complements the time-consuming weakness is limited to apply because it could not reveal a correlation between long-term exposure test. Accordingly, the purpose of this study is to derive a correlation coefficient between cycle drying-wetting accelerated corrosion test and long-term exposure test. Corrosion initiation time was measured in four types of concrete samples, i.e., two samples mixed with fly ash(FA) and blast furnace slag(BS), and the other two samples having two water/cement ratio(W/C = 0.6, 0.35) without admixture(OPC 60 and OPC 35). The accelerated corrosion test was carried out by two case, i.e., one is a cyclic drying-wetting method(case 1), and the other is a artificial seawater ponding test method(case 2). Whether corrosion occurs, it was measures using half-cell potential method. The results indicated that case 1 is to accelerated the corrosion of rebar about 24~36% as compared with case 2, then the corrosion of rebar embedded in concrete occurred according to the order of OPC60, FA, BS, OPC35. Correlation coefficient between accelerated corrosion test and long-term exposure test, case 1 is 4.23 to 5.42, and case 2 is 6.54 to 7.82.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.2
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• pp.94-101
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• 2016

This paper presents an investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(0, 30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0) and initial curing temperatures($23^{\circ}C$ and $70^{\circ}C$). The tests involved immersions for a period of 6 months into 10% solutions of sodium sulfate and magnesium sulfate. The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, as higher GGBFS replace ratio or Ms shown higher compressive strengths on 28 days. In case of immersed in 10% sodium sulfate solution, the samples shows increase in long-term strength. However, for samples immersed in magnesium sulfate solutions, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$); the gypsum increased up to 6 months continuously.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.1
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• pp.22-28
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• 2019

Cement is a basic material for the construction industry and it requires high temperature sintering when manufacturing cement. $CO_2$ emissions from raw materials and fuels are recognized as new environmental problems and efforts are underway to reduce them. Techniques for reducing $CO_2$ in concrete are also recommended to use blended cement such as blast furnace slag or fly ash. In addition, the construction waste generated in the dismantling of concrete structures is recognized as another environmental problem. Thus, various methods are being implemented to increase the recycling rate. The purpose of this study is to utilize the inorganic raw materials generated during the dismantling of the structure as a raw material for the low carbon type cement binder. Such as, waste concrete powder, waste cement block, waste clay brick and waste textile as raw materials for low carbon type cement binder. From the research results, low carbon type cement binder was manufactured from the raw material composition of waste concrete powder, waste cement block, waste clay brick and waste textile.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.2
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• pp.61-70
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• 2019

Geopolymer is an eco-friendly construction material that has various advantages such as reduced $CO_2$ emission, fire resistance and low thermal conductivity compared to cement. However, it has not been many studies on the thermal behavior of the surface of the geopolymer panel when flame is applied to the surface. In this study, surface characteristics of hardened geopolymer on flame exposure was investigated to observe its characteristics as heat-resistant architectural materials. External structure changes and crack due to the heat shock were not observed during the exposure on flame. According to the residue of calcite and halo pattern of aluminosilicate gel, decarboxylation and dehydration were extremely limited to the surface and, therefore, it is thought that durability of hardened geopolymer was sustained. Gehlenite and calcium silicate portion was inversely proportional to quartz and calcite and significantly directly proportional to BFS replacement ratio. Microstructure changes due to the thermal shock caused decarboxylation and dehydration of crystallization and it was developed the pore and new crystalline phase like calcium silicate and gehlenite. It is thought that those crystalline phase worked as a densification and strengthening mechanism on geopolymer panel surface.

• Journal of the Korean Geosynthetics Society
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• v.22 no.3
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• pp.87-95
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• 2023

Recently, redevelopment of the original downtown area is underway, the necessity of construction in adjacent location is increasing. However, excavations in dense urban areas are prone to ground problems due to various causes, so it is necessary to use materials and methods that can minimize such problems. As a general earth retaining method, various methods such as diaphragm wall and CIP method are applied using cement. However, since a large amount of cement is used for the installation of earth retaining method, it is necessary to conduct research on the development of new cement substitute materials to significantly reduce greenhouse gas emissions. In this study, we utilized the hardening reaction of blast furnace slag powder, desulfurized gypsum and high calcium fly ash by alkali activation and applied it to the SCW method. As a result, it was analyzed that the compressive strength of solidified soil using development solidification material was 96.2 ~ 106.3% of OPC at 28 days of curing. In addition, the strength increment ratio was 2.06 for sandy soil and 2.41 for clayey soil, which was higher than 1.85 of OPC. It seems an advantageous in terms of long-term strength. In addition, from the environmental point of view, it was analyzed that there is no elution of heavy metals and that greenhouse gas emissions can be dramatically reduced. Therefore, if further studies are conducted, it can be applied to the SCW method.

• Journal of the Korea institute for structural maintenance and inspection
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• v.28 no.3
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• pp.37-46
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• 2024

This study investigates the evolution of concrete damage due to chloride-induced steel corrosion through Impact-echo (IE) testing. Three reinforced concrete specimens, each measuring 1500 mm in length, 400 mm in width, and 200 mm in thickness, were fabricated using three concrete mixture proportions of blended cement types: ordinary Portland cement, ground granulated blast-furnace slag and fly ash. Steel corrosion in the concrete was accelerated by impressing a 0.5 A current following a 35-day cycle of wet-and-dry saturation in a 3% NaCl solution. Initial IE data collected during the saturation phase showed no significant changes, indicating that moisture had a minimal impact on IE signals and highlighting the slow progress of corrosion under natural conditions. Post-application of current, however, there was a noticeable decline in both IE peak frequency and the P-wave velocity in the concrete as the duration of the impressed current increased. Remarkably, progressive monitoring of IE proves highly effective in capturing the critical features of steel-corrosion induced concrete deterioration, such as the onset of internal damages and the rate of damage propagation. These results demonstrate the potential of progressive IE data monitoring to enhance the reliability of diagnosing and prognosticating the evolution of concrete damage in marine environment.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.82-93
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• 2024

Since the cement industry generates more than 60 % of CO₂ during the clinker production process, supplementary cementitious materials are used worldwide to reduce CO₂ efficiently. Mainly used supplementary cementitious materials such as blast furnace slag and fly ash, which are used in various industries including the cement industry, concrete admixtures, and ground solidification materials. However, since their availability is expected to decrease in the future according to the carbon neutrality strategy of each industry, new supplementary cementitious materials should be used to achieve the cement industry's goal for increasing the additive content of Portland cement. Limestone is a material that already has a large amount in the cement industry and has the advantage of high grinding efficiency, so overseas developed countries established Portland limestone cement standards and succeeded in commercialization. This study was an experimental study conducted to evaluate the possibility of utilizing domestic PLC, the effect of fineness and replacement ratio on the physical properties of cement was investigated, and the environmental impact of cement was evaluated by analyzing CO₂ emissions.